Citation: HUANG Dengfa, LIU Yanhua, WANG Feng. Partial Factorial Analysis for the Stability of Water-in-Oil Type Polyethyleneimine Solution-in-Paraffin Emulsion[J]. Chinese Journal of Applied Chemistry, ;2018, 35(10): 1234-1242. doi: 10.11944/j.issn.1000-0518.2018.10.170349 shu

Partial Factorial Analysis for the Stability of Water-in-Oil Type Polyethyleneimine Solution-in-Paraffin Emulsion

School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China

Corresponding author: WANG Feng, fwang@jiangnan.edu.cn
Received Date: 22 September 2017
Revised Date: 10 November 2017
Accepted Date: 4 January 2018

Fund Project: Supported by China Scholarship Council(No.201406795023), Postgraduate Research & Practice Innovation Program of Jiangsu Provence(No.SJCX18_0618)Supported by China Scholarship Council 201406795023Postgraduate Research & Practice Innovation Program of Jiangsu Provence SJCX18_0618

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Polyethyleneimine(PEI) and its emulsions have been widely used in enzyme immobilization, gene therapy and waste water treatment, etc. In this work, a partial factorial test was employed to study the main factors and the interaction effect between various factors influencing the stability of water-in-oil(W/O) type PEI solution-in-paraffin emulsion. The results show that the amount of emulsifier and the mass fraction of PEI in aqueous phase are the main factors that influence the stability of the emulsion. The most significant factor is the interaction between the mass fraction of PEI in aqueous phase and the volume ratio of water/oil. The optimum conditions of the emulsion are:20% PEI in the aqueous phase, 0.07 g/mL of the emulsifier, 6:4 volume ratio of water/oil, 3 min of homogenization time and 6000 r/min of the homogenization velocity. The emulsion prepared under the optimal conditions has shown no significant changes of emulsification in a week, indicating its excellent stability.
- polyethyleneimine solution-in-paraffin emulsion,
- stability,
- partial factors test,
- factors interaction
1. [1]
  Jung H, Kim S A, Lee E. Linear Polyethyleneimine-Doxorubicin Conjugate for pH-Responsive Synchronous Delivery of Drug and MicroRNA-34a[J]. Macromol Res, 2015,23(5):449-456. doi: 10.1007/s13233-015-3060-y
2. [2]
  WANG Dongmei, CAO Jinli, ZHANG Yi. The Structure Characterization of Polyethylenimine via FTIR[J]. Spectrosc Spectr Anal, 2016(S1):199-200.
3. [3]
  Guo X, Ding L, Kanamori K. Functionalization of Hierarchically Porous Silica Monoliths with Polyethyleneimine(PEI) for CO ₂ Adsorption[J]. Micropor Mesopor Mater, 2017,245:51-57. doi: 10.1016/j.micromeso.2017.02.076
4. [4]
  Bayramoǧlu G, Arica M Y. Adsorption of Cr(Ⅵ) onto PEI Immobilized Acrylate-based Magnetic Beads:Isotherms, Kinetics and Thermodynamics Study[J]. Chem Eng J, 2008,139(1):20-28. doi: 10.1016/j.cej.2007.07.068
5. [5]
  Sahiner N, Demirci S, Sahiner M. The Synthesis of Desired Functional Groups on PEI Microgel Particles for Biomedical and Environmental Applications[J]. Appl Surf Sci, 2015,354:380-387. doi: 10.1016/j.apsusc.2015.05.022
6. [6]
  Zhang X Q, Intra J, Salem A K. Comparative Study of Poly(lactic-co-glycolic acid)-Poly Ethyleneimine-Plasmid DNA Microparticles Prepared Using Double Emulsion Methods[J]. J Microencapsul, 2008,25(1):1-12. doi: 10.1080/02652040701659347
7. [7]
  LIU Pei, NIE Tingting, WANG Feng. Preparation of Polyamine Microsphere and Its Protein Adsorption Properties[J]. Chem Ind Eng Prog, 2013,32(2):404-409.
8. [8]
  Chiang C L, Sung C S. Purification of Transfection-grade Plasmid DNA from Bacterial Cells with Superparamagnetic Nanoparticles[J]. J Magn Magn Mater, 2006,302(1):7-13. doi: 10.1016/j.jmmm.2005.08.022
9. [9]
  Rodriguez M, Lapierre J, Ojha C R. Intranasal Drug Delivery of Small Interfering RNA Targeting Beclin1 Encapsulated with Polyethylenimine(PEI) in Mouse Brain to Achieve HIV Attenuation[J]. Sci Rep, 2017,7(1)1862. doi: 10.1038/s41598-017-01819-9
10. [10]
  Matos M, García C F, Suárez M A. Treatment of Oil-in-Water Emulsions by a Destabilization/Ultrafiltration Hybrid Process:Statistical Analysis of Operating Parameters[J]. J Taiwan Inst Chem Eng, 2016,59:295-302. doi: 10.1016/j.jtice.2015.08.006
11. [11]
  ZHOU Yonghua, YE Hongqi, ZHONG Hong. Chemical Demulsification and Immobilization of Pd Nanoparticles in W/O Microemulsion by Conductivity Method[J]. Chinese J Process Eng, 2008,8(6):1163-1166. doi: 10.3321/j.issn:1009-606X.2008.06.023
12. [12]
  ZHANG Wen, TAO Senlin, SU Hongying. Latent Heat of Melting of Mg-based Eutectic Alloys as High Temperature Phase Change Materials for Latent Heat Storage[J]. J Funct Mater, 2017,48(2):2231-2235.
13. [13]
  FANG Hongbo, LIN Yun, LIN Meiqin. Effects of Acrylamide Polymer and Foamer on Oil-water Interfacial Properties and Emulsion Stability[J]. China Surfactant Deterg Cosmet, 2010,40(4):235-241.
14. [14]
  KANG Wanli, LI Jinhuan, ZHAO Xueqian. Effects of Interfacial Tension and Millet Size on Emulsion Stability[J]. Oil-Gasfield Surf Eng, 2005,24(1):11-12. doi: 10.3969/j.issn.1006-6896.2005.01.007
15. [15]
  CUI Zhenggang. Fundamentals of Surfactants, Colloids, and Interface Chemistry[M]. Beijing:Chemical Industry Press, 2013:238-240(in Chinese).
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