Citation: HUANG Guobin, LUO Dengfeng, ZHANG Maosheng. Preparation of CsPbX₃(X=Cl, Br, I) Perovskite Quantum Dots with Multicolor and High Luminescence Efficiency and Its Application in Light Emitting Diode Devices[J]. Chinese Journal of Applied Chemistry, ;2019, 36(8): 932-938. doi: 10.11944/j.issn.1000-0518.2019.08.190016 shu

Preparation of CsPbX₃(X=Cl, Br, I) Perovskite Quantum Dots with Multicolor and High Luminescence Efficiency and Its Application in Light Emitting Diode Devices

a.
School of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou, Fujian 363000, China
b.
Fujian Province University Key Laboratory of Analytical Science, Minnan Normal University, Zhangzhou, Fujian 363000, China

Corresponding author: ZHANG Maosheng, maoshengzhang@mnnu.edu.cn
Received Date: 17 January 2019
Revised Date: 6 March 2019
Accepted Date: 4 April 2019

Fund Project: the Natural Science Foundation of Zhangzhou City, China ZZ2016J30the Natural Science Foundation of Fujian Province, China 2013J01062the Natural Science Foundation of Minnan Normal University Mk201721Science and Technology Projects of the Education Department, Fujian Province of China JK2017032Supported by the Natural Science Foundation of Fujian Province, China(No.2013J01062), Science and Technology Projects of the Education Department, Fujian Province of China(No.JK2017032), the Natural Science Foundation of Zhangzhou City, China(No.ZZ2016J30), the Natural Science Foundation of Minnan Normal University(No.Mk201721)

Figures(5)

