Citation: YE Lin, ZHANG Shaofeng, MIN Jiakang, MA Li, TANG Tao. Poly(n-butyl methacrylate)/Polystyrene Blend Compatibilized by the Diels-Alder Reaction of Furan/Maleimide[J]. Chinese Journal of Applied Chemistry, ;2019, 36(4): 451-458. doi: 10.11944/j.issn.1000-0518.2019.04.180300 shu

Poly(n-butyl methacrylate)/Polystyrene Blend Compatibilized by the Diels-Alder Reaction of Furan/Maleimide

YE Lin ^a,b ,
ZHANG Shaofeng ^a,b ,
MIN Jiakang ^a,b ,
MA Li ^a,, ,
TANG Tao ^a,,

a.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Acdemy of Sciences, Changchun 130022, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: MA Li, mali@ciac.ac.cn TANG Tao, ttang@ciac.ac.cn
Received Date: 10 September 2018
Revised Date: 28 September 2018
Accepted Date: 29 September 2018

Fund Project: Supported by the National Natural Science Foundation of China(No.51233005, No.51573179, No.21304089)the National Natural Science Foundation of China 51573179the National Natural Science Foundation of China 51233005the National Natural Science Foundation of China 21304089

Figures(9)

The compatibilization of immiscible poly(n-butyl methacrylate)(PBMA)/polystyrene(PS) blends was realized by the reaction of furan and maleimide groups. The furan-functionalized poly(n-butyl methacrylate)(P(BMA-co-FMA)) and maleimide-functionalized polystyrene(MPS) was synthesized by copolymerization and post-polymerization modification, respectively. The Diels-Alder reaction of the functionalized polymers and their blend were confirmed by nuclear magnetic resonance spectroscopy(NMR). The reaction of furan and maleimide dramatically promoted the compatibility of two components, confirmed by a homogeneous microstructure evidenced by transmission electron microscopy(TEM) observation and by the presence of a single glass transition temperature in the (P(BMA-co-FMA)/MPS blends. The properties of the blend materials could be controlled conveniently by adjusting the reaction time, and the blends transformed from tough material to brittle material gradually as the reaction processed, which was confirmed by the three point bending test.
- poly(butyl methacrylate,
- polystyrene,
- polymer blend,
- compatibilization,
- diels-Alder reaction,
- furan/maleimide
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