Citation: HUANG Qi, SONG Haohan, WANG Xiao, PANG Lanfang, ZHOU Yanmei. Synthesis of a New Rhodamine-Based Probe for Selective Detection of Ni²⁺ in Aqueous Solution[J]. Chinese Journal of Applied Chemistry, ;2017, 34(12): 1468-1473. doi: 10.11944/j.issn.1000-0518.2017.12.170294 shu

Synthesis of a New Rhodamine-Based Probe for Selective Detection of Ni²⁺ in Aqueous Solution

HUANG Qi ^a,b,c ,
SONG Haohan ^c ,
WANG Xiao ^c ,
PANG Lanfang ^c ,
ZHOU Yanmei ^c,,

a.
State Key Laboratory of Marine Environmental Science of China
b.
College of the Environment and Ecology, Xiamen University, Xiamen, Fujian 361102, China
c.
Institute of Environmental and Analytical Sciences, College of Chemistry and Chemical Engineering, He'nan University, Kaifeng, He'nan 475004, China

Corresponding author: ZHOU Yanmei, zhouyanmei@henu.edu.cn
Received Date: 21 August 2017
Revised Date: 8 October 2017
Accepted Date: 17 October 2017

Fund Project: Supported by the National Natural Science Foundation of China(No.21576071, No.21776061), the Open Foundation of State Key Laboratory of Fine Chemicals(No.KF1514)the National Natural Science Foundation of China 21776061the Open Foundation of State Key Laboratory of Fine Chemicals KF1514the National Natural Science Foundation of China 21576071

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Molecular spectroscopy has the advantages of high sensitivity and simple operation. Therefore, it is significant to develop a probe with high selectivity for nickel ions(Ni²⁺). In this paper, a novel molecular probe was designed and synthesized from rhodamine B, hydrazine hydrate and 2-acetylpyrazine for the detection of Ni²⁺ with excellent selectivity in aqueous media. Simultaneously, the probe rhodamine B amide derivative(RWZ) can achieve "naked eye" recognition of Ni²⁺ in aqueous solution. Furthermore, the probe shows high sensitivity to Ni²⁺ with low limit of detection(0.5 μmol/L), indicating that the probe can be used for detection of Ni²⁺ in aqueous solution.
- molecular probe,
- rhodamine B,
- nickel ion,
- "naked-eye" identification
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of a New Rhodamine-Based Probe for Selective Detection of Ni2+ in Aqueous Solution

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通讯作者: 陈斌, bchen63@163.com

Synthesis of a New Rhodamine-Based Probe for Selective Detection of Ni²⁺ in Aqueous Solution