Citation: FU Liuwa, SU Jiahui, YAN Jiajin, ZHANG Ting, YANG Yan, LIU Xiaoxuan. Preparation and Properties of Photochromic Fluoroacrylate Coating[J]. Chinese Journal of Applied Chemistry, ;2018, 35(12): 1434-1441. doi: 10.11944/j.issn.1000-0518.2018.12.180014 shu

Preparation and Properties of Photochromic Fluoroacrylate Coating

FU Liuwa ^a ,
SU Jiahui ^a ,
YAN Jiajin ^a ,
ZHANG Ting ^a,b ,
YANG Yan ^a ,
LIU Xiaoxuan ^a,,

a.
Department of Polymeric Materials and Engineering, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China
b.
College of Chemistry and Environment, Minnan Normal University, Zhangzhou, Fujian 363000, China

Corresponding author: LIU Xiaoxuan, p-xxliu@gdut.edu.cn
Received Date: 17 January 2018
Revised Date: 9 March 2018
Accepted Date: 28 April 2018

Fund Project: the Major(Key) Projects of the Science and Technology Department of Guangzhou Science and Technology with Department of Guangdong Province and Guangzhou City 2015B090925008the Major(Key) Projects of the Science and Technology Department of Guangzhou Science and Technology with Department of Guangdong Province and Guangzhou City 20150122Supported by the Major(Key) Projects of the Science and Technology Department of Guangzhou Science and Technology with Department of Guangdong Province and Guangzhou City(No.2005B010122005, No.2015B090925008, NO.20150122)the Major(Key) Projects of the Science and Technology Department of Guangzhou Science and Technology with Department of Guangdong Province and Guangzhou City 2005B010122005

Figures(8)

The fluorine modified acrylate emulsion polymerization was performed using sodium dodecyl sulfate(SDS) and octylphenyl polyoxyethylene ether(OP-10) as complex emulsifiers, 2-(perfluorohexyl) ethylmethacrylate(PFM) as the fluorinated acrylate monomer, and potassium persulfate(KPS) as the initiator.Spiropyran was physically blended with the emulsion to obtain a photochromic fluorinated acrylate emulsion.The effects of the mass ratio of methyl methacrylate(MMA) to butyl acrylate(BA) monomers, and the amount of hydroxyspiropyran(SPOH) on the polymerization and the properties of the latex films were studied by means of various spectroscopic methods.The results show that the contact angle and thermal stability of the fluorinated polyacrylate are improved.The film presents good photochromic properties with addition of 1.25%(mass fraction) spiropyran.
- emulsion polymerization,
- photochromic,
- fluorinated acrylate,
- spiropyran
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