Citation: HUANG Guobin, LUO Dengfeng, ZHANG Maosheng. Preparation of CsPbX3(X=Cl, Br, I) Perovskite Quantum Dots with Multicolor and High Luminescence Efficiency and Its Application in Light Emitting Diode Devices[J]. Chinese Journal of Applied Chemistry, ;2019, 36(8): 932-938. doi: 10.11944/j.issn.1000-0518.2019.08.190016 shu

Preparation of CsPbX3(X=Cl, Br, I) Perovskite Quantum Dots with Multicolor and High Luminescence Efficiency and Its Application in Light Emitting Diode Devices

  • Corresponding author: ZHANG Maosheng, maoshengzhang@mnnu.edu.cn
  • Received Date: 17 January 2019
    Revised Date: 6 March 2019
    Accepted Date: 4 April 2019

    Fund Project: the Natural Science Foundation of Zhangzhou City, China ZZ2016J30the Natural Science Foundation of Fujian Province, China 2013J01062the Natural Science Foundation of Minnan Normal University Mk201721Science and Technology Projects of the Education Department, Fujian Province of China JK2017032Supported by the Natural Science Foundation of Fujian Province, China(No.2013J01062), Science and Technology Projects of the Education Department, Fujian Province of China(No.JK2017032), the Natural Science Foundation of Zhangzhou City, China(No.ZZ2016J30), the Natural Science Foundation of Minnan Normal University(No.Mk201721)

Figures(5)

  • Highly efficient and polychromatic luminescent CsPbX3 perovskite quantum dots(PQDs) were synthesized under room temperature. The entire reaction is very fast and simple. Polychromatic luminescence of CsPbX3 PQDs can be achieved by adjusting different halide compositions(Cl, Br, I). The as-prepared CsPbX3 PQDs have a cubic morphology with an average size about 10 nm. The photoluminescence of CsPbX3 PQDs has a characteristic of wide visible spectral region of 410~630 nm, narrow emission line-widths of 14~38 nm and quantum yields of 10%~90%. Finally, the CsPbX3 PQDs are successfully applied to prepare light emitting diode(LED) devices. At a constant voltage work for a long time, the emission color, intensity, and color coordinates of the LED device remain unchanged.
  • 加载中
    1. [1]

      Zhang F, Zhong H, Chen C. Brightly Luminescent and Color-Tunable Colloidal CH3NH3PbX3(X=Br, I, Cl) Quantum Dots:Potential Alternatives for Display Technology[J]. ACS Nano, 2015,9(4):4533-4542. doi: 10.1021/acsnano.5b01154

    2. [2]

      LOU Sunqi, XUAN Tongtong, YU Caiyan. Synthesis, Properties and Applications of Inorganic Halide Perovskite Nanocrystals[J]. Chinese J Appl Chem, 2016,33(9):977-993.  

    3. [3]

      Song J, Li J, Li X. Nanocrystals:Quantum Dot Light-Emitting Diodes Based on Inorganic Perovskite Cesium Lead Halides(CsPbX3)[J]. Adv Mater, 2015,27(44):7162-7167. doi: 10.1002/adma.201502567

    4. [4]

      Zhang X, Lin H, Huang H. Enhancing the Brightness of Cesium Lead Halide Perovskite Nanocrystal Based Green Light-Emitting Devices Through the Interface Engineering with Perfluorinated Ionomer[J]. Nano Lett, 2016,16(2):1415-1420. doi: 10.1021/acs.nanolett.5b04959

    5. [5]

      Chiba T, Hoshi K, Pu Y J. High Efficiency Perovskite Quantum-Dot Light-Emitting Devices by Effective Washing Process and Interfacial Energy Level Alignment[J]. ACS Appl Mater Interfaces, 2017,9(21):18054-18060. doi: 10.1021/acsami.7b03382

    6. [6]

      Shi T, Deng Y, Zheng X. Composition Engineering in Doctor-Blading of Perovskite Solar Cells[J]. Adv Energy Mater, 2017,7(18)1700302. doi: 10.1002/aenm.201700302

    7. [7]

      Jr P C, Savenije T J, Abdellah M. Organometal Halide Perovskite Solar Cell Materials Rationalized:Ultrafast Charge Generation, High and Microsecond-Long Balanced Mobilities, and Slow Recombination[J]. J Am Chem Soc, 2014,136(14):5189-5192. doi: 10.1021/ja412583t

    8. [8]

      LIU Jiao, LI Renzhi, DONG Xiandui. Research Progress of Perovskite Solar Cells[J]. Chinese J Appl Chem, 2016,33(5):489-503.  

