Citation: XING Chenli, WANG Jing, ZHANG Zhaohui, XIE Dandan, LÜ Piaopiao. Multiple Metal Ion Imprinted Electrochemical Sensor with Enhanced Sensitivity by Graphene Oxide-C₆₀ Composite[J]. Chinese Journal of Applied Chemistry, ;2019, 36(3): 341-348. doi: 10.11944/j.issn.1000-0518.2019.03.180160 shu

Multiple Metal Ion Imprinted Electrochemical Sensor with Enhanced Sensitivity by Graphene Oxide-C₆₀ Composite

a.
National Demonstration Center for Experimental Chemistry Education, College of Chemistry and Chemical Engineering, Jishou University, Jishou, Hunan 416000, China
b.
State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha 410082, China

Corresponding author: ZHANG Zhaohui, zhaohuizhang77@163.com
Received Date: 8 May 2018
Revised Date: 6 June 2018
Accepted Date: 20 July 2018

Fund Project: the National Natural Science Foundation of China 21565014Supported by the National Natural Science Foundation of China(No.21767011, No.21565014), the Innovation Fund Designated for Graduate Students of Jishou University and the Collaborative Innovation Center 2011 of Hunan Provincethe National Natural Science Foundation of China 21767011

Figures(8)

A novel multiple-ion imprinted sensor based on graphene oxide/fullerene composite(GO-C₆₀) was developed for simultaneous and selective determination of Pb(Ⅱ), Cd(Ⅱ) and Cu(Ⅱ). The multiple-ion imprinted polymer was prepared with methacrylic acid and edetic acid as the functional monomer and ligand, respectively. The multiple-ion imprinted sensor was prepared by dispensing the imprinted polymer onto the GO-C60 modified carbon electrode surface. The performance of multiple-ion imprinted sensor was investigated using cyclic voltammetry, differential pulse voltammetry and electrochemical impedance spectroscopy in details. Under the optimized conditions, a linear relationship existed between the response currents of the multiple-ion imprinted sensor and the negative logarithm of ion concentrations ranging from 1.0×10^-9 mol/L to 5.0×10^-7 mol/L with the detection limit of 5.0×10^-10, 5.0×10^-10 and 1.0×10^-10 mol/L for Pb(Ⅱ), Cd(Ⅱ) and Cu(Ⅱ), respectively. The multiple-ion imprinted sensor was successfully used for simultaneous detection of trace level Pb(Ⅱ), Cd(Ⅱ) and Cu(Ⅱ) ions in real samples.
- multiple metal ions,
- imprinting,
- electrochemical sensor,
- graphene oxide/fullerene composite
1. [1]
  Dai G, Peng N, Zhong J. Effect of Metals on Microcystin Abundance and Environmental Fate[J]. Environ Pollut, 2017,226:154-162. doi: 10.1016/j.envpol.2017.04.013
2. [2]
  Yu J, Yang S, Sun D. Simultaneously Determination of Multi Metal Elements in Water Samples by Liquid Cathode Glow Discharge-Atomic Emission Spectrometry[J]. Microchem J, 2016,128:325-330. doi: 10.1016/j.microc.2016.05.019
3. [3]
  Boutorabi L, Rajabi M, Bazregar M. Selective Determination of Chromium(Ⅵ) Ions Using In-Tube Electro-Membrane Extraction Followed by Flame Atomic Absorption Spectrometry[J]. Microchem J, 2017,132:378-384. doi: 10.1016/j.microc.2017.02.028
4. [4]
  Silva F L, Duarte T A, Melo L S. Development of a Wet Digestion Method for Paints for the Determination of Metals and Metalloids Using Inductively Coupled Plasma Optical Emission Spectrometry[J]. Talanta, 2016,146(4/5):188-194.
