Citation: LONG Xia, WANG Yaqiong, JU Min, WANG Zheng, YANG Shihe. Elaboration and Application of Transition Metals Based Layered Double Hydroxides for Electrochemical Water Oxidation[J]. Chinese Journal of Applied Chemistry, ;2018, 35(8): 881-889. doi: 10.11944/j.issn.1000-0518.2018.08.180130 shu

Elaboration and Application of Transition Metals Based Layered Double Hydroxides for Electrochemical Water Oxidation

Guangdong Key Laboratory of Nano-Micro Material Research, School of Chemical Biology and Biotechnology, Shenzhen Graduate School, Peking University, Shenzhen, Guangdong 518055, China

Corresponding author: YANG Shihe, yangsh@pkusz.edu.cn
Received Date: 24 April 2018
Revised Date: 20 June 2018
Accepted Date: 22 June 2018

Fund Project: Shenzhen Peacock Plan Program KQTD2016053015544057Supported by the National Natural Science Foundation of China(No.21703003), Shenzhen Peacock Plan Program(No.KQTD2016053015544057)the National Natural Science Foundation of China 21703003

Figures(6)

Benefiting from the large specific surface area, open microstructure, tunable interlayer distance and chemical composition, the transition metals based layered double hydroxides(TM LDHs) have been widely applied and studied as efficient catalysts in recent years. This review introduces the design and applications of LDHs for electrochemical catalytic water oxidation. Illustrative examples are given on the origin of the advanced catalytic performance of TM LDHs towards water splitting, by focusing on their chemical compositions, microstructures and electronic properties. Possible strategies for further improving the catalytic performance and future development of TM LDHs are also prospected.
- transition metals-based catalysts,
- layered double hydroxides,
- water splitting,
- electrocatalysis,
- two-dimensional nanomaterials,
- layered structure
1. [1]
  Dresselhaus M S, Thomas I L. Alternative Energy Technologies[J]. Nature, 2001,414(6861):332-337. doi: 10.1038/35104599
2. [2]
  Crabtree G W, Dresselhaus M S, Buchanan M V. The Hydrogen Economy[J]. Phys Today, 2004,57(12):39-44. doi: 10.1063/1.1878333
3. [3]
  Turner J A. Sustainable Hydrogen Production[J]. Science, 2004,305(5686):972-974. doi: 10.1126/science.1103197
4. [4]
  Koper M T M. Thermodynamic Theory of Multi-Electron Transfer Reactions:Implications for Electrocatalysis[J]. J Electroanal Chem, 2011,660(2):254-260. doi: 10.1016/j.jelechem.2010.10.004
5. [5]
  Long X, Wang Z L, Xiao S. Transition Metal Based Layered Double Hydroxides Tailored for Energy Conversion and Storage[J]. Mater Today, 2016,19(4):213-226. doi: 10.1016/j.mattod.2015.10.006
6. [6]
  Ma W, Ma R Z, Wang C X. A Superlattice of Alternately Stacked Ni-Fe Hydroxide Nanosheets and Graphene for Efficient Splitting of Water[J]. ACS Nano, 2015,9(2):1977-1984. doi: 10.1021/nn5069836
7. [7]
  Long X, Li J K, Xiao S. A Strongly Coupled Graphene and FeNi Double Hydroxide Hybrid as an Excellent Electrocatalyst for the Oxygen Evolution Reaction[J]. Angew Chem Int Ed, 2014,53(29):7584-7588. doi: 10.1002/anie.201402822
8. [8]
