Citation: WANG Cui, ZHANG Feiyun, LYU Rongwen, ZHANG Shufen. Gold Nanopaticle Surface Energy Transfer and Its Application for Thiols Detection[J]. Chinese Journal of Applied Chemistry, ;2018, 35(1): 60-67. doi: 10.11944/j.issn.1000-0518.2018.01.170048 shu

Gold Nanopaticle Surface Energy Transfer and Its Application for Thiols Detection

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: LYU Rongwen, lurw@dlut.edu.cn
Received Date: 28 February 2017
Revised Date: 12 April 2017
Accepted Date: 31 May 2017

Figures(11)

The fluorescence of Rhodamine B was quenched due to the surface energy transfer from Rhodamine B to silica supported gold nanoparticle surface. The Stern-Volmer quenching constant of the gold nanoparticles was 4.3×10³ L/mol in this system. While, the fluorescence of Rhodamine B recovered after the addition of thiols due to the strong affinity of thiol to gold nanoparticles which obstructed the energy transfer between Rhodamine B and gold nanoparticles. As the unique response of Rhodamine B-Au-SiO₂ system to thiols, it provides a simple analytical method for the detection of thiols. Moreover, Au-SiO₂ becomes a recyclable probe because of the stabilization of silica support.
- surface energy transfer,
- gold nanoparticles,
- silica,
- Rhodamine B,
- thiols
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