Citation: CHE Tinghua, TAN Xiao, YAN Jiawei, SONG Fengdan, ZHANG Hongmei, QI Suitao. Synthesis of Copper Modified Porous Nickel Self-supported Electrode and Its Catalytic Oxidation of Glucose[J]. Chinese Journal of Applied Chemistry, ;2019, 36(9): 1091-1098. doi: 10.11944/j.issn.1000-0518.2019.09.190005 shu

Synthesis of Copper Modified Porous Nickel Self-supported Electrode and Its Catalytic Oxidation of Glucose

Shaanxi Key Laboratory of Energy and Chemical Process Intensification, School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an 710049, China

Corresponding author: QI Suitao, suitaoqi@mail.xjtu.edu.cn
Received Date: 7 January 2019
Revised Date: 13 March 2019
Accepted Date: 29 April 2019

Fund Project: Supported by the Fundamental Research Funds for the Central Universities(No.xjj2016045)the Fundamental Research Funds for the Central Universities xjj2016045

Figures(7)

Porous Ni(nickel foam, NF) self-supported electrodes modified by Cu₂O/Cu were fabricated by hydrothermal method. Their morphology and structure were characterized by X-ray diffraction(XRD) and field-emission scanning electron microscopy(FESEM). The resulted surface of porous Ni is completely covered with octahedral Cu₂O/Cu composites of different sizes. The maximum diameter of the octahedron is about 5 μm. The glucose catalytic oxidation activity of Cu₂O/Cu-NF was measured by cyclic voltammetry and constant potential amperometric method in alkaline medium with three-electrode system. The results show that the Cu₂O/Cu-NF fabricated at 150℃ has the strongest electrocatalytic activity. The linear relationship of response current and glucose concentration could be observed clearly in the range of 3.7×10^-3~1.1 mmol/L and 1.4~5.0 mmol/L, with sensitivity of 6929 μA/(mmol·L^-1·cm²) and 706.1 μA/(mmol·L^-1·cm²), respectively. Satisfyingly, the Cu₂O/Cu-NF electrode is successfully employed to eliminate the interferences from uric acid(UA), acid ascorbic(AA) and L-proline(L-P) during the catalytic oxidation of glucose. The response current of Cu₂O/Cu-NF electrode for glucose electrocatalytic oxidation could reach 91.6% of the original current after one month. The Cu₂O/Cu-NF electrode allows highly sensitive, excellently selective, stable, and fast amperometric sensing of glucose and thus is promising for the future development of nonenzymatic glucose sensors.
- electrocatalysis,
- glucose oxidation,
- porous Ni self-supported electrode
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