  Lu Z, Xu W W, Zhu W. Three-Dimensional NiFe Layered Double Hydroxide Film for High-Efficiency Oxygen Evolution Reaction[J]. Chem Commun, 2014,50(49):6479-6482. doi: 10.1039/C4CC01625D
9. [9]
  Gerken J B, Shaner S E, Masse R C. A Survey of Diverse Earth Abundant Oxygen Evolution Electrocatalysts Showing Enhanced Activity from Ni-Fe Oxides Containing a Third Metal[J]. Energy Environ Sci, 2014,7(7):2376-2382. doi: 10.1039/C4EE00436A
10. [10]
  Kim J, Yin X, Tsao K C. Ca₂Mn₂O₅ as Oxygen-Deficient Perovskite Electrocatalyst for Oxygen Evolution Reaction[J]. J Am Chem Soc, 2014,136(42):14646-14649. doi: 10.1021/ja506254g
11. [11]
  Suntivich J, May K J, Gasteiger H A. A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles[J]. Science, 2011,334(6061):1383-1385. doi: 10.1126/science.1212858
12. [12]
  Lee J G, Hwang J, Hwang H J. A New Family of Perovskite Catalysts for Oxygen-Evolution Reaction in Alkaline Media:BaNiO₃ and BaNi_0.83O_2.5[J]. J Am Chem Soc, 2016,138(10):3541-3547. doi: 10.1021/jacs.6b00036
13. [13]
  Trotochaud L, Young S L, Ranney J K. Nickel-Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts:The Role of Intentional and Incidental Iron Incorporation[J]. J Am Chem Soc, 2014,136(18):6744-6753. doi: 10.1021/ja502379c
14. [14]
  Ahn H S, Bard A J. Surface Interrogation Scanning Electrochemical Microscopy of Ni_1-xFe_xOOH(0 < x < 0.27) Oxygen Evolving Catalyst:Kinetics of the "Fast" Iron Sites[J]. J Am Chem Soc, 2016,138(1):313-318. doi: 10.1021/jacs.5b10977
15. [15]
  Zhang B, Zheng X L, Voznyy O. Homogeneously Dispersed Multimetal Oxygen-Evolving Catalysts[J]. Science, 2016,352(6283):333-337. doi: 10.1126/science.aaf1525
16. [16]
  Feng J X, Ye S H, Xu H. Design and Synthesis of FeOOH/CeO₂ Heterolayered Nanotube Electrocatalysts for the Oxygen Evolution Reaction[J]. Adv Mater, 2016,28(23):4698-4703. doi: 10.1002/adma.v28.23
17. [17]
  Wang Y Y, Liu D D, Liu Z J. Porous Cobalt-Iron Nitride Nanowires as Excellent Bifunctional Electrocatalysts for Overall Water Splitting[J]. Chem Commun, 2016,52(85):12614-12617. doi: 10.1039/C6CC06608A
18. [18]
  Yu X Y, Feng Y, Guan B Y. Carbon Coated Porous Nickel Phosphides Nanoplates for Highly Efficient Oxygen Rvolution Reaction[J]. Energy Environ Sci, 2016,9(4):1246-1250. doi: 10.1039/C6EE00100A
19. [19]
  Li D, Baydoun H, Verani C N. Efficient Water Oxidation Using CoMnP Nanoparticles[J]. J Am Chem Soc, 2016,138(12):4006-4009. doi: 10.1021/jacs.6b01543
20. [20]
  Wang Q, O'Hare D. Recent Advances in the Synthesis and Application of Layered Double Hydroxide(LDH) Nanosheets[J]. Chem Rev, 2012,112(7):4124-4155. doi: 10.1021/cr200434v
21. [21]
  Patel R, Park J T, Patel M. Transition-Metal-Based Layered Double Hydroxides Tailored for Energy Conversion and Storage[J]. J Mater Chem A, 2018,6(1):12-29. doi: 10.1039/C7TA09370E
22. [22]
  Fan G L, Li F, Evans D G. Catalytic Applications of Layered Double Hydroxides:Recent Advances and Perspectives[J]. Chem Soc Rev, 2014,43(20):7040-7066. doi: 10.1039/C4CS00160E
23. [23]
