Citation: MENG Qingnan, DU Lulu, TANG Yufei, ZHAO Kang, ZHAO Lang. Preparation and Catalytic Properties of MnO_X-C@SiO₂ Core-Shell Particles[J]. Chinese Journal of Applied Chemistry, ;2018, 35(11): 1357-1363. doi: 10.11944/j.issn.1000-0518.2018.11.180235 shu

Preparation and Catalytic Properties of MnO_X-C@SiO₂ Core-Shell Particles

MENG Qingnan ^a,, ,
DU Lulu ^a ,
TANG Yufei ^a ,
ZHAO Kang ^a ,
ZHAO Lang ^b

a.
School of Materials Science & Engineering, Xi'an University of Technology, Xi'an 710048, China
b.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: MENG Qingnan, mengqn@xaut.edu.cn
Received Date: 5 July 2018
Revised Date: 7 August 2018
Accepted Date: 27 August 2018

Fund Project: Supported by the National Natural Science Foundation of China(No.51502241)the National Natural Science Foundation of China 51502241

Figures(6)

To prepare catalysts with high activity in the Fenton reaction toward the decomposition of pollutants in water, SiO₂ coated polyacrylate and manganese dioxide composite colloids (PAA-Mn@SiO₂) were carbonized under N₂ atmosphere. The synthesis process is very facile and effective. The as-prepared manganese oxides-carbon@SiO₂ core shell type catalyst (MnO_X-C@SiO₂) was characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), transmission electron microscope (TEM) and the specific surface area analysis. The results indicate that low-valenced manganese oxides (Mn₃O₄ and MnO) are formed in the MnO_X-C@SiO₂ due to the reductive atmosphere formed by the pyrolysis of PAA, which is beneficial for the enhancement of the catalytic performance in the Fenton reaction. In addition, the SiO₂ shell not only effectively prevents the inside manganese oxide nanoparticles from getting larger but also stops the product from aggregating during carbonation. The carbon component in the core can further stabilize the manganese oxide nanoparticles and promote the enrichment of organic pollutants. The specific surface area of the MnO_X-C@SiO₂ is 317.3 m²/g, which is well dispersed in water. For the catalytic degradation of methylene blue (MB) solution via the Fenton process, the degradation rate of MB can reach ~96.8% only after 40 min.
- manganese oxide,
- carbon,
- silica,
- core-shell structure,
- catalysis
1. [1]
  WU Zhongzheng, ZHU Weiju, WANG Dongmei. Preparation of Copper Oxide-Silica Porous Composites and Its Adsorption of Methylene Blue[J]. Chinese J Appl Chem, 2014,31(9):1089-1095.
2. [2]
  Debnath B, Roy A S, Kapri S. Efficient Dye Degradation Catalyzed by Manganese Oxide Nanoparticles and the Role of Cation Valence[J]. ChemistrySelect, 2016,1(14):4265-4273. doi: 10.1002/slct.201600806
3. [3]
  Wang Y L, Zhu L, Yang X. Facile Synthesis of Three-Dimensional Mn₃O₄ Hierarchical Microstructures and Their Application in the Degradation of Methylene Blue[J]. J Mater Chem A, 2015,3(6):2934-2941. doi: 10.1039/C4TA05493H
4. [4]
  Xu J H, Li D N, Chen Y. Constructing Sheet-On-Sheet Structured Graphitic Carbon Nitride/Reduced Graphene Oxide/Layered MnO₂ Ternary Nanocomposite with Outstanding Catalytic Properties on Thermal Decomposition of Ammonium Perchlorate[J]. Nanomaterials, 2017,7(12):450-462. doi: 10.3390/nano7120450
5. [5]
  Meng Q N, Du L L, Yang J. Well-Dispersed Small-Sized MnO_x Nanoparticles and Porous Carbon Composites for Effective Methylene Blue Degradation[J]. Colloids Surf A, 2018,548:142-149. doi: 10.1016/j.colsurfa.2018.03.064
6. [6]
  Meng Q N, Xiang S Y, Cheng W. Facile Synthesis of Manganese Oxide Loaded Hollow Silica Particles and Their Application for Methylene Blue Degradation[J]. J Colloid Interface Sci, 2013,405:28-34. doi: 10.1016/j.jcis.2013.05.025
7. [7]
  Zhang S W, Fan Q H, Gao H. Formation of Fe₃O₄@MnO₂ Ball-in-Ball Hollow Spheres as a High Performance Catalyst for Enhanced Catalytic Performances[J]. J Mater Chem A, 2016,4(4):1414-1422. doi: 10.1039/C5TA08400H
8. [8]
  Rehman S, Tang T Y, Ali Z. Integrated Design of MnO₂@Carbon Hollow Nanoboxes to Synergistically Encapsulate Polysulfdes for Empowering Lithium Sulfur Batteries[J]. Small, 2017,13(20):87-94.
9. [9]
  Meng Q N, Wang K, Tang Y F. Facile Synthesis of Porous Flower-Like Co₃O₄-SiO₂ Composite for Catalytic Decoloration of Rhodamine B[J]. ChemistrySelect, 2017,2(32):10442-10448. doi: 10.1002/slct.201701884
10. [10]
  WANG Cui, ZHANG Feiyun, LYU Rongwen. Gold Nanopaticle Surface Energy Transfer and Its Application for Thiols Detection[J]. Chinese J Appl Chem, 2018,35(1):59-67.
11. [11]
  Meng Q N, Wang K, Tang Y F. One-Pot Synthesis of Fe₂O₃ Loaded SiO₂ Hollow Particles as Effective Visible Light Photo-Fenton Catalyst[J]. J Alloys Compd, 2017,722:8-16. doi: 10.1016/j.jallcom.2017.06.077
12. [12]
  Xu H M, Jia J P, Guo Y F. Design of 3D MnO₂/Carbon Sphere Composite for the Catalytic Oxidation and Adsorption of Elemental Mercury[J]. J Hazard Mater, 2018,342:69-76. doi: 10.1016/j.jhazmat.2017.08.011
13. [13]
  Wang X Q, Dou L Y, Yang L. Hierarchical Structured MnO₂@SiO₂ Nanofibrous Membranes with Superb Flexibility and Enhanced Catalytic Performance[J]. J Hazard Mater, 2017,324:203-212. doi: 10.1016/j.jhazmat.2016.10.050
14. [14]
  Liu C Q, Li K Z, Li H J. The Effect of Zirconium Incorporation on the Thermal Stability and Carbonized Product of Phenol-Formaldehyde Resin[J]. Polym Degrad Stab, 2014,102:180-185. doi: 10.1016/j.polymdegradstab.2014.01.013
15. [15]
  Xu J, Deng Y Q, Zhang X M. Preparation, Characterization, and Kinetic Study of a Core-Shell Mn₃O₄@SiO₂ Nanostructure Catalyst for CO Oxidation[J]. ACS Catal, 2014,4(11):4106-4115. doi: 10.1021/cs5011376
16. [16]
  Bai Z C, Sun B, Fan N. Branched Mesoporous Mn₃O₄ Nanorods:Facile Synthesis and Catalysis in the Degradation of Methylene Blue[J]. Chem Eur J, 2012,18(17):5319-5324. doi: 10.1002/chem.v18.17
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Preparation and Catalytic Properties of MnO_X-C@SiO₂ Core-Shell Particles