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Citation: HUANG Guobin, LUO Dengfeng, ZHANG Maosheng. Preparation of CsPbX3(X=Cl, Br, I) Perovskite Quantum Dots with Multicolor and High Luminescence Efficiency and Its Application in Light Emitting Diode Devices[J]. Chinese Journal of Applied Chemistry, ;2019, 36(8): 932-938. doi: 10.11944/j.issn.1000-0518.2019.08.190016 shu

Preparation of CsPbX3(X=Cl, Br, I) Perovskite Quantum Dots with Multicolor and High Luminescence Efficiency and Its Application in Light Emitting Diode Devices

  • a.

    School of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou, Fujian 363000, China

  • b.

    Fujian Province University Key Laboratory of Analytical Science, Minnan Normal University, Zhangzhou, Fujian 363000, China

  • Corresponding author: ZHANG Maosheng, maoshengzhang@mnnu.edu.cn
  • Received Date: 17 January 2019
    Revised Date: 6 March 2019
    Accepted Date: 4 April 2019

    Fund Project: the Natural Science Foundation of Zhangzhou City, China ZZ2016J30the Natural Science Foundation of Fujian Province, China 2013J01062the Natural Science Foundation of Minnan Normal University Mk201721Science and Technology Projects of the Education Department, Fujian Province of China JK2017032Supported by the Natural Science Foundation of Fujian Province, China(No.2013J01062), Science and Technology Projects of the Education Department, Fujian Province of China(No.JK2017032), the Natural Science Foundation of Zhangzhou City, China(No.ZZ2016J30), the Natural Science Foundation of Minnan Normal University(No.Mk201721)

Figures(5)

  • Highly efficient and polychromatic luminescent CsPbX3 perovskite quantum dots(PQDs) were synthesized under room temperature. The entire reaction is very fast and simple. Polychromatic luminescence of CsPbX3 PQDs can be achieved by adjusting different halide compositions(Cl, Br, I). The as-prepared CsPbX3 PQDs have a cubic morphology with an average size about 10 nm. The photoluminescence of CsPbX3 PQDs has a characteristic of wide visible spectral region of 410~630 nm, narrow emission line-widths of 14~38 nm and quantum yields of 10%~90%. Finally, the CsPbX3 PQDs are successfully applied to prepare light emitting diode(LED) devices. At a constant voltage work for a long time, the emission color, intensity, and color coordinates of the LED device remain unchanged.
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    1. [1]

      Zhang F, Zhong H, Chen C. Brightly Luminescent and Color-Tunable Colloidal CH3NH3PbX3(X=Br, I, Cl) Quantum Dots:Potential Alternatives for Display Technology[J]. ACS Nano, 2015,9(4):4533-4542. doi: 10.1021/acsnano.5b01154

    2. [2]

      LOU Sunqi, XUAN Tongtong, YU Caiyan. Synthesis, Properties and Applications of Inorganic Halide Perovskite Nanocrystals[J]. Chinese J Appl Chem, 2016,33(9):977-993.  

    3. [3]

      Song J, Li J, Li X. Nanocrystals:Quantum Dot Light-Emitting Diodes Based on Inorganic Perovskite Cesium Lead Halides(CsPbX3)[J]. Adv Mater, 2015,27(44):7162-7167. doi: 10.1002/adma.201502567

    4. [4]

      Zhang X, Lin H, Huang H. Enhancing the Brightness of Cesium Lead Halide Perovskite Nanocrystal Based Green Light-Emitting Devices Through the Interface Engineering with Perfluorinated Ionomer[J]. Nano Lett, 2016,16(2):1415-1420. doi: 10.1021/acs.nanolett.5b04959

    5. [5]

      Chiba T, Hoshi K, Pu Y J. High Efficiency Perovskite Quantum-Dot Light-Emitting Devices by Effective Washing Process and Interfacial Energy Level Alignment[J]. ACS Appl Mater Interfaces, 2017,9(21):18054-18060. doi: 10.1021/acsami.7b03382

