Citation: QIN Sinan, TANG Luhua, GAO Wenhui. Cyhalothrin Molecularly Imprinted Electrochemical Sensor: Preparation, Performance and Application[J]. Chinese Journal of Applied Chemistry, ;2019, 36(8): 958-967. doi: 10.11944/j.issn.1000-0518.2019.08.180414 shu

Cyhalothrin Molecularly Imprinted Electrochemical Sensor: Preparation, Performance and Application

Research Center for Fermentation Engineering of Hebei, College of Biological Science and Engineering, Hebei University of Science and Technology, Shijiazhuang 050000, China

Corresponding author: GAO Wenhui, wenhuigao@126.com
Received Date: 28 December 2018
Revised Date: 4 March 2019
Accepted Date: 3 April 2019

Fund Project: Supported by Science and Technology Planning Project of Hebei Province(No.16275503D), Scientific and Technological Research and Development Project of Shijiazhuang City(No.181490372A)Scientific and Technological Research and Development Project of Shijiazhuang City 181490372AScience and Technology Planning Project of Hebei Province 16275503D

Figures(9)

A novel molecularly imprinted electrochemical sensor with specific recognition ability to template molecules and its structural analogs were prepared by electro-polymerization. Cyhalothrin was used as the template molecule and o-phenylenediamine and o-aminophenol as composite functional monomers. The imprinting effect and analytical performance of the sensor were characterized by cyclic voltammetry and square wave voltammetry. A rapid analysis method was established for determination of cyhalothrin residues in agricultural products. Under the optimal conditions, the linear relationship of cyhalothrin was good within the concentration range of 1.0×10^-7~1.0×10^-5 mol/L, and the detection limit(S/N=3) was 3.0×10^-8 mol/L, the average recoveries of spiked sample were between 84.8% and 94.7%, and the relative standard deviations(RSDs) were 1.1%~4.8%(n=5). This sensor has advantages of simple operation, detection speediness, high sensitivity, low cost, good selectivity, stability and reproducibility, which provides it a good application prospect.
- cyhalothrin,
- molecular imprinting polymer,
- electrochemical sensor,
- rapid analysis
1. [1]
  CHEN Linglong. Residues and Environmental Behavior of Lambda-Cyhalothrin in Tea and Soil[D]. Changsha: Hunan Normal University, 2011(in Chinese).
2. [2]
  YU Chun, LI Jun, YANG Guanghong. Acute Toxicity Study of 2.5% Lambda-Cyhalothrin Emulsion[J]. Guizhou Med J, 2013,37(1):66-68. doi: 10.3969/j.ISSN.1000-744X.2013.01.028
3. [3]
  Maund S J, Hamer J, Warinton J S. Aquatic Ecotoxicology of the Pyrethroid Insecticide Lambda-Cyhalothrin:Considerations for Higher-Tier Aquatic Risk Assessment[J]. Pest Manage Sci, 2015,54(4):408-417.
4. [4]
  GAO Jingpeng, CHEN Hanming, MA Yajun. Establishment of Diagnostic Doses of Three Pyrethroid Insecticides for Detecting Resistance in Aedes albopictus(Diptera:Culicidae) in China[J]. Acta Entomol Sin, 2018,61(1):18-24. doi: 10.3969/j.issn.1005-0507.2018.01.004
5. [5]
  Daniel B K N, Norbert N T, Francis N. Ecotoxicological Effects of Imidacloprid and Lambda-Cyhalothrin(Insecticide) on Tadpoles of the African Common Toad, Amietophrynus regularis(Reuss, 1833)(Amphibia:Bufonidae)[J]. Ital J Sci Eng, 2017,1(2):49-53.
6. [6]
  Rodrigues E N L, Mendonca Jr M D S M, Fritz L L. Effect of the Insecticide Lambda-Cyhalothrin on Rice Spider Populations in Southern Brazil[J]. Zoologia, 2013,30(6):615-622. doi: 10.1590/S1984-46702013005000010
7. [7]
  Boonchiangma S, Ngeontae W, Srijaranai S. Determination of Six Pyrethroid Insecticides in Fruit Juice Samples Using Dispersive Liquid-Liquid Microextraction Combined with High Performance Liquid Chromatography[J]. Talanta, 2012,88(15):209-215.
8. [8]
  Jiang C, Sun Y, Yu X. Liquid-Solid Extraction Coupled with Magnetic Solid-Phase Extraction for Determination of Pyrethroid Residues in Vegetable Samples by Ultra Fast Liquid Chromatography[J]. Talanta, 2013,114(10):167-175.
9. [9]
  Yang G L, Wang W, Liang S M. Pesticide Residues in Bayberry(Myrica rubra) and Probabilistic Risk Assessment for Consumers in Zhejiang, China[J]. J Integr Agric, 2017,16(9):2101-2109. doi: 10.1016/S2095-3119(16)61600-3
10. [10]
  LIU Yongxia. Degradation Dynamics and Residual Amount of Cyhalothrin in Ya Pear Fruit[D]. Baoding: Hebei Agricultural University, 2008(in Chinese).
11. [11]
  Li Y, Dong W F, Wang X. Determination of 9 Synthetic Pyrethroids in Brown Rice by Gas Chromatography-Mass Spectrometry[J]. J Food Safe Food Qual, 2015,6(1):65-71.
