Citation: ZHANG Liansheng, TANG Yuyuan, WANG Cuijuan, XIONG Xiaoyang, LI Zexian, CHEN Zhibin. Synthesis and Properties of 2, 2'-Biphenyl Dicarboxylic Acid Coordination Compound[J]. Chinese Journal of Applied Chemistry, ;2018, 35(4): 442-448. doi: 10.11944/j.issn.1000-0518.2018.04.170086 shu

Synthesis and Properties of 2, 2'-Biphenyl Dicarboxylic Acid Coordination Compound

Department of Chemistry and Chemical Engineering, College of Life Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China

Corresponding author: WANG Cuijuan, ejuan6046@163.com
Received Date: 27 March 2017
Revised Date: 26 May 2017
Accepted Date: 10 July 2017

Fund Project: the College Students Innovation Experiment Program of Sichuan Province 2016099the National College Students′ Innovative Experimental Project 201610613072Supported by the National Natural Science Foundation of China(No.21401151), the Science and Technology Support Plan of Sichuan Province(No.2015GZ0233), the Chengdu Huimin Technology Research and Development Project(No.2015-HM01-00336-SF), the National College Students′ Innovative Experimental Project(No.201610613072), the College Students Innovation Experiment Program of Sichuan Province(No.2016099)the Chengdu Huimin Technology Research and Development Project 2015-HM01-00336-SFthe Science and Technology Support Plan of Sichuan Province 2015GZ0233National Natural Science Foundation of China 21401151

Figures(7)

[Zn₂(oba)₂·2H₂O]_n was synthesized from 2, 2'-biphenyl carboxylic acid(H₂oba) and Zn(Ⅱ) by the hydrothermal method. Its structure was characterized by X-ray diffraction analysis, elemental analysis, fluorescence analysis and thermo gravimetric analysis. The results show that the compound is monoclinic, space group P2₁/c and the unit cell of the compound contains two separate zinc ions, two H₂oba ligands and two water molecules. The compound has a one-dimensional chain structure with infinite circulation under the action of the coordination bond. The linking of one-dimensional chain structure by hydrogen bonds forms its two-dimensional chain structure. In addition, the antioxidant activity studies show that the compound has good antioxidant activity with an IC₅₀(Half inhibitory concentration) value of 25 mg/L and is a good mimic of superoxide dismutase(SOD).
- biphenyl carboxylic acid,
- fluorescence property,
- thermogravimetric analysis,
- antioxidant activity
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