Citation: DING Hao, YAN Fei, ZHENG Wenjing, GUO Weiliang, SU Bin. Electrochemical Detection of Antioxidants in Cosmetic Samples Using Mesoporous Silica Film and Confined Micelles[J]. Chinese Journal of Applied Chemistry, ;2017, 34(11): 1307-1313. doi: 10.11944/j.issn.1000-0518.2017.11.170251 shu

Electrochemical Detection of Antioxidants in Cosmetic Samples Using Mesoporous Silica Film and Confined Micelles

Institute of Analytical Chemistry, Department of Chemistry, Zhejiang University, Hangzhou 310058, China

Corresponding author: SU Bin, subin@zju.edu.cn
Received Date: 18 July 2017
Revised Date: 11 August 2017
Accepted Date: 30 August 2017

Fund Project: the National Natural Science Foundation of China 21575126the Natural Science Foundation of Zhejiang Province LR14B050001the National Natural Science Foundation of China 21335001Supported by the National Natural Science Foundation of China(No.21335001, No.21575126), the Natural Science Foundation of Zhejiang Province(No.LR14B050001)

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This work presents a novel approach for the electrochemical determination of butylated hydroxyanisole(BHA) and tert-butylhydroquinone(TBHQ) in real cosmetic samples using the indium tin oxide(ITO) electrodes modified with vertically aligned mesoporous silica channels retaining micelles of cetyltrimethylammonium bromide(CTAB). The ultra-small pore size of the channels, namely 2.3 nm in diameter, rendered the size screening capability of the electrode. Meanwhile, the hydrocarbon tails of CTAB provided a hydrophobic microenvironment, which enabled the rapid extraction and preconcentration of lipophilic organic analytes from sample solutions. An excellent analytical sensitivity, a wide dynamic range and a low limit of detection were obtained for both antioxidants under optimized conditions. Recovery values between 96.4% and 104% indicate the practical usefulness of the proposed sensor.
- electrochemical sensor,
- mesoporous silica film,
- antioxidants,
- micelles,
- cosmetic
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