12. [12]
  Chen G F, Liu F, Zhang X B. Determination of Thiamethoxam and Lambda-Cyhalothrin Residue in Wheat Field by GC-MS/MS[J]. Mod Agrochem, 2015,14(5):39-41.
13. [13]
  Xue C, Han Q, Wang Y. Amperometric Detection of Dopamine in Human Serum by Electrochemical Sensor Based on Gold Nanoparticles Doped Molecularly Imprinted Polymers[J]. Biosens Bioelectron, 2013,49(22):199-203.
14. [14]
  Sooraj M P, Nair A S, Pillai S C. CuNPs Decorated Molecular Imprinted Polymer on MWCNT for the Electrochemical Detection of l-DOPA[J]. Arab J Chem, 2018.
15. [15]
  GAO Wenhui, PANG Jun, WANG Jiaojiao. Preparation and Recognition Performance of Biphenyl Triazole Alcohol Molecularly Imprinted Electrochemical Sensor[J]. Mod Food Sci Technol, 2015,31(1):96-100.
16. [16]
  ZHAO Lingyu, GAO Lin, PANG Jun. Preparation and Application of Molecularly Imprinted Electrochemical Sensor for the Detection of Tetramethrin and Its Performance[J]. Food Sci, 2017,38(8):283-289.
17. [17]
  TAN Xuecai, MAI Zhibin, ZOU Xiaoyong. Study on the Determination of Chitosan by Using Alizarin Red as an Electrochemical Activity Probe[J]. J Instrum Anal, 2005,24(6):32-36. doi: 10.3969/j.issn.1004-4957.2005.06.008
18. [18]
  CHI Damin, SU Liqiang, DENG Qianshan. Research Progress in Molecular Selection Methods for Molecular Imprinting Functions[J]. Chem J, 2009,23(12):55-57. doi: 10.3969/j.issn.1002-154X.2009.12.016
19. [19]
  WANG Shuaishuai, ZHU Qiujin. Ultraviolet Spectrum Research of the Preparation Ratio of Template Molecule in Histamine Molecularly Imprinted Polymers[J]. China Brew, 2016,35(11):149-152. doi: 10.11882/j.issn.0254-5071.2016.11.031
20. [20]
  SHI Yang, LIU Junbo, TANG Shanshan. Molecular Imprinted Interaction Between Salbutamol and Each of Different Functional Monomers[J]. J Jilin Univ(Sci Ed), 2014,52(05):1059-1066.
21. [21]
  MA Liang, DAI Fangfang, ZHOU Yao. Development of a Type Ⅱ Pyrethroid Molecularly Imprinted Membrane Based on Electrochemical Technology[J]. Mod Food Sci Technol, 2016,32(2):121-129.
22. [22]
  ZHAO Lingyu, WANG Jiaojiao, GAO Wenhui. Preparation of Cyhalothrin Molecularly Imprinted Solid-Phase Extraction Membrane and Its Application in Food Detection[J]. Chem Bull, 2019,82(1):80-86.
1. [1]
  Jiarong Feng , Yejie Duan , Chu Chu , Dezhen Xie , Qiu'e Cao , Peng Liu . Preparation and Application of a Streptomycin Molecularly Imprinted Electrochemical Sensor: A Suggested Comprehensive Analytical Chemical Experiment. University Chemistry, 2024, 39(8): 295-305. doi: 10.3866/PKU.DXHX202401016
2. [2]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
3. [3]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
4. [4]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
5. [5]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
6. [6]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
7. [7]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021
8. [8]
  Min Gu , Huiwen Xiong , Liling Liu , Jilie Kong , Xueen Fang . Rapid Quantitative Detection of Procalcitonin by Microfluidics: An Instrumental Analytical Chemistry Experiment. University Chemistry, 2024, 39(4): 87-93. doi: 10.3866/PKU.DXHX202310120
9. [9]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
10. [10]
  Meiqing Yang , Lu Wang , Haozi Lu , Yaocheng Yang , Song Liu . Recent Advances of Functional Nanomaterials for Screen-Printed Photoelectrochemical Biosensors. Acta Physico-Chimica Sinica, 2025, 41(2): 100018-. doi: 10.3866/PKU.WHXB202310046
11. [11]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
12. [12]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
13. [13]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
14. [14]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
15. [15]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022
16. [16]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
17. [17]
  Qiaoqiao BAI , Anqi ZHOU , Xiaowei LI , Tang LIU , Song LIU . Construction of pressure-temperature dual-functional flexible sensors and applications in biomedicine. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2259-2274. doi: 10.11862/CJIC.20240128
18. [18]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
19. [19]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
20. [20]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(379)
HTML views(100)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142