Citation: HAO Bin, ZHAO Wenwu, YU Jianyuan, LIU Jinqiang, LIU Jian, DONG Xiuzhen, WANG Xiuwen. Preparation and Luminescence Property of Ba_5-3x/2B₄O₁₁: xEu³⁺ Phosphor[J]. Chinese Journal of Applied Chemistry, ;2019, 36(5): 548-553. doi: 10.11944/j.issn.1000-0518.2019.05.180276 shu

Preparation and Luminescence Property of Ba_5-3x/2B₄O₁₁: xEu³⁺ Phosphor

HAO Bin ^a,b ,
ZHAO Wenwu ^b,c ,
YU Jianyuan ^b,c ,
LIU Jinqiang ^b,c ,
LIU Jian ^b,c,, ,
DONG Xiuzhen ^b,c ,
WANG Xiuwen ^b,c

a.
Scientific Technology Service, Tangshan College, Tangshan, Hebei 063000, China
b.
Key Laboratory of Micro-nano Materials Preparation and Application of Tangshan City, Tangshan College, Tangshan, Hebei 063000, China
c.
Department of Environmental and Chemical Engineering, Tangshan College, Tangshan, Hebei 063000, China

Corresponding author: LIU Jian, sword_liujian@aliyun.com
Received Date: 27 August 2018
Revised Date: 9 October 2018
Accepted Date: 29 November 2018

Fund Project: Tangshan Science and Technology Research and Development Program 17130259aSupported by the Youth Top Talent Program of Hebei Education Department (No.BJ2018203), Tangshan Science and Technology Research and Development Program(No.17130259a)the Youth Top Talent Program of Hebei Education Department BJ2018203

Figures(7)