  Li Z H, Shao M F, An H L. Fast Electrosynthesis of Fe-Containing Layered Double Hydroxide Arrays Toward Highly Efficient Electrocatalytic Oxidation Reactions[J]. Chem Sci, 2015,6(11):6624-6631. doi: 10.1039/C5SC02417J
24. [24]
  Tang C, Wang H S, Wang H F. Spatially Confined Hybridization of Nanometer-Sized NiFe Hydroxides into Nitrogen-Doped Graphene Frameworks Leading to Superior Oxygen Evolution Reactivity[J]. Adv Mater, 2015,27(30):4516-4522. doi: 10.1002/adma.v27.30
25. [25]
  Wang Y Y, Zhang Y Q, Liu Z J. Layered Double Hydroxide Nanosheets with Multiple Vacancies Obtained by Dry Exfoliation as Highly Efficient Oxygen Evolution Electrocatalysts[J]. Angew Chem Int Ed, 2017,56(21):5867-5871. doi: 10.1002/anie.201701477
26. [26]
  Vialat P, Mousty C, Taviot-Gueho C. High-Performing Monometallic Cobalt Layered Double Hydroxide Supercapacitor with Defined Local Structure[J]. Adv Funct Mater, 2014,24(30):4831-4842. doi: 10.1002/adfm.v24.30
27. [27]
  Nejati K, Akbari A R, Davari S. Zn-Fe-Layered Double Hydroxide Intercalated with Vanadate and Molybdate Anions for Electrocatalytic Water Oxidation[J]. New J Chem, 2018,42(4):2889-2895. doi: 10.1039/C7NJ04469K
28. [28]
  Li Y, Zhang L, Xiang X. Engineering of ZnCo-Layered Double Hydroxide Nanowalls Toward High-Efficiency Electrochemical Water Oxidation[J]. J Mater Chem A, 2014,2(33):13250-13258. doi: 10.1039/C4TA01275E
29. [29]
  Zou X, Goswami A, Asefa T. Efficient Noble Metal-Free (Electro)catalysis of Water and Alcohol Oxidations by Zinc-Cobalt Layered Double Hydroxide[J]. J Am Chem Soc, 2013,135(46):17242-17245. doi: 10.1021/ja407174u
30. [30]
  Long X, Xiao S, Wang Z L. Co Intake Mediated Formation of Ultrathin Nanosheets of Transition Metal LDH-An Advanced Electrocatalyst for Oxygen Evolution Reaction[J]. Chem Commun, 2015,51(6):1120-1123. doi: 10.1039/C4CC08856E
31. [31]
  Dinh K N, Zheng P L, Dai Z F. Ultrathin Porous NiFeV Ternary Layer Hydroxide Nanosheets as a Highly Efficient Bifunctional Electrocatalyst for Overall Water Splitting[J]. Small, 2018,14(8)1703257. doi: 10.1002/smll.201703257
32. [32]
  Smith R D L, Prevot M S, Fagan R D. Photochemical Route for Accessing Amorphous Metal Oxide Materials for Water Oxidation Catalysis[J]. Science, 2013,340(6128):60-63. doi: 10.1126/science.1233638
33. [33]
  Gerken J B, Shaner S E, Masse R C. A Survey of Diverse Earth Abundant Oxygen Evolution Electrocatalysts Showing Rnhanced Activity from Ni-Fe Oxides Containing a Third Metal[J]. Energy Environ Sci, 2014,7(7):2376-2382. doi: 10.1039/C4EE00436A
34. [34]
  Long X, Ma Z J, Yu H. Porous FeNi Oxide Nanosheets as Advanced Electrochemical Catalysts for Sustained Water Oxidation[J]. J Mater Chem A, 2016,4(39):14939-14943. doi: 10.1039/C6TA05907D
35. [35]
  Grimaud A, May K J, Carlton C E. Double Perovskites as a Family of Highly Active Catalysts for Oxygen Evolution in Alkaline Solution[J]. Nat Commun, 2013,43439.
36. [36]
  Klaus S, Cai Y, Louie M W. Effects of Fe Electrolyte Impurities on Ni(OH)₂/NiOOH Structure and Oxygen Evolution Activity[J]. J Phys Chem C, 2015,119(13):7243-7254. doi: 10.1021/acs.jpcc.5b00105
37. [37]