    9. [9]

      Wang Q, Zhang X, Jin Z. Energy-Down-Shift CsPbCl3:Mn Quantum Dots for Boosting the Efficiency and Stability of Perovskite Solar Cells[J]. ACS Energy Lett, 2017,2(7):1479-1486. doi: 10.1021/acsenergylett.7b00375

    10. [10]

      Wang Y, Zhu Y, Huang J. CsPbBr3 Perovskite Quantum Dots-Based Monolithic Electrospun Fiber Membrane as an Ultrastable and Ultrasensitive Fluorescent Sensor in Aqueous Medium[J]. J Phys Chem Lett, 2016,7(21):4253-4258. doi: 10.1021/acs.jpclett.6b02045

    11. [11]

      Chen X, Hu H, Xia Z. CsPbBr3 Perovskite Nanocrystals as Highly Selective and Sensitive Spectrochemical Probes for Gaseous HCl Detection[J]. J Mater Chem C, 2016,5(2):309-313.  

    12. [12]

      Liu M, Zhong G, Yin Y. Aluminum-Doped Cesium Lead Bromide Perovskite Nanocrystals with Stable Blue Photoluminescence Used for Display Backlight[J]. Adv Sci, 2017,4(11)1700335. doi: 10.1002/advs.201700335

    13. [13]

      Protesescu L, Yakunin S, Bodnarchuk M I. Nanocrystals of Cesium Lead Halide Perovskites(CsPbX3, X=Cl, Br, and I):Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut[J]. Nano Lett, 2016,15(6):3692-3696.

    14. [14]

      Liu W, Lin Q, Li H. Mn2+-Doped Lead Halide Perovskite Nanocrystals with Dual-color Emission Controlled by Halide Content[J]. J Am Chem Soc, 2016,138(45):14954-14961. doi: 10.1021/jacs.6b08085

    15. [15]

      Balakrishnan S K, Kamat P V. Au-CsPbBr3 Hybrid Architecture. Anchoring Gold Nanoparticles on Cubic Perovskite Nanocrystals[J]. ACS Energy Lett, 2017,2(1):88-93. doi: 10.1021/acsenergylett.6b00592

    16. [16]

      Wei S, Yang Y, Kang X. Room-Temperature and Gram-Scale Synthesis of CsPbX3(X=Cl, Br, I) Perovskite Nanocrystals with 50~85% Photoluminescence Quantum Yields[J]. Chem Commun, 2016,52(45):7265-7268. doi: 10.1039/C6CC01500J

    17. [17]

      Yantara N, Bhaumik S, Yan F. Inorganic Halide Perovskites for Efficient Light-Emitting Diodes[J]. J Phys Chem Lett, 2015,6(21):4360-4364. doi: 10.1021/acs.jpclett.5b02011

    18. [18]

      Yoon H C, Kang H, Lee S. Study of Perovskite QD Down-Converted LEDs and Six-Color White LEDs for Future Displays with Excellent Color Performance[J]. ACS Appl Mater Interfaces, 2016,8(28):18189-18200. doi: 10.1021/acsami.6b05468

  • 加载中
    1. [1]

      Lihui Liu ,  Mingguang Li . 基于空穴传输层调控的钙钛矿发光二极管制备及表征综合实验设计. University Chemistry, 2026, 41(9): 337-346. doi: 10.12461/PKU.DXHX202509054

    2. [2]

      Runnan Yu ,  Xirui Liu ,  Xiangyuan Zheng ,  Bo Wen ,  Zhan'ao Tan . Undergraduate experimental design for preparing perovskite quantum dots via room-temperature ligand-assisted reprecipitation and investigating their luminescent properties. University Chemistry, 2026, 41(7): 290-299. doi: 10.12461/PKU.DXHX202506028

    3. [3]

      Nian LIU , Biao ZHENG , Kun WANG , Chunbao ZHENG , Qingyan HAN , Enjie HE , Saidong XUE . Synthesis and spectroscopic performance of double perovskite Li0.5La0.5MgSrWO6∶Mn4+ phosphors for plant growth lighting. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 129-140. doi: 10.11862/CJIC.20250069

