Citation: HEI Jiahui, YANG Lining, LI Jun. Synthesis and Photocatalysis of Metal Complexes with Schiff Base Derived from 2-Thiophene Carboxaldehyde and Ethylenediamine[J]. Chinese Journal of Applied Chemistry, ;2019, 36(8): 949-957. doi: 10.11944/j.issn.1000-0518.2019.08.180415 shu

Synthesis and Photocatalysis of Metal Complexes with Schiff Base Derived from 2-Thiophene Carboxaldehyde and Ethylenediamine

HEI Jiahui ^a,, ,
YANG Lining ^b ,
LI Jun ^c

a.
Aerospace Technology School, Xi'an 710100, China
b.
Department of Pharmacy, Medical University of Xi'an, Xi'an 710021, China
c.
College of Chemistry & Matericals Science, Northwest University, Xi'an 710069, China

Corresponding author: HEI Jiahui, heijiahui@126.com
Received Date: 29 December 2018
Revised Date: 7 March 2019
Accepted Date: 5 May 2019

Fund Project: Supported by the National Natural Science Foundation of China(No.21671158)the National Natural Science Foundation of China 21671158

Figures(13)

The ligand N, N'-bis(thiophenaldehyde) ethylenediamine(L) obtained by the condensation between 2-thiophene carboxaldehyde and ethylenediamine were used for synthesis of new complexes[ZnLCl₂](1) and[NiL'(NO₃)₂](2)(L'-thiophenaldehyde-ethylenediamine). The structures of these complexes and ligand were characterized by single crystal X-ray analysis. These compounds were used for modifying the surface of TiO₂. The obtained photocatalysts(L-TiO₂, 1-TiO₂, 2-TiO₂) were characterized by IR spectra, UV-Vis diffuse reflectance spectroscopy and XRD. Their photocatalytic activities in the photodegradation of 4-nitrophenol(4-NP) and Rhodamine B(RhB) were evaluated under UV-visible light irradiation. The results revealed higher photocatalytic activities of 1-TiO₂ and 2-TiO₂ than that of bare TiO₂. In addition, the degradation rate can reach above 90%.
- 2-thiophenealdehyde,
- Schiff base,
- metal complexes,
- titanium dioxide,
- photocatalytic degradation
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