Citation: FAN Zhonglei, LIU Dazhuang. Study on the Miscibility of Chlorinated Polypropylene with Coating Resins by Viscometry[J]. Chinese Journal of Applied Chemistry, ;2017, 34(11): 1273-1278. doi: 10.11944/j.issn.1000-0518.2017.11.160516 shu

Study on the Miscibility of Chlorinated Polypropylene with Coating Resins by Viscometry

FAN Zhonglei ^, ,
LIU Dazhuang

School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: FAN Zhonglei, zhlfan@zzu.edu.cn
Received Date: 22 December 2016
Revised Date: 24 April 2017
Accepted Date: 23 May 2017

Fund Project: the Key Science and Technology Project of He′nan Province 152102310063Supported by the Key Science and Technology Project of He′nan Province(No.152102310063)

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The viscosities of the dilute solutions containing chlorinated polypropylene(CPP) and the coating resins, such as petroleum resin(PTR), acrylic resin(ALR) and alkyd resin(SAR), with different compositions were measured. The miscibilities of PTR/CPP blends, ALR/CPP blends and SAR/CPP blends were discriminated by the miscibility criterion α which was calculated from the experimental data by dilute solution viscosity. The results show that PTR/CPP blends are miscible and ALR/CPP blends are immiscible, while the miscibilities of SAR/CPP blends are determined by their compositions. SAR/CPP blends are compatible when the mass ratios of SAR to CPP are less than 1:1, while the blends are incompatible when the mass ratios are greater than 1:1, which are consistent with the results of the stability of the mixtures, the clarity and the related glossiness of the films. Therefore, the dilute solution viscosity can be used in the determination of coating polyblend miscibility by determining polymer-polymer interactions in solution.
- chlorinated polypropylene,
- coating resin,
- blend,
- miscibility,
- viscometry
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