  Corrigan D A. The Catalysis of the Oxygen Evolution Reaction by Iron Impurities in Thin-Film Nickel-Oxide Electrodes[J]. J Electrochem Soc, 1987,134(2):377-384. doi: 10.1149/1.2100463
38. [38]
  Hunter B M, Hieringer W, Winkler J R. Effect of Interlayer Anions on[NiFe]-LDH Nanosheet Water Oxidation Activity[J]. Energy Environ Sci, 2016,91734. doi: 10.1039/C6EE00377J
39. [39]
  Gong M, Li Y G, Wang H L. An Advanced Ni-Fe Layered Double Hydroxide Electrocatalyst for Water Oxidation[J]. J Am Chem Soc, 2013,135(23):8452-8455. doi: 10.1021/ja4027715
40. [40]
  Liu Y W, Hua X M, Xiao C. Heterogeneous Spin States in Ultrathin Nanosheets Induce Subtle Lattice Distortion to Trigger Efficient Hydrogen Evolution[J]. J Am Chem Soc, 2016,138(15):5087-5092. doi: 10.1021/jacs.6b00858
41. [41]
  Gunjakar J L, Kim T W, Kim H N. Mesoporous Layer-by-Layer Ordered Nanohybrids of Layered Double Hydroxide and Layered Metal Oxide:Highly Active Visible Light Photocatalysts with Improved Chemical Stability[J]. J Am Chem Soc, 2011,133(38):14998-15007. doi: 10.1021/ja203388r
42. [42]
  Song F, Hu X L. Exfoliation of Layered Double Hydroxides for Enhanced Oxygen Evolution Catalysis[J]. Nat Commun, 2014,55477. doi: 10.1038/ncomms6477
43. [43]
  Xu X, Song F, Hu X L. A Nickel Iron Diselenide-Derived Efficient Oxygen-Evolution Catalyst[J]. Nat Commun, 2016,712324. doi: 10.1038/ncomms12324
44. [44]
  Tompsett D A, Parker S C, Islam M S. Rutile (beta-)MnO₂ Surfaces and Vacancy Formation for High Electrochemical and Catalytic Performance[J]. J Am Chem Soc, 2014,136(4):1418-1426. doi: 10.1021/ja4092962
45. [45]
  Bao J, Zhang X D, Fan B. Ultrathin Spinel-Structured Nanosheets Rich in Oxygen Deficiencies for Enhanced Electrocatalytic Water Oxidation[J]. Angew Chem Int Ed, 2015,54(25):7399-7404. doi: 10.1002/anie.v54.25
46. [46]
  Lei F C, Sun Y F, Liu K T. Oxygen Vacancies Confined in Ultrathin Indium Oxide Porous Sheets for Promoted Visible-Light Water Splitting[J]. J Am Chem Soc, 2014,136(19):6826-6829. doi: 10.1021/ja501866r
47. [47]
  Wang Q, Chen L, Guan S. Ultrathin and Vacancy-Rich CoAl-Layered Double Hydroxide/Graphite Oxide Catalysts:Promotional Effect of Cobalt Vacancies and Oxygen Vacancies in Alcohol Oxidation[J]. ACS Catal, 2018,8(4):3104-3115. doi: 10.1021/acscatal.7b03655
48. [48]
  Wang Y Y, Xie C, Zhang Z Y. In Situ Exfoliated, N-Doped, and Edge-Rich Ultrathin Layered Double Hydroxides Nanosheets for Oxygen Evolution Reaction[J]. Adv Funct Mater, 2018,28(4)1703363. doi: 10.1002/adfm.201703363
49. [49]
  Liu R, Wang Y Y, Liu D D. Water-Plasma-Enabled Exfoliation of Ultrathin Layered Double Hydroxide Nanosheets with Multivacancies for Water Oxidation[J]. Adv Mater, 2017,29(30)1701546. doi: 10.1002/adma.201701546
50. [50]
  Xie Q, Cai Z, Li P. Layered Double Hydroxides with Atomic-Scale Defects for Superior Eectrocatalysis[J]. Nano Res, 2018.
51. [51]
  Zhang Y, Cui B, Zhao C. Co-Ni Layered Double Hydroxides for Water Oxidation in Neutral Electrolyte[J]. Phys Chem Chem Phys, 2013,15(19):7363-7369. doi: 10.1039/c3cp50202c
52. [52]
