Citation: TAN Yuhui, LIU Yi, CHEN Shaopeng, WANG Changfeng, TANG Yunzhi. Syntheses, Structure and Photo-Luminescent Properties of Mn^Ⅱ Complex with 2-(1H-1, 2, 4-Triazol-3-yl)pyridine[J]. Chinese Journal of Applied Chemistry, ;2018, 35(10): 1249-1255. doi: 10.11944/j.issn.1000-0518.2018.10.170356 shu

Syntheses, Structure and Photo-Luminescent Properties of Mn^Ⅱ Complex with 2-(1H-1, 2, 4-Triazol-3-yl)pyridine

School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China

Corresponding author: TAN Yuhui, tyxcn@163.com
Received Date: 28 September 2017
Revised Date: 9 November 2017
Accepted Date: 30 November 2018

Fund Project: the National Natural Science Foundation of China 21761013Supported by the National Natural Science Foundation of China(No.21471070, No.21761013, No.21261009, No.21461010), the Program of Jiangxi Provincial Science and Technology Department(No.20153BCB22006)the National Natural Science Foundation of China 21471070the Program of Jiangxi Provincial Science and Technology Department 20153BCB22006the National Natural Science Foundation of China 21261009the National Natural Science Foundation of China 21461010

Figures(7)

A novel complex, [Mn(C₇H₅N₄)·(SO₄)·2H₂O](1), was synthesized by hydrothermal reaction of organic ligand 2-(1H-1, 2, 4-triazol-3-yl)pyridine(2-HTP) with MnSO₄·H₂O in ethanol aqueous solution. The analysis and characterization of complex 1 were obtained via elemental analysis, infrared(IR), X-ray single-crystal diffraction, solid fluorescence analysis, and thermogravimetric analysis(TGA). Crystal data of complex 1 at 297 K are:monoclinic, P2₁/n, a=1.16373(12) nm, b=0.79324(9) nm, c=1.40241(15) nm, V=1.1996(2) nm³, Z=4. Crystal structure analysis indicates that 2-HTPs, as bidentate ligands, coordinate to Mn²⁺ that links to two water molecules and SO₄^2- by bridge connection into one-dimensional chain complex. In addition, there are π-π stacking between the aromatic-ring of 2-HTPs. Solid fluorescence analysis reveals that complex 1 shows blue fluorescence property with a strong emission at 477 nm.
- 2-(1H-1, 2, 4-triazol-3-yl)pyridine,
- one-dimensional chain,
- blue fluorescence properties
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通讯作者: 陈斌, bchen63@163.com

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Syntheses, Structure and Photo-Luminescent Properties of MnⅡ Complex with 2-(1H-1, 2, 4-Triazol-3-yl)pyridine

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通讯作者: 陈斌, bchen63@163.com

Syntheses, Structure and Photo-Luminescent Properties of Mn^Ⅱ Complex with 2-(1H-1, 2, 4-Triazol-3-yl)pyridine