    4. [4]

      Lin Song ,  Dourong Wang ,  Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107

    5. [5]

      Wenjuan SHI , Yuxuan LEI , Lei HOU , Yaoyu WANG . Synthesis, structure, and luminescence properties of trinucluear Cu(Ⅰ)-pyrazole complexes containing different substituent groups. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 543-550. doi: 10.11862/CJIC.20250270

    6. [6]

      Lixing ZHANG , Yaowen WANG , Xu HAN , Junhong ZHOU , Jinghui WANG , Liping LI , Guangshe LI . Research progress in the synthesis of fluorine-containing perovskites and their derivatives. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1689-1701. doi: 10.11862/CJIC.20250007

    7. [7]

      Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393

    8. [8]

      Tong WANG , Xuefang ZHU , Qi GAO , Hongbo ZHANG , Chao REN , Lixia GE . Luminescence and thermal stability of Tb3+-Eu3+ doped glass-ceramics containing Na8.12Y1.293Si6O18 crystal phase. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2237-2250. doi: 10.11862/CJIC.20250137

    9. [9]

      Wenwei Zeng ,  Qingyu Sun ,  Mengxiang Liang ,  Lirong Lin ,  Laiying Zhang . Unveiling Anti-Counterfeiting Secrets: Excitation-Dependent Luminescence in Sb3+-Doped Perovskite Materials. University Chemistry, 2026, 41(2): 375-384. doi: 10.12461/PKU.DXHX202503036

    10. [10]

      Yu SU , Xinlian FAN , Yao YIN , Lin WANG . From synthesis to application: Development and prospects of InP quantum dots. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2105-2123. doi: 10.11862/CJIC.20240126

    11. [11]

      Miaomiao He ,  Zhiqing Ge ,  Qiang Zhou ,  Jiaqing He ,  Hong Gong ,  Lingling Li ,  Pingping Zhu ,  Wei Shao . Exploring the Fascinating Realm of Quantum Dots. University Chemistry, 2024, 39(6): 231-237. doi: 10.3866/PKU.DXHX202310040

    12. [12]

      Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099

    13. [13]

      Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 100030-0. doi: 10.3866/PKU.WHXB202309045

    14. [14]

      Yixuan Gao ,  Lingxing Zan ,  Wenlin Zhang ,  Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091

    15. [15]

      Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs3Bi2X9 (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282

    16. [16]

      Peirui Qiu ,  Xianyun Zeng ,  Kehan Tang ,  Hongyun Chen ,  Guoran Li ,  Yang Liu . Synthesis and characterization of cesium lead halide perovskite quantum dots: a comprehensive chemistry experiment. University Chemistry, 2026, 41(6): 395-403. doi: 10.12461/PKU.DXHX202508073

    17. [17]

      Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn2+ doped quasi-two-dimensional perovskites (PEA)2PbyMn1-yBr4. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473

    18. [18]

      Longxiang LUO , Xiaoguo CAO , Yannan QIAN . Interface engineering with NH4PF6 for CsPbI2Br quantum dots for enhancing the performance of carbon-based all-inorganic perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 227-236. doi: 10.11862/CJIC.20250279

    19. [19]

      Binbin Liu , Yang Chen , Tianci Jia , Chen Chen , Zhanghao Wu , Yuhui Liu , Yuhang Zhai , Tianshu Ma , Changlei Wang . Hydroxyl-functionalized molecular engineering mitigates 2D phase barriers for efficient wide-bandgap and all-perovskite tandem solar cells. Acta Physico-Chimica Sinica, 2026, 42(1): 100128-0. doi: 10.1016/j.actphy.2025.100128

    20. [20]

      Zhen FAN , Jiayan WANG , Wenhao ZHU , Xiuchun ZHANG , Yang WANG , Hao LI , Zeyuan WANG , Songzhi ZHENG , Weihai SUN . Fabrication of CsPbBr3 perovskite solar cells using buried polyvinylidene fluorideinterface modification method. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2464-2478. doi: 10.11862/CJIC.20250191

Metrics
  • PDF Downloads(24)
  • Abstract views(2258)
  • HTML views(617)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return