    6. [6]

      Shi T, Deng Y, Zheng X. Composition Engineering in Doctor-Blading of Perovskite Solar Cells[J]. Adv Energy Mater, 2017,7(18)1700302. doi: 10.1002/aenm.201700302

    7. [7]

      Jr P C, Savenije T J, Abdellah M. Organometal Halide Perovskite Solar Cell Materials Rationalized:Ultrafast Charge Generation, High and Microsecond-Long Balanced Mobilities, and Slow Recombination[J]. J Am Chem Soc, 2014,136(14):5189-5192. doi: 10.1021/ja412583t

    8. [8]

      LIU Jiao, LI Renzhi, DONG Xiandui. Research Progress of Perovskite Solar Cells[J]. Chinese J Appl Chem, 2016,33(5):489-503.  

    9. [9]

      Wang Q, Zhang X, Jin Z. Energy-Down-Shift CsPbCl3:Mn Quantum Dots for Boosting the Efficiency and Stability of Perovskite Solar Cells[J]. ACS Energy Lett, 2017,2(7):1479-1486. doi: 10.1021/acsenergylett.7b00375

    10. [10]

      Wang Y, Zhu Y, Huang J. CsPbBr3 Perovskite Quantum Dots-Based Monolithic Electrospun Fiber Membrane as an Ultrastable and Ultrasensitive Fluorescent Sensor in Aqueous Medium[J]. J Phys Chem Lett, 2016,7(21):4253-4258. doi: 10.1021/acs.jpclett.6b02045

    11. [11]

      Chen X, Hu H, Xia Z. CsPbBr3 Perovskite Nanocrystals as Highly Selective and Sensitive Spectrochemical Probes for Gaseous HCl Detection[J]. J Mater Chem C, 2016,5(2):309-313.  

    12. [12]

      Liu M, Zhong G, Yin Y. Aluminum-Doped Cesium Lead Bromide Perovskite Nanocrystals with Stable Blue Photoluminescence Used for Display Backlight[J]. Adv Sci, 2017,4(11)1700335. doi: 10.1002/advs.201700335

    13. [13]

      Protesescu L, Yakunin S, Bodnarchuk M I. Nanocrystals of Cesium Lead Halide Perovskites(CsPbX3, X=Cl, Br, and I):Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut[J]. Nano Lett, 2016,15(6):3692-3696.

    14. [14]

      Liu W, Lin Q, Li H. Mn2+-Doped Lead Halide Perovskite Nanocrystals with Dual-color Emission Controlled by Halide Content[J]. J Am Chem Soc, 2016,138(45):14954-14961. doi: 10.1021/jacs.6b08085

    15. [15]

      Balakrishnan S K, Kamat P V. Au-CsPbBr3 Hybrid Architecture. Anchoring Gold Nanoparticles on Cubic Perovskite Nanocrystals[J]. ACS Energy Lett, 2017,2(1):88-93. doi: 10.1021/acsenergylett.6b00592

    16. [16]

      Wei S, Yang Y, Kang X. Room-Temperature and Gram-Scale Synthesis of CsPbX3(X=Cl, Br, I) Perovskite Nanocrystals with 50~85% Photoluminescence Quantum Yields[J]. Chem Commun, 2016,52(45):7265-7268. doi: 10.1039/C6CC01500J

    17. [17]

      Yantara N, Bhaumik S, Yan F. Inorganic Halide Perovskites for Efficient Light-Emitting Diodes[J]. J Phys Chem Lett, 2015,6(21):4360-4364. doi: 10.1021/acs.jpclett.5b02011

    18. [18]

      Yoon H C, Kang H, Lee S. Study of Perovskite QD Down-Converted LEDs and Six-Color White LEDs for Future Displays with Excellent Color Performance[J]. ACS Appl Mater Interfaces, 2016,8(28):18189-18200. doi: 10.1021/acsami.6b05468

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