Citation: HUANG Huodi, ZHANG Xiaofeng, ZHANG Yi, LE Lijuan, Lin Shen. Synthesis of Pt/{Reduced Graphene Oxide/Polyoxometalates}_n Composite Films and Their Electrocatalytic Performance[J]. Chinese Journal of Applied Chemistry, ;2017, 34(10): 1209-1220. doi: 10.11944/j.issn.1000-0518.2017.10.160501 shu

Synthesis of Pt/{Reduced Graphene Oxide/Polyoxometalates}_n Composite Films and Their Electrocatalytic Performance

College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350007, China

Corresponding author: Lin Shen, shenlin@fjnu.edu.cn
Received Date: 9 December 2016
Revised Date: 12 February 2017
Accepted Date: 13 April 2017

Fund Project: Natural Science Foundation of Fujian Province 2014J01033the National Natural Science Foundation of China 21571034Supported by the National Natural Science Foundation of China(No.21571034), Natural Science Foundation of Fujian Province(No.2014J01033)

Figures(13)

A series of {Reduced graphene oxide/Polyoxometalates}_n({rGO/POMs }_n) multilayer composite films was prepared by layer by layer assembly(LBL) combined with the light-assisted reduction in situ. The {rGO/POMs }_n film was used as a carrier to support Pt nanoparticles electrodeposited by constant potential method to obtain a new type of fuel cell anode catalyst, namely Pt/{rGO/SiW₁₂}₆ multilayer composite film. The growth of the multilayer composite films and Pt nanoclusters' morphology were characterized by UV-visible absorption spectrum(UV-Vis), atomic force microscope(AFM) and scanning elecrton microscopy(SEM). The results indicate that the multilayer composite {rGO/SiW₁₂}₆ is assembled on different substrate(quartz plate, indium tin oxide(ITO), and glass carbon electrode(GC)) surfaces with a continuous and uniform state, and the Pt nanoparticles on the surface exhibit a flower-like morphology. The electrochemical experiments show that Pt/{rGO/SiW₁₂}₆ catalyst exhibits better electrocatalytic activity, electrochemical stability and superior resistance to CO poisoning in the acidic methanol solution when it is compared with Pt/{rGO/PMo₁₂}₆, Pt/{rGO/PW₁₂}₆ and Pt. The Pt/{rGO/SiW₁₂}₆ multilayer composite film is expected to be the most promising methanol oxidation reaction catalyst in fuel cell anode.
- methanol fuel cell,
- electrocatalytic oxidation,
- electrodeposition,
- graphene,
- polyoxometallate,
- platinum
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Pt/{Reduced Graphene Oxide/Polyoxometalates}n Composite Films and Their Electrocatalytic Performance

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通讯作者: 陈斌, bchen63@163.com

Synthesis of Pt/{Reduced Graphene Oxide/Polyoxometalates}_n Composite Films and Their Electrocatalytic Performance