Citation: BI Weihui, MAO Hongchao, ZHANG Suobo. Synthesis, Characterization and Gas Transport Properties of Polynaphthalimides Membranes[J]. Chinese Journal of Applied Chemistry, ;2017, 34(11): 1265-1272. doi: 10.11944/j.issn.1000-0518.2017.11.170042 shu

Synthesis, Characterization and Gas Transport Properties of Polynaphthalimides Membranes

BI Weihui ^a,b ,
MAO Hongchao ^a ,
ZHANG Suobo ^a,c,,

a.
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM), Nanjing 211816, China

Corresponding author: ZHANG Suobo, sbzhang@ciac.ac.cn
Received Date: 22 February 2017
Revised Date: 7 March 2017
Accepted Date: 27 April 2017

Fund Project: the National Natural Science Foundation of China 51473163the National Natural Science Foundation of China 51503199Supported by the National Natural Science Foundation of China(No.51473163, No.51503199)

Figures(5)

A series of novel polynaphthalimides(PNIs) was synthesized from 1, 4, 5, 8-naphthalenetracarboxylic dianhydride and several diamines containing alkyl substituents in the o-position. Almost all the PNIs with alkyl substituents in the o-position are readily soluble in polar solvents and can be solution-cast to transparent and tough films. The films have tensile strengths, elongations at break, and tensile module in the range of 54~77 MPa, 6.4%~8.1%, and 1.3~2.2 GPa, respectively. The PNIs exhibit excellent thermal stabilities with the onset decomposition temperature ranging from 448 to 501℃. The glass transition temperatures of the PNIs are in the range of 382 to 391℃. The CO₂ permeability coefficients and permeability selectivities of CO₂ to CH₄ of the PNIs are in the range of 37.2~151 barrer and 20.9~31.7, respectively, making these novel polynaphthalimides potentially useful candidate materials for membranes in natural gas purification.
- naphthalene dianhydride,
- polynaphthalimides,
- gas separation,
- membrane material
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