Citation: FAN Tianbo, CHEN Si, JIANG Yu, CAI Xun, KANG Ping, Li LI, ZHANG Li, LIU Yunyi. Processing and Properties of Rubber Modified by Coated Heavy Calcium Powder as the Filler[J]. Chinese Journal of Applied Chemistry, ;2019, 36(7): 790-797. doi: 10.11944/j.issn.1000-0518.2019.07.180326 shu

Processing and Properties of Rubber Modified by Coated Heavy Calcium Powder as the Filler

FAN Tianbo ^a ,
CHEN Si ^a ,
JIANG Yu ^a ,
CAI Xun ^b ,
KANG Ping ^c ,
Li LI ^d ,
ZHANG Li ^e ,
LIU Yunyi ^a,,

a.
Liaoning Provincial Key Laboratory of Chemical Application Technology, College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China
b.
Zhonghua Quanzhou Petrochemical Company Limited, Quan zhou, Fujian 362103, China
c.
College of Materials Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China
d.
College of Computer Science and Technology, Shenyang University of Chemical Technology, Shenyang 110142, China
e.
Shenyang Research Institute of Chemical Industry, Shenyang 110021, China

Corresponding author: LIU Yunyi, liuyunyia@163.com
Received Date: 11 October 2018
Revised Date: 9 January 2019
Accepted Date: 22 March 2019

Fund Project: the Liaoning Provincial Innovation Team Support Program 2013010Supported by the National Natural Science Foundation of China(No.61102041), the Liaoning Provincial Innovation Team Support Program(No.2013010), the National Science and Technology Support Program(No.2013BAB09B01), the Liaoning Provincial Department of Education Project(No.L2013169), the Liaoning Provincial Fine Chemicals Collaborative Innovation Center Project, and the Liaoning Province Natural Fund(No.201602582)the Liaoning Provincial Department of Education Project L2013169the National Science and Technology Support Program 2013BAB09B01the National Natural Science Foundation of China 61102041the Liaoning Provincial Fine Chemicals Collaborative Innovation Center Project, and the Liaoning Province Natural Fund 201602582

Figures(6)

Heavy calcium powder is widely used as a filler in rubber processing, but the interface with the rubber material is poorly combined due to high polarity and poor dispersibility of powders, which affects the mechanical properties such as tensile strength and elongation at break of the rubber product. In this paper, the precipitation method is used to form calcium carbonate which is directly crystallized on the surface of heavy calcium powder particles in CaCl₂-H₂O-NH₃-CO₂ system. If n(CaCl₂):n(heavy calcium powder)=1:100, 5:100, 10:100 coated calcium powder are filled into natural rubber and recycled rubber, the mechanical properties of rubber are some what improved compared to rubber filled with uncoated calcium powder. The filling amount is 8.5% and 15%, in the mechanical properties such as hardness and modulus, the coated calcium powder rubber product is obviously superior to the light calcium powder rubber product; when it comes to 5% or 8.5%, the tensile strength and elongation at break of the coated heavy calcium rubber product are close to that of silica, and the hardness is higher than rubber products filled with silica.
- heavy calcium powder,
- coating,
- light calcium powder,
- rubber,
- mechanical properties
1. [1]
  CHEN Yunxi, WU Wenbiao, CHEN Shuming. Reinforcing Properties of Inorganic Fillers in Rubber from Sericite Powder[J]. Rubber Sci Tech, 2004(5):6-9.
2. [2]
  PENG Limin. Effect of Lignin Combined with Inorganic Filler on Compression Set of Nitrile Rubber[D]. Hunan Normal University, 2016(in Chinese).
3. [3]
  LV Bailing. Application of Calcium Carbonate in Rubber Industry[J]. China Rubber/Plast Technol Equip, 2003,29(8):28-30. doi: 10.3969/j.issn.1009-797X.2003.08.008
4. [4]
  LI Xiaoyun. Surface Modification of Heavy Calcium Carbonate and Its Application in Polymers[D]. Lanzhou University, 2008(in Chinese).
5. [5]
  LIU Yin, WU Yan, YANG Yufen. Study on Nano-coated Heavy Calcium Carbonate Used as Papermaking Filler[J]. CN PPR, 2013,32(2):16-21. doi: 10.3969/j.issn.0254-508X.2013.02.004
6. [6]
  FAN Shimin. Research and Application of Surface Nano-modification Technology of Mineral Powder[D]. Beijing: Tsinghua University, 2004(in Chinese).
7. [7]
  WANG Huiping. Coating Modification of Heavy Calcium Carbonate by Starch and Its Application in Papermaking[D]. Shanxi University of Science and Technology, 2010(in Chinese).
8. [8]
  GAI Guosheng, YANG Yufen, FAN Shimin, et al. Surface Modification Technology and Development of Heavy Calcium Carbonate[C]//National Powder Engineering Conference and Related Equipment and Product Exchange Conference Papers, 2003(in Chinese).
9. [9]
  DING Yang, REN Yangyang, WANG Dan. Study on Controllable Synthesis of Calcium Carbonate in Microemulsion System[J]. J Inorg Salts, 2017,49(6):33-36.
10. [10]
  Bertora A, Castellano M, Marsano E. A New Modifier for Silica in Reinforcing SBR Elastomers for the Tyre Industry[J]. Macromol Mater Eng, 2011,296(5):455-464. doi: 10.1002/mame.v296.5
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沈阳化工大学材料科学与工程学院沈阳 110142