The phosphors, Ba_5-3x/2B₄O₁₁:xEu³⁺(x = 0.02~0.22), were synthesized by high-temperature solid-state reaction method. The luminescence property of Ba_5-3x/2B₄O₁₁:xEu³⁺ was studied in this paper. The phase and surface topographies of as-prepared samples were characterized by X-ray diffraction(XRD) and scanning electron microscope(SEM). This phosphor can be effectively excited at 393 nm and the emission peaks are located at 596 nm, 621 nm, 657 nm and 706 nm corresponding to the ⁵D₀-⁷F_J(J = 1, 2, 3, 4) transition of Eu³⁺ ions, respectively. Therein the ⁵D₀-⁷F₂ electric dipole transition of Eu³⁺ ions, which locates at 621 nm, is the strongest wave crest. Investigation of Eu³⁺ content-dependent emission spectra indicates that x = 0.16 is the optimum doping content of Eu³⁺ ions in the Ba₅B₄O₁₁ host.
- high-temperature solid-state reaction method,
- luminescence property,
- borate,
- Ba_5-3x/2B₄O₁₁:xEu³⁺,
- rare earth doping
1. [1]
  Rohwer L S, Srivastava A M. Development of Phosphors for LEDS[J]. Electrochem Soc Interface, 2003,12(2):36-40.
2. [2]
  Pawar P P, Munishwar S R, Gedamr S. Physical and Optical Properties of Dy³⁺/Pr³⁺ Co-doped Lithium Borate Glasses for W-LED[J]. J Alloys Compd, 2016,660:347-355. doi: 10.1016/j.jallcom.2015.11.087
3. [3]
  Sun X, Zhang C, Wu J. A Novel Blue-Emitting KCa₄(BO₃)₃:Ce³⁺ Phosphor for White LED Application[J]. J Rare Earths, 2016,34(6):571-577. doi: 10.1016/S1002-0721(16)60063-7
4. [4]
  Nakamura S, Mukai T, Senoh M. Candela-Class High-Brightness InGaN/AlGaN Double-Heterostructure Blue-Light-Emitting Diodes[J]. Appl Phys Lett, 1994,64(13):1687-1689. doi: 10.1063/1.111832
5. [5]
  Lee S P, Chan T S, Chen T M. Novel Reddish-Orange-Emitting BaLa₂Si₂S₈:Eu(2+) Thiosilicate Phosphor for LED Lighting[J]. ACS Appl Mater Interfaces, 2015,7(1):40-44.
6. [6]
  Jang H S, Won Y, Jeon D Y. Improvement of Electroluminescent Property of Blue LED Coated with Highly Luminescent Yellow-Emitting Phosphors[J]. Appl Phys B, 2009,95(4):715-720. doi: 10.1007/s00340-009-3484-1
7. [7]
  Li J, Yan H, Yan F. Luminescence Properties of a Novel Orange Red CaBi₂B₂O₇:Eu³⁺ Phosphor for Near-UV Pumped W-LEDs[J]. Optik-Int J Light Electron Opt, 2016,127:4541-4544. doi: 10.1016/j.ijleo.2016.01.155
8. [8]
  Zhang Q H, Wang J, Zhang M. Luminescence Properties of Sm³⁺ Doped Bi₂ZnB₂O₇[J]. J Rare Earths, 2006,24(4)392.
9. [9]
  Wu L W, Zhang F, Wu L. Structure Refinement and One-Center Luminescence of Eu³⁺ Activated ZnBi₂B₂O₇ under UV Excitation[J]. J Alloys Compd, 2015,648:500-506. doi: 10.1016/j.jallcom.2015.06.187
10. [10]
  WU Dongni, CUI Ruirui, GONG Xinyong. Synthesis and Photoluminescence Properties of NaLa_0.7(MoO₄)_2-x(WO₄)_x:0.3Eu³⁺ Novel Red Phosphors[J]. Chinese J Lumin, 2016,37(3):374-279.
11. [11]
  SHI Wenjie, CHEN Songling, CHANG Jiazhong. Synthesis and Luminescent Properties of KAlSiO₄:Eu³⁺ Phosphor[J]. J Chinese Soc Rare Earths, 2014,32(2):164-169.
12. [12]
  Kokh A E, Kononova N G, Bekker T B. BaO-BaB₂O₄ Phase Diagram[J]. Russ J Inorg Chem, 2005,55(11):1749-1753.
13. [13]
  Qiao X B, Cheng Y, Qin L. Coprecipitation Synthesis, Structure and Photoluminescence Properties of Eu³⁺-Doped Sodium Barium Borate[J]. J Alloys Compd, 2014,617:946-951. doi: 10.1016/j.jallcom.2014.08.050
14. [14]
  QIU Guiming, XU Chengke, HUANG Chong. Synthesis and Luminescent Characteristic of BaMoO₄:Eu³⁺[J]. Spectrosc Spectr Anal, 2011,31(5):1200-1203. doi: 10.3964/j.issn.1000-0593(2011)05-1200-04
15. [15]
  ZHANG Qingxia, LONG Dandan, ZHANG Fan. Influence of Bi³⁺ Doping on Properties of CaMoO₄:Eu³⁺ Phosphors[J]. Spectrosc Spectr Anal, 2013,33(7):1758-1762. doi: 10.3964/j.issn.1000-0593(2013)07-1758-05
16. [16]
  HUANG Hongsheng, JIN Huafeng, YUAN Guanghui. Synthesis and Luminescent Properties of Nano/Micro SrB₆O₁₀·5H₂O:Eu³⁺[J]. Chinese J Lumin, 2014,35(10):1176-1181.
17. [17]
  WU Dongni, CUI Ruirui, GONG Xinyong. Synthesis and Photoluminescence Properties of NaLa_0.7(MoO₄)_2-x(WO₄)_x:0.3Eu³⁺ Novel Red Phosphors[J]. Chinese J Lumin, 2016,37(3):274-279.
18. [18]
  Tanner P A. Some Misconceptions Concerning the Electronic Spectra of Tri-positive Europium and Cerium[J]. Chem Soc Rev, 2013,42(12):5090-5101. doi: 10.1039/c3cs60033e
19. [19]
  Binnemans K. Interpretation of Europium(Ⅲ) Spectra[J]. Coord Chem Rev, 2015,295:1-45. doi: 10.1016/j.ccr.2015.02.015
20. [20]
  LV Xingdong, SHU Wan'gen. Formation and Roles of Point Defects in SrAl₂O₄:Eu²⁺, Dy³⁺ Phosphors[J]. Chinese J Inorg Chem, 2006,22(5):809-812.
21. [21]
  Ping Y, Meng K L, Chun F S. Photoluminescence Properties of Alkaline Metallic Ions Doped Sol-Gel Silica Glasses[J]. Mater Sci Eng B, 2002,90(1/2):99-102.
1. [1]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
2. [2]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
3. [3]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
4. [4]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
5. [5]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
6. [6]
  Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu³⁺-doped CaLaGaO₄ red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242
7. [7]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
8. [8]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
9. [9]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
10. [10]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
11. [11]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342
12. [12]
  Jinghan ZHANG , Guanying CHEN . Progress in the application of rare-earth-doped upconversion nanoprobes in biological detection. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2335-2355. doi: 10.11862/CJIC.20240249
13. [13]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
14. [14]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
15. [15]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
16. [16]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
17. [17]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
18. [18]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
19. [19]
  Qianqian Liu , Xing Du , Wanfei Li , Wei-Lin Dai , Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb₂O₆/Nitrogen-Enriched C₃N₅ S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016
20. [20]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(931)
HTML views(195)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Luminescence Property of Ba5-3x/2B4O11: xEu3+ Phosphor

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Luminescence Property of Ba_5-3x/2B₄O₁₁: xEu³⁺ Phosphor