Citation: SONG Xueli, ZHANG Jianhui, LU Haiyan, BAO Jinpeng, TIAN Yongxia, LIN Haibo. Effect of Activated Carbon from Rice Husk on the Rate Performance of Lithium Manganese Oxide Battery[J]. Chinese Journal of Applied Chemistry, ;2018, 35(12): 1507-1513. doi: 10.11944/j.issn.1000-0518.2018.12.180020 shu

Effect of Activated Carbon from Rice Husk on the Rate Performance of Lithium Manganese Oxide Battery

a.
Zhuhai College of Jilin University, Zhuhai, Guangdong 519041, China
b.
College of Chemistry, Jilin University, Changchun 130012, China

Corresponding author: ZHANG Jianhui, 306844669@qq.com
Received Date: 22 January 2018
Revised Date: 16 March 2018
Accepted Date: 14 May 2018

Fund Project: the National Natural Science Foundation of China 21573093Supported by the National Natural Science Foundation of China(No.21573093)

Figures(5)

Rice husk activated carbon(RH-AC) was synthesized via facile carbonization and activation basing on previous work. Lithium Manganese Oxide(LMO) and RH-AC were used to prepare composite electrode. Lithium metal was used as the counter electrode. Composite electrode and pure LMO electrode were tested via the galvanostatic charge/discharge(GCD). The results show that the specific capacity of 89.3 mA·h/g at 5 C rate, and the capacity retention of 89% after 100 cycles are obtained for the composite electrode with addition 5% mass fraction of RH-AC(RH-AC5). Obviously, the composite electrode exhibits higher specific capacity with better rate capability and cycle stability than those of LMO electrode. This result was further verified by the impedance simulation result and the lithium ion diffusion coefficients obtained by the cyclic voltammetric method for LMO electrode and RH-AC5 electrode.
- lithium manganese oxide,
- activated carbon,
- rate capability,
- diffusion coefficients
1. [1]
  Yue H J, Huang X K, Lv D P. Hydrothermal Synthesis of LiMn₂O₄/C Composite as a Cathode for Rechargeable Lithium-Ion Battery with Excellent Rate Capability[J]. Electrochim Acta, 2009,54(23):5363-5367. doi: 10.1016/j.electacta.2009.04.019
2. [2]
  Kim D K, Muralidharan P, Lee H W. Spinel LiMn₂O₄ Nanorods as Lithium Ion Battery Cathodes[J]. Nano Lett, 2008,8(11):3948-3952. doi: 10.1021/nl8024328
3. [3]
  Hashem A M, Abdel-Ghany A E, Abuzeid H M. EDTA as Chelating Agent for Sol-Gel Synthesis of Spinel LiMn₂O₄ Cathode Material for Lithium Batteries[J]. J Alloys Compd, 2018,737:758-766. doi: 10.1016/j.jallcom.2017.12.153
4. [4]
  SHU Dong, YANG Yong, XIA Xi. Preparation of Spinel LiMn₂O₄ at Low Temperature[J]. Chinese J Appl Chem, 2000,17(6):633-635. doi: 10.3969/j.issn.1000-0518.2000.06.013
5. [5]
  YU Bingchuan, WU Hongte, YANG Guangzhong. Synthesis and Properties of SiO₂-Modified LiMn₂O₄ Cathode Material[J]. Chinese J Appl Chem, 2006(4):378-381. doi: 10.3969/j.issn.1000-0518.2006.04.008
6. [6]
  Xia H, Ragavendran K R, Xie J. Ultrafine LiMn₂O₄/Carbon Nanotube Nanocomposite with Excellent Rate Capability and Cycling Stability for Lithium-Ion Batteries[J]. J Power Sources, 2012,212:28-34. doi: 10.1016/j.jpowsour.2012.03.079
7. [7]
  Cheng F Y, Wang H B, Zhu Z Q. Porous LiMn₂O₄ Nanorods with Durable High-Rate Capability for Rechargeable Li-Ion Batteries[J]. Energy Environ Sci, 2011,4(9):3668-3675. doi: 10.1039/c1ee01795k
8. [8]
  Deng Y F, Zhou Y B, Shi Z C. Porous LiMn₂O₄ Microspheres as Durable High Power Cathode Materials for Lithium Ion Batteries[J]. J Mater Chem A, 2013,1(28):8170-8177. doi: 10.1039/c3ta11563a
9. [9]
  Cericola D, Nov k P, Wokaun A. Mixed Bi-Material Electrodes Based on LiMn₂O₄ and Activated Carbon for Hybrid Electrochemical Energy Storage Devices[J]. Electrochim Acta, 2011,56(24):8403-8411. doi: 10.1016/j.electacta.2011.07.029
10. [10]
  Sun X Z, Zhang X, Huang B. (LiNi_0.5Co_0.2Mn_0.3O₂+AC)/Graphite Hybrid Energy Storage Device with High Specific Energy and High Rate Capability[J]. J Power Sources, 2013,243:361-368. doi: 10.1016/j.jpowsour.2013.06.038
11. [11]
  Kishore B, Shanmughasundaram D, Penki T R. Coconut Kernel-Derived Activated Carbon as Electrode Material for Electrical Double-Layer Capacitors[J]. J Appl Electrochem, 2014,44(8):903-916. doi: 10.1007/s10800-014-0708-9
12. [12]
  Liu D C, Zhang W L, Lin H B. Hierarchical Porous Carbon Based on the Self-Templating Structure of Rice Husk for High-performance Supercapacitors[J]. RSC Adv, 2015,5(25):19294-19300. doi: 10.1039/C4RA15111A
13. [13]
  Xing A, Tian S, Tang H. Mesoporous Silicon Engineered by the Reduction of Biosilica from Rice Husk as a High-Performance Anode for Lithium-Ion Batteries[J]. RSC Adv, 2013,3(26):10145-10149. doi: 10.1039/c3ra41889h
14. [14]
  YU Junfeng, CHEN Peirong, YU Zhimin. Preparation and Characteristic of Activated Carbon from Sawdust Bio-Char by Chemical Activation with KOH[J]. Chinese J Appl Chem, 2013,30(9):1017-1022.
15. [15]
  Zhang W, Lin H, Lin Z. 3 D Hierarchical Porous Carbon for Supercapacitors Prepared from Lignin Through a Facile Template-Free Method[J]. ChemSusChem, 2015,8(12):2114-2122. doi: 10.1002/cssc.201403486
16. [16]
  Qian M L, Huang J J, Han S C. Preparation and Electrochemical Performance of the Interconnected LiMn₂O₄ Fibers[J]. Electrochim Acta, 2014,120:16-22. doi: 10.1016/j.electacta.2013.12.092
17. [17]
  Lee S, Cho Y, Song H K. Carbon-Coated Single-Crystal LiMn₂O₄ Nanoparticle Clusters as Cathode Material for High-Energy and High-Power Lithium-Ion Batteries[J]. Angew Chem Int Ed, 2012,51(35):8748-8752. doi: 10.1002/anie.v51.35
18. [18]
  Zhang W L, Yin J, Lin Z. Facile Preparation of 3D Hierarchical Porous Carbon from Lignin for the Anode Material in Lithium Ion Battery with High Rate Performance[J]. Electrochim Acta, 2015,176:1136-1142. doi: 10.1016/j.electacta.2015.08.001
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Activated Carbon from Rice Husk on the Rate Performance of Lithium Manganese Oxide Battery

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com