Highly efficient and polychromatic luminescent CsPbX₃ perovskite quantum dots(PQDs) were synthesized under room temperature. The entire reaction is very fast and simple. Polychromatic luminescence of CsPbX₃ PQDs can be achieved by adjusting different halide compositions(Cl, Br, I). The as-prepared CsPbX₃ PQDs have a cubic morphology with an average size about 10 nm. The photoluminescence of CsPbX₃ PQDs has a characteristic of wide visible spectral region of 410~630 nm, narrow emission line-widths of 14~38 nm and quantum yields of 10%~90%. Finally, the CsPbX₃ PQDs are successfully applied to prepare light emitting diode(LED) devices. At a constant voltage work for a long time, the emission color, intensity, and color coordinates of the LED device remain unchanged.
- perovskites,
- quantum dots,
- luminescence,
- room temperature synthesis method,
- light emitting diode
1. [1]
  Zhang F, Zhong H, Chen C. Brightly Luminescent and Color-Tunable Colloidal CH₃NH₃PbX₃(X=Br, I, Cl) Quantum Dots:Potential Alternatives for Display Technology[J]. ACS Nano, 2015,9(4):4533-4542. doi: 10.1021/acsnano.5b01154
2. [2]
  LOU Sunqi, XUAN Tongtong, YU Caiyan. Synthesis, Properties and Applications of Inorganic Halide Perovskite Nanocrystals[J]. Chinese J Appl Chem, 2016,33(9):977-993.
3. [3]
  Song J, Li J, Li X. Nanocrystals:Quantum Dot Light-Emitting Diodes Based on Inorganic Perovskite Cesium Lead Halides(CsPbX₃)[J]. Adv Mater, 2015,27(44):7162-7167. doi: 10.1002/adma.201502567
4. [4]
  Zhang X, Lin H, Huang H. Enhancing the Brightness of Cesium Lead Halide Perovskite Nanocrystal Based Green Light-Emitting Devices Through the Interface Engineering with Perfluorinated Ionomer[J]. Nano Lett, 2016,16(2):1415-1420. doi: 10.1021/acs.nanolett.5b04959
5. [5]
  Chiba T, Hoshi K, Pu Y J. High Efficiency Perovskite Quantum-Dot Light-Emitting Devices by Effective Washing Process and Interfacial Energy Level Alignment[J]. ACS Appl Mater Interfaces, 2017,9(21):18054-18060. doi: 10.1021/acsami.7b03382
6. [6]
  Shi T, Deng Y, Zheng X. Composition Engineering in Doctor-Blading of Perovskite Solar Cells[J]. Adv Energy Mater, 2017,7(18)1700302. doi: 10.1002/aenm.201700302
7. [7]
  Jr P C, Savenije T J, Abdellah M. Organometal Halide Perovskite Solar Cell Materials Rationalized:Ultrafast Charge Generation, High and Microsecond-Long Balanced Mobilities, and Slow Recombination[J]. J Am Chem Soc, 2014,136(14):5189-5192. doi: 10.1021/ja412583t
8. [8]
  LIU Jiao, LI Renzhi, DONG Xiandui. Research Progress of Perovskite Solar Cells[J]. Chinese J Appl Chem, 2016,33(5):489-503.
9. [9]
  Wang Q, Zhang X, Jin Z. Energy-Down-Shift CsPbCl₃:Mn Quantum Dots for Boosting the Efficiency and Stability of Perovskite Solar Cells[J]. ACS Energy Lett, 2017,2(7):1479-1486. doi: 10.1021/acsenergylett.7b00375
10. [10]
  Wang Y, Zhu Y, Huang J. CsPbBr₃ Perovskite Quantum Dots-Based Monolithic Electrospun Fiber Membrane as an Ultrastable and Ultrasensitive Fluorescent Sensor in Aqueous Medium[J]. J Phys Chem Lett, 2016,7(21):4253-4258. doi: 10.1021/acs.jpclett.6b02045
11. [11]
  Chen X, Hu H, Xia Z. CsPbBr₃ Perovskite Nanocrystals as Highly Selective and Sensitive Spectrochemical Probes for Gaseous HCl Detection[J]. J Mater Chem C, 2016,5(2):309-313.
12. [12]
  Liu M, Zhong G, Yin Y. Aluminum-Doped Cesium Lead Bromide Perovskite Nanocrystals with Stable Blue Photoluminescence Used for Display Backlight[J]. Adv Sci, 2017,4(11)1700335. doi: 10.1002/advs.201700335
13. [13]
  Protesescu L, Yakunin S, Bodnarchuk M I. Nanocrystals of Cesium Lead Halide Perovskites(CsPbX₃, X=Cl, Br, and I):Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut[J]. Nano Lett, 2016,15(6):3692-3696.
14. [14]
  Liu W, Lin Q, Li H. Mn²⁺-Doped Lead Halide Perovskite Nanocrystals with Dual-color Emission Controlled by Halide Content[J]. J Am Chem Soc, 2016,138(45):14954-14961. doi: 10.1021/jacs.6b08085
15. [15]
  Balakrishnan S K, Kamat P V. Au-CsPbBr₃ Hybrid Architecture. Anchoring Gold Nanoparticles on Cubic Perovskite Nanocrystals[J]. ACS Energy Lett, 2017,2(1):88-93. doi: 10.1021/acsenergylett.6b00592
16. [16]
  Wei S, Yang Y, Kang X. Room-Temperature and Gram-Scale Synthesis of CsPbX₃(X=Cl, Br, I) Perovskite Nanocrystals with 50~85% Photoluminescence Quantum Yields[J]. Chem Commun, 2016,52(45):7265-7268. doi: 10.1039/C6CC01500J
17. [17]
  Yantara N, Bhaumik S, Yan F. Inorganic Halide Perovskites for Efficient Light-Emitting Diodes[J]. J Phys Chem Lett, 2015,6(21):4360-4364. doi: 10.1021/acs.jpclett.5b02011
18. [18]
  Yoon H C, Kang H, Lee S. Study of Perovskite QD Down-Converted LEDs and Six-Color White LEDs for Future Displays with Excellent Color Performance[J]. ACS Appl Mater Interfaces, 2016,8(28):18189-18200. doi: 10.1021/acsami.6b05468
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Preparation of CsPbX3(X=Cl, Br, I) Perovskite Quantum Dots with Multicolor and High Luminescence Efficiency and Its Application in Light Emitting Diode Devices

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通讯作者: 陈斌, bchen63@163.com

Preparation of CsPbX₃(X=Cl, Br, I) Perovskite Quantum Dots with Multicolor and High Luminescence Efficiency and Its Application in Light Emitting Diode Devices