Citation: YAN Bing, XIONG Wenxu, ZHENG Shibing, ZHANG Xueqian, HUANG Weiwei. Single-Walled Carbon Nanotubes Enhanced Electrochemical Performance of High-Capacity Organic Cathode Composites Calix[4]quinone/Mesporous Carbon CMK-3 for Li-Ion Batteries[J]. Chinese Journal of Applied Chemistry, ;2019, 36(5): 554-563. doi: 10.11944/j.issn.1000-0518.2019.05.180231 shu

Single-Walled Carbon Nanotubes Enhanced Electrochemical Performance of High-Capacity Organic Cathode Composites Calix[4]quinone/Mesporous Carbon CMK-3 for Li-Ion Batteries

College of Environmental and Chemical Engineering, Yan Shan University, Qinhuangdao, Hebei 066004, China

Corresponding author: HUANG Weiwei, huangweiwei@ysu.edu.cn
Received Date: 2 July 2018
Revised Date: 13 September 2018
Accepted Date: 9 October 2018

Fund Project: the Natural Science Foundation of Hebei Province of China B2015203124the National Natural Science Foundation of China 21403187Supported by the National Natural Science Foundation of China(No.21403187), the Natural Science Foundation of Hebei Province of China(No.B2015203124)

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The dissolution of calix[4]quinone(C4Q) in electrolytes can be inhibited by the C4Q/CMK-3(mesoporous carbon) nanocomposites prepared through perfusion method, but the electrochemical performance of the nanocomposites needs to be further improved. We prepared a serious of C4Q/CMK-3/SWCNTs(single-walled carbon nanotubes) composites with different ratio by deaerating-stirring method. In these composites, SWCNTs substituted conductive carbon blacks Super-P of the original C4Q/CMK-3 composites, which also reduced the content of CMK-3. SEM and electrochemical tests are conducted to investigate the relation of the morphology and electrochemical performance that cased by SWCNTs. The results show that the optimum mass ratio was m(C4Q):m(CMK-3):m(SWCNTs)=(1:1:1), which shows a capacity retention of 55% after 100 cycles at 0.1 C. Even at 1 C, the discharge capacity is still 260 mA·h/g. The significant improvement in the electrochemical performance could be ascribed to the formation of three-dimensional conductive network by SWCNTs.
- single-walled carbon nanotubes,
- calix[4]quinone,
- C4Q/CMK-3,
- lithium-ion batteries
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