Citation: BI Haoyu, LIANG Yaqin, LI Yan. Adsorption of p-Cresol on X-Type Gemini Surfactant-modified Hydrotalcite-like Nanocomposite[J]. Chinese Journal of Applied Chemistry, ;2017, 34(11): 1329-1335. doi: 10.11944/j.issn.1000-0518.2017.11.160507 shu

Adsorption of p-Cresol on X-Type Gemini Surfactant-modified Hydrotalcite-like Nanocomposite

BI Haoyu ^a ,
LIANG Yaqin ^b ,
LI Yan ^b,,

a.
Department of Biomedical Engineering, Changzhi Medical College, Changzhi, Shangxi 046000, China
b.
Department of Chemistry, Changzhi University, Changzhi, Shanxi 046011, China

Corresponding author: LI Yan, liyan_china@126.com
Received Date: 13 December 2016
Revised Date: 10 January 2017
Accepted Date: 27 February 2017

Fund Project: the Teaching Reform Project of Colleges and Universities in Shanxi Province J2013104Supported by the Natural Science Foundation of Shanxi Province(No.2013011040-8), the Teaching Reform Project of Colleges and Universities in Shanxi Province(No.J2013104)the Natural Science Foundation of Shanxi Province 2013011040-8

Figures(6)

Traditional surfactant-hydrotalcite-like(HTlc) nanocomposites can effectively adsorb the main organic pollutants, such as phenolic pollutants, in water. With high performance Gemini surfactant instead of traditional surfactant, an improved removal efficiency of surfactant-HTlc nanocomposites for organic pollutants is expected. In this paper, Gemini surfactant(MXC₆)-HTlc nanocomposite was prepared by delamination/reassembling method. The material was characterised by powder X-ray diffraction, Fourier transform infrared spectroscopy, specific surface area, atomic absorption spectrometry, and elemental analysis. The results show that MXC₆ anions are reassembled in the layers of HTlc. The adsorption behavior of p-cresol on MXC₆-HTlc nanocomposite was then investigated. The adsorption kinetics and adsorption isotherm of p-cresol on MXC₆-HTlc nanocomposite well fitted pseudo-first order kinetics and Linear equation, respectively. These results indicate that the adsorption amount of p-cresol on MXC₆-HTlc nanocomposite, is much higher than that on HTlc, and is decreased by increasing either pH(5.00~10.00) or temperature. The adsorption mechanism was discussed in detail. It is confirmed that MXC₆-HTlc nanocomposite can be as a new kind of highly effective adsorbent for phenolic pollution from water.
- X-type Gemini surfactant,
- hydrotalcite-like compound,
- delamination/reassembling,
- p-cresol,
- adsorption
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