5. [5]
  Jalalvand A R, Goicoechea H C, Rutledge D N. Applications and Challenges of Multi-way Calibration in Electrochemical Analysis[J]. TrAC-Trend Anal Chem, 2017,87:32-48. doi: 10.1016/j.trac.2016.11.002
6. [6]
  ZHANG Minglei, ZHANG Zhaohui, LUO Lijuan. Preparation and Adsorption Properties of Magnetic Fe₃O₄@SiO₂@CS Cadmium Ion-Imprinted Polymer[J]. Chem J Chinese Univ, 2011,32(12):2763-2768.
7. [7]
  LIU Qiuye, HE Xiwen, LI Wenyou. Studies on Chitosan Coated on Silica for Imprinting Bovine Hemoglobin[J]. Chem J Chinese Univ, 2009,30(4):691-696. doi: 10.3321/j.issn:0251-0790.2009.04.010
8. [8]
  Laatikainen K, Udomsap D, Siren H. Effect of Template Ion-Ligand Complex Stoichiometry on Selectivity of Ion-Imprinted Polymers[J]. Talanta, 2015,134:538-545. doi: 10.1016/j.talanta.2014.11.050
9. [9]
  AN Fuqiang, GAO Baojiao, LI Gang. Studies on Preparation of Ion-Imprinted Polyethyleneimine on Silica Gel Particles and Binding Properties for Metal Ions[J]. Acta Polym Sin, 2007(4):366-373. doi: 10.3321/j.issn:1000-3304.2007.04.012
10. [10]
  Lin S, Wei W, Wu X. Selective Recovery of Pd(Ⅱ) from Extremely Acidic Solution Using Ion-Imprinted Chitosan Fiber:Adsorption Performance and Mechanisms[J]. J Hazard Mater, 2015,299(6):10-17.
11. [11]
  Liu H, Kong D, Sun W. Effect of anions on the Polymerization and Adsorption Processes of Cu(Ⅱ) Ion-Imprinted Polymers[J]. Chem Eng J, 2016,303:348-358. doi: 10.1016/j.cej.2016.06.004
12. [12]
  Luo X, Guo B, Luo J. Recovery of Lithium from Wastewater Using Development of Li Ion-Imprinted Polymers[J]. ACS Sustainable Chem Eng, 2015,3:460-467. doi: 10.1021/sc500659h
13. [13]
  FAN Hongtao, SUI Dianpeng, ZHAO Lixing. Preparation of Cobalt(Ⅱ) Ion Imprinted Silica Gel Sorbents by Surface Imprinting Technique and Its Adsorption Properties[J]. Chem J Chinese Univ, 2011,32(12):2902-2907.
14. [14]
  Li J, Zhang L, Wei G. Highly Sensitive and Doubly Orientated Selective Molecularly Imprinted Electrochemical Sensor for Cu²⁺[J]. Biosens Bioelectron, 2015,69:316-320. doi: 10.1016/j.bios.2015.03.010
15. [15]
  Kokkios C, Economou A, Raptis I. Lithographically Fabricated Disposable Bismuth-Film Electrodes for the Trace Determination of Pb(Ⅱ) and Cd(Ⅱ) by Anodic Stripping Voltammetry[J]. Electrochim Acta, 2008,53(2):5294-5299.
16. [16]
  Hummers W S, Offeman R E. Functionalized Graphene and Graphene Oxide:Materials Synthesis and Electronic Applications[J]. J Am Chem Soc, 1958,80:1339-1339. doi: 10.1021/ja01539a017
17. [17]
  Zhang Z H, Yang X, Zhang H B. Novel Molecularly Imprinted Polymers Based on Multi-Walled Carbon Nanotubes with Binary Functional Monomer for the Solid-Phase Extraction of Erythromycin from Chicken Muscle[J]. J Chromatogr B, 2011,879:1617-1624. doi: 10.1016/j.jchromb.2011.03.054
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Multiple Metal Ion Imprinted Electrochemical Sensor with Enhanced Sensitivity by Graphene Oxide-C60 Composite

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通讯作者: 陈斌, bchen63@163.com

Multiple Metal Ion Imprinted Electrochemical Sensor with Enhanced Sensitivity by Graphene Oxide-C₆₀ Composite