Citation: LI Jiaqi, FU Dayou, YUAN Dong, XU Jing. Preparation and Characterization of ZnMgAl Hydrotalcite Supported BiOI[J]. Chinese Journal of Applied Chemistry, ;2019, 36(1): 83-90. doi: 10.11944/j.issn.1000-0518.2019.01.180059 shu

Preparation and Characterization of ZnMgAl Hydrotalcite Supported BiOI

LI Jiaqi ^a ,
FU Dayou ^a,, ,
YUAN Dong ^b ,
XU Jing ^b

a.
College of Chemical Engineering, Sichuan University of Science and Engineering, Zigong, Sichuan 643000, China
b.
College of Chemistry and Environmental Engineering, Sichuan University of Science and Engineering, Zigong, Sichuan 643000, China

Corresponding author: FU Dayou, Fdy888@263.net
Received Date: 6 March 2018
Revised Date: 6 June 2018
Accepted Date: 26 June 2018

Fund Project: Supported by the Science & Technology Department of Sichuan Province(No.2013JY0081), the Innovation Fund of Postgraduate, Sichuan University of Science and Engineering(No.y2018057), the Green Catalysis Key Laboratory Open Fund Project of Universities in Sichuan Province(No.LYJ1405)the Green Catalysis Key Laboratory Open Fund Project of Universities in Sichuan Province LYJ1405the Science & Technology Department of Sichuan Province 2013JY0081the Innovation Fund of Postgraduate, Sichuan University of Science and Engineering y2018057

Figures(13)

The ZnMgAl hydrotalcite-like compounds(HTLCs) supported bismuth oxyiodide(BiOI)(BiOI/ZnMgAl-HTLCs) visible light photocatalyst was prepared by hydrothermal method. The effects of BiOI loading mass fraction, reaction temperature, reaction time, and addition sequence on the structure and morphology of the BiOI/ZnMgAl-HTLCs photocatalyst were investigated by X-ray diffraction(XRD), scanning electron microscopy(SEM) and Fourier transform infrared spectroscopy(FTIR). The results show that BiOI/ZnMgAl-HTLCs with high crystallinity and good morphology can be obtained by firstly adding BiOI in 40% mass fraction to ZnMgAl-HTLCs at 140℃, and keeping reaction for 24 h.
- ZnMgAl hydrotalcite-like compounds,
- bismuth oxyiodide,
- photocatalyst
1. [1]
  Wang L J, Wang L R, Feng Y J. Highly Efficient and Selective Infrared Absorption Material Based on Layered Double Hydroxides for Use in Agricultural Plastic Film[J]. Appl Clay Sci, 2011,53(4):592-597. doi: 10.1016/j.clay.2011.05.008
2. [2]
  Wang L J, Xu X Y, Evans D G. Synthesis and Selective IR Absorption Properties of Iminodiacetic-Acid Intercalated MgAl-layered Double Hydroxide[J]. J Solid State Chem, 2010,183(5):1114-1119. doi: 10.1016/j.jssc.2010.03.022
3. [3]
  Evants D G, Rct S. Structure Aspects of Layered Double Hydroxide[J]. Struct Bond, 2006,119:1-87.
4. [4]
  Zhu H F, Tang P G, Feng Y J. Intercalation of IR Absorber into Layered Double Hydroxides:Preparation, Thermal Stability and Selective IR Absorption[J]. Mater Res Bull, 2012,47(3):532-536. doi: 10.1016/j.materresbull.2011.12.056
5. [5]
  Li L D, Yu J J, Hao Z P. Novel Ru-Mg-Al-O Catalyst Derived from Hydrotalcite-Like Compound for NO Storage/Decomposition/Reduction[J]. J Phys Chem C, 2007,111(28):10552-10559. doi: 10.1021/jp0678352
6. [6]
  Obalová L, Jirátová K, Kovanda F. Catalytic Decomposition of Nitrous Oxide over Catalysts Prepared from Co/Mg-Mn/Al Hydrotalcite-like Compounds[J]. Appl Catal B-Environ, 2005,60:289-297. doi: 10.1016/j.apcatb.2005.04.002
7. [7]
  Shao M, Ning F, Zhao J. Preparation of Fe₃O₄/SiO₂/Layered Double Hydroxide Coreshell Microspheres for Magnetic Separation of Proteins[J]. J Am Chem Soc, 2012,134:1071-1077. doi: 10.1021/ja2086323
8. [8]
  Lu X, Wang G, Zhai T. Hydrogenated TiO₂ Nanotube Arrays for Supercapacitors[J]. Nano Lett, 2012,12:1690-1696. doi: 10.1021/nl300173j
9. [9]
  Yuan D, Zhou L, Fu D Y. Adsorption of Methyl Orange from Aqueous Solutions by Calcined ZnMgAl Hydrotalcite[J]. Appl Phys A-Mater, 2017,123:146-153. doi: 10.1007/s00339-017-0763-2
10. [10]
  Xu J Y, Liu J, Li K D. Novel PEPA-Functionalized Graphene Oxide for Fire Safety Enhancement of Polypropylene[J]. Sci Technol Adv Mater, 2015(16):1-11.
11. [11]
  Song Y, Wang J, Li Z. Self-assembled Hierarchical Porous Layered Double Hydroxides by Solvothermal Method and Their Application for Capacitors[J]. Micropor Mesopor Mater, 2012,148(1):159-165. doi: 10.1016/j.micromeso.2011.08.013
12. [12]
  Zhang L, Zhang X, Shen L. Enhanced High-Current Capacitive Behavior of Graphene/CoAl-layered Double Hydroxide Composites as Electrode Material for Supercapacitors[J]. J Power Sources, 2012,199:395-401. doi: 10.1016/j.jpowsour.2011.10.056
13. [13]
  Hou W G, Jin Z L. Synthesis and Characterization of Naproxen Intercalated Zn-Al Layered Double Hydroxides[J]. Colloid Polym Sci, 2007,285(13):1449-1454. doi: 10.1007/s00396-007-1704-y
14. [14]
  XUE Yuanming, FAN Lihui, LIU Dongbin. Photocatalytic Degradation of Methyl Orange on ZnCr Layered Double Hydroxides[J]. J Shenyang Univ Chem Tech, 2015,29(3):233-237. doi: 10.3969/j.issn.2095-2198.2015.03.009
15. [15]
  WANG Lina. Prepapation and Properties of Go/BiOI Composite Visible-Light Photocatalytic Materials[D]. Harbin: Harbin Normal University, 2013(in Chinese).
16. [16]
  Chen L, Huang R, Xiong M. Room-Temperature Synthesis of Flower-Like BiOX(X=Cl, Br, I) Hierarchical Structures and Their Visible-Light Photocatalytic Activity[J]. Inorg Chem, 2013,52(19):11118-11125. doi: 10.1021/ic401349j
17. [17]
  Liu Q C, Ma D K, Hu Y Y. Various Bismuth Oxyiodide Hierarchical Architectures:Alcohothermal-Controlled Synthesis, Photocatalytic Activities, and Adsorption Capabilities for Phosphate in Water[J]. ACS Appl Mater Interfaces, 2013,5(22):11927-11934. doi: 10.1021/am4036702
18. [18]
  WANG Na, ZHONG Jianchu, WANG Hongzhi. Preparation, Characterization and Application of Calcium and Aluminum Layered Double Hydroxides Intercalated by Boric Acid Radical[J]. Inorg Chem Ind, 2016,48(1):25-27.
19. [19]
  WANG Ruirui. Studies on Synthesis and Properties of Layered Double Hydroxides Intercalated with Drugs[D]. Harbin: Harbin Engineering University, 2012(in Chinese).
20. [20]
  Wang J T, Xu F. Preparation of EDTA Pillared MgZnAl LDHs and Its Adsorption of Pb(Ⅱ)[J]. Chem Res Appl, 2014,26(4):581-585.
21. [21]
  Han X G, He H Z, Kuang Q. Controlling Morphologies and Tuning the Related Properties of Nano/Microstructured ZnO Crystallites[J]. J Phys Chem C, 2009,113(2):584-589.
1. [1]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
2. [2]
  Xianghai Song , Xiaoying Liu , Zhixiang Ren , Xiang Liu , Mei Wang , Yuanfeng Wu , Weiqiang Zhou , Zhi Zhu , Pengwei Huo . 氮掺杂显著提升BiOBr光催化还原CO₂性能研究. Acta Physico-Chimica Sinica, 2025, 41(6): 100055-. doi: 10.1016/j.actphy.2025.100055
3. [3]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
4. [4]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
5. [5]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . S型ZnO/CdIn₂S₄光催化剂制备H₂O₂偶联苄胺氧化的超快电子转移飞秒吸收光谱研究. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-. doi: 10.1016/j.actphy.2025.100064
6. [6]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . 设计热力学稳定的贵金属单原子光催化剂用于乙醇的高效非氧化转化形成高纯氢和增值产物乙醛. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-. doi: 10.1016/j.actphy.2025.100067
7. [7]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
8. [8]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
9. [9]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
10. [10]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
11. [11]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
12. [12]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088
13. [13]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
14. [14]
  Yuan CONG , Yunhao WANG , Wanping LI , Zhicheng ZHANG , Shuo LIU , Huiyuan GUO , Hongyu YUAN , Zhiping ZHOU . Construction and photocatalytic properties toward rhodamine B of CdS/Fe₃O₄ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2241-2249. doi: 10.11862/CJIC.20240219
15. [15]
  Zhinan GUO , Junli WANG , Qiang ZHAO , Zhifang JIA , Zuopeng LI , Kewei WANG , Yong GUO . Cu₂O/Bi₂CrO₆ Z-scheme heterojunction: Construction and photocatalytic degradation properties for tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 741-752. doi: 10.11862/CJIC.20240403
16. [16]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
17. [17]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
18. [18]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
19. [19]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
20. [20]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(1562)
HTML views(411)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142