  Gao X Y, Long X, Yu H. Ni Nanoparticles Decorated NiFe Layered Double Hydroxide as Bifunctional Electrochemical Catalyst[J]. J Electrochem Soc, 2017,164(6):H307-H310. doi: 10.1149/2.0561706jes
53. [53]
  Long X, Lin H, Zhou D. Enhancing Full Water-Splitting Performance of Transition Metal Bifunctional Electrocatalysts in Alkaline Solutions by Tailoring CeO₂-Transition Metal Oxides-Ni Nanointerfaces[J]. ACS Energy Lett, 2018,3(2):290-296. doi: 10.1021/acsenergylett.7b01130
54. [54]
  Li K D, Zhang J F, Wu R. Anchoring CoO Domains on CoSe₂ Nanobelts as Bifunctional Electrocatalysts for Overall Water Splitting in Neutral Media[J]. Adv Sci, 2016,31500426. doi: 10.1002/advs.201500426
55. [55]
  Zhao Y F, Chen S Q, Sun B. Graphene-Co₃O₄ Nanocomposite as Electrocatalyst with High Performance for Oxygen Evolution Reaction[J]. Sci Rep, 2015,57629. doi: 10.1038/srep07629
1. [1]
  Zhao Lu , Hu Lv , Qinzhuang Liu , Zhongliao Wang . Modulating NH₂ Lewis Basicity in CTF-NH₂ through Donor-Acceptor Groups for Optimizing Photocatalytic Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(12): 2405005-. doi: 10.3866/PKU.WHXB202405005
2. [2]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350
3. [3]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
4. [4]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
5. [5]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
6. [6]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
7. [7]
  Hao WANG , Kun TANG , Jiangyang SHAO , Kezhi WANG , Yuwu ZHONG . Electro-copolymerized film of ruthenium catalyst and redox mediator for electrocatalytic water oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2193-2202. doi: 10.11862/CJIC.20240176
8. [8]
  Runhua Chen , Qiong Wu , Jingchen Luo , Xiaolong Zu , Shan Zhu , Yongfu Sun . 缺陷态二维超薄材料用于光/电催化CO₂还原的基础与展望. Acta Physico-Chimica Sinica, 2025, 41(3): 2308052-. doi: 10.3866/PKU.WHXB202308052
9. [9]
  Xi Xu , Chaokai Zhu , Leiqing Cao , Zhuozhao Wu , Cao Guan . Experiential Education and 3D-Printed Alloys: Innovative Exploration and Student Development. University Chemistry, 2024, 39(2): 347-357. doi: 10.3866/PKU.DXHX202308039
10. [10]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
11. [11]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
12. [12]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
13. [13]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
14. [14]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
15. [15]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
16. [16]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
17. [17]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
18. [18]
  Zhifang SU , Zongjie GUAN , Yu FANG . Process of electrocatalytic synthesis of small molecule substances by porous framework materials. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2373-2395. doi: 10.11862/CJIC.20240290
19. [19]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029
20. [20]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020

Get Citation

PDF

XML

Metrics

PDF Downloads(12)
Abstract views(633)
HTML views(160)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142