Citation: YIN Zhengri. A Renewable High Selective Fluorescent Probe for Hydrogen Sulfide[J]. Chinese Journal of Applied Chemistry, ;2018, 35(12): 1514-1520. doi: 10.11944/j.issn.1000-0518.2018.12.180026 shu

A Renewable High Selective Fluorescent Probe for Hydrogen Sulfide

YIN Zhengri ^,

Department of Chemistry, College of Science, Yanbian University, Yanji, Jilin 133002, China

Corresponding author: YIN Zhengri, yinzhengri@ybu.edu.cn
Received Date: 29 January 2018
Revised Date: 7 March 2018
Accepted Date: 28 March 2018

Fund Project: the National Natural Science Foundation of China 21262039Supported by the National Natural Science Foundation of China(No.21262039)

Figures(7)

For expedient detection of H₂S in environmental samples, a renewable H₂S fluorescent probe(1-Cu²⁺) was constructed based on a complex formed by coumarin hydrazide oxime fluorescent ligand and a Cu²⁺. The probe displays very weak emission owing to quenching effect of Cu²⁺. The emission could be enhanced in the presence of S^2-, but no obvious changes in fluorescence intensity were observed upon the addition of other relevant anionic analytes(F^-, Cl^-, Br^-, I^-, CO₃^2-, HPO₄^2-, H₂PO₄^-, NO₂^-, NO₃^-, SO₄^2-, CH₃COO^-, N₃^-, S₂O₃^2-, CN^-). That is to say the probe system exhibits a remarkably selective fluorescence "ON" behavior exclusively with sulfide. The probe could be regenerated by the addition of Cu²⁺, and therefore the probe could be utilized repeatedly to sense sulfide anions with Cu²⁺ and S^2-. The detection limit of the fluorescent assay for sulfide is as low as ~37.0 nmol/L with a rapid response time(a few seconds), and the linear range is 0.5~4.0 μmol/L.
- coumarin hydrazide oxime,
- Cu²⁺ complex,
- hydrogen sulfide,
- renewable fluorescent probe,
- turn-on type
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