Citation: LI Shuailong, LIU Xiaoming, TANG Xinghua, FENG Jingchun, XIE Weijie. Synthesis and Luminescence Properties of Ba₃Y(PO₄)₃:Dy³⁺, Eu³⁺ Single Phase White-emitting Phosphor[J]. Chinese Journal of Applied Chemistry, ;2017, 34(10): 1186-1194. doi: 10.11944/j.issn.1000-0518.2017.10.160495 shu

Synthesis and Luminescence Properties of Ba₃Y(PO₄)₃:Dy³⁺, Eu³⁺ Single Phase White-emitting Phosphor

Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, China

Corresponding author: LIU Xiaoming, xmliu2014@163.com
Received Date: 5 December 2016
Revised Date: 6 February 2017
Accepted Date: 29 March 2017

Fund Project: the Postgraduate Innovation Foundation of Nanchang Hangkong University YC2015009the Natural Science Foundation of the Jiangxi Province of China 20152ACB20011Supported by the Natural Science Foundation of the Jiangxi Province of China(No.20152ACB20011), the Postgraduate Innovation Foundation of Nanchang Hangkong University(No.YC2015009)

Figures(8)

A series of Dy³⁺ and/or Eu³⁺ doped Ba₃Y(PO₄)₃ phosphors was prepared via a traditional high temperature solid state reaction to investigate how the luminescent properties of Dy³⁺ doped Ba₃Y(PO₄)₃ phosphor can be tuned by co-doping Eu³⁺ ions into the host lattice. X-ray diffraction(XRD), photoluminescence and fluorescence lifetime were used to characterize the as-prepared samples. The results show that all the samples have Ba₃Y(PO₄)₃ eulytite cubic structure. Under the excitation of near-UV light, the Ba₃Y(PO₄)₃:Dy³⁺ phosphor shows cool-white emission and the Ba₃Y(PO₄)₃:Eu³⁺ phosphor presents an orange-red emission. For Ba₃Y(PO₄)₃:Dy³⁺, Eu³⁺ phosphor, warm-white emission with high color rendering index and appropriate correlated color temperature has been obtained by combining red emission of Eu³⁺with cool-white emission of Dy³⁺. The luminescence mechanism of Ba₃Y(PO₄)₃:Dy³⁺, Eu³⁺ phosphor has been tentatively proposed and the prepared Ba₃Y(PO₄)₃:Dy³⁺, Eu³⁺ phosphor has potential application in white-light-emitting-diodes(WLEDs) filed.
- Ba₃Y(PO₄)₃:Dy³⁺, Eu³⁺,
- white-emitting phosphor,
- energy transfer
1. [1]
  Guo N, Huang Y, You H. Ca₉Lu(PO₄)₇:Eu²⁺, Mn²⁺:A Potential Single-phased White-light-emitting Phosphor Suitable for White-light-emitting Diodes[J]. Inorg Chem, 2010,49(23):10907-10913. doi: 10.1021/ic101749g
2. [2]
  Shang M, Li G, Kang X. Tunable Luminescence and Energy Transfer Properties of Sr₃AlO₄F:RE³⁺(RE=Tm/Tb, Eu, Ce) Phosphors[J]. ACS Appl Mater Interfaces, 2011,3(7):2738-2746. doi: 10.1021/am200534u
3. [3]
  Bandi V R, Grandhe B K, Jang K. Citric Based Sol gel Synthesis and Luminescence Characteristics of CaLa₂ZnO₅:Eu³⁺ Phosphors for Blue LED Excited White LEDs[J]. J Alloys Compd, 2012,512(1):264-269. doi: 10.1016/j.jallcom.2011.09.078
4. [4]
  Sun J, Sun Y, Du H. Luminescence Properties and Energy Transfer Investigations of Sr₃Gd(PO₄)₃:Ce³⁺, Tb³⁺ Phosphors[J]. J Phys Chem Solids, 2013,74(7):1007-1011. doi: 10.1016/j.jpcs.2013.02.019
5. [5]
  Li T, Li P, Wang Z. A Series of Tunable Emission Phosphors of Sm³⁺, Eu³⁺ and Mn²⁺Doped Ba₃Tb(PO₄)₃:Luminescence and Energy Transfer[J]. RSC Adv, 2015,5(88):71735-71742. doi: 10.1039/C5RA12619C
6. [6]
  XIE Ye, YIN Yan, ZHANG Ruixi. Progress in the Single Matrix White Light Emitting Phosphor for White-light LED[J]. New Chem Mater, 2012,40(2):24-26.
7. [7]
  Bandi V R, Grandhe B K, Woo H J. Luminescence and Energy Transfer of Eu³⁺ or/and Dy³⁺Co-doped in Sr₃AlO₄F Phosphors with NUV Excitation for WLEDs[J]. J Alloys Compd, 2012,538:85-90. doi: 10.1016/j.jallcom.2012.05.057
8. [8]
  WU Jiang, ZHANG Ping, JIANG Chundong. Single Host White Phosphors Ca₃Y₂Si₃O₁₂:Dy³⁺ Excited by Near UV Light[J]. Chinese J Lumin, 2014(9):1046-1050.
9. [9]
  REN Qiang, WANG Baoxing, WU Xiulan. Influence of Eu³⁺ Doping on Luminescent Properties of Ba₃La(PO₄)₃:Dy³⁺ White Phosphor and Its Luminescent Mechanism[J]. J Synth Cryst, 2016,45(