Citation: HAO Bin, ZHAO Wenwu, YU Jianyuan, LIU Jinqiang, LIU Jian, DONG Xiuzhen, WANG Xiuwen. Preparation and Luminescence Property of Ba_5-3x/2B₄O₁₁: xEu³⁺ Phosphor[J]. Chinese Journal of Applied Chemistry, ;2019, 36(5): 548-553. doi: 10.11944/j.issn.1000-0518.2019.05.180276 shu

Preparation and Luminescence Property of Ba_5-3x/2B₄O₁₁: xEu³⁺ Phosphor

HAO Bin ^a,b ,
ZHAO Wenwu ^b,c ,
YU Jianyuan ^b,c ,
LIU Jinqiang ^b,c ,
LIU Jian ^b,c,, ,
DONG Xiuzhen ^b,c ,
WANG Xiuwen ^b,c

a.
Scientific Technology Service, Tangshan College, Tangshan, Hebei 063000, China
b.
Key Laboratory of Micro-nano Materials Preparation and Application of Tangshan City, Tangshan College, Tangshan, Hebei 063000, China
c.
Department of Environmental and Chemical Engineering, Tangshan College, Tangshan, Hebei 063000, China

Corresponding author: LIU Jian, sword_liujian@aliyun.com
Received Date: 27 August 2018
Revised Date: 9 October 2018
Accepted Date: 29 November 2018

Fund Project: Tangshan Science and Technology Research and Development Program 17130259aSupported by the Youth Top Talent Program of Hebei Education Department (No.BJ2018203), Tangshan Science and Technology Research and Development Program(No.17130259a)the Youth Top Talent Program of Hebei Education Department BJ2018203

Figures(7)

The phosphors, Ba_5-3x/2B₄O₁₁:xEu³⁺(x = 0.02~0.22), were synthesized by high-temperature solid-state reaction method. The luminescence property of Ba_5-3x/2B₄O₁₁:xEu³⁺ was studied in this paper. The phase and surface topographies of as-prepared samples were characterized by X-ray diffraction(XRD) and scanning electron microscope(SEM). This phosphor can be effectively excited at 393 nm and the emission peaks are located at 596 nm, 621 nm, 657 nm and 706 nm corresponding to the ⁵D₀-⁷F_J(J = 1, 2, 3, 4) transition of Eu³⁺ ions, respectively. Therein the ⁵D₀-⁷F₂ electric dipole transition of Eu³⁺ ions, which locates at 621 nm, is the strongest wave crest. Investigation of Eu³⁺ content-dependent emission spectra indicates that x = 0.16 is the optimum doping content of Eu³⁺ ions in the Ba₅B₄O₁₁ host.
- high-temperature solid-state reaction method,
- luminescence property,
- borate,
- Ba_5-3x/2B₄O₁₁:xEu³⁺,
- rare earth doping
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Preparation and Luminescence Property of Ba_5-3x/2B₄O₁₁: xEu³⁺ Phosphor