Citation: WANG Zhaoyun, ZHANG Ping, ZHANG Min, JIAO Lijuan. Synthesis and Properties of Quinoline Substituted Boron Dipyrromethene Based Ferric Ion Probe[J]. Chinese Journal of Applied Chemistry, ;2018, 35(1): 46-52. doi: 10.11944/j.issn.1000-0518.2018.01.170340 shu

Synthesis and Properties of Quinoline Substituted Boron Dipyrromethene Based Ferric Ion Probe

College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China

Corresponding author: JIAO Lijuan, jiao421@ahnu.edu.cn
Received Date: 18 September 2017
Revised Date: 3 November 2017
Accepted Date: 24 November 2017

Fund Project: Supported by the National Natural Science Foundation of China(No.21372011), the Natural Science Foundation of Anhui Province(No.1508085J07)the Natural Science Foundation of Anhui Province 1508085J07the National Natural Science Foundation of China 21372011

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A quinoline substituted boron dipyrromethene(BODIPY) based probe(BHQ) was synthesized and characterized by nuclear magnetic resonance spectroscopy(NMR) and high resolution mass spectrometer(HRMS). The probe shows significant enhancement of fluorescence intensity in the presence of Fe³⁺ in aqueous solution. The probe exhibits fast response, high sensitivity and high selectivity toward Fe³⁺, while other common metal ions do not show significant interference. The binding between the probe and Fe³⁺ has been found to be in 1:1 mole ratio based on Job's plot. This result suggests that the probe BHQ has potential application in the determination of Fe³⁺ ions.
- boron dipyrromethene,
- quinoline derivatives,
- fluorescent probe,
- ion sensing,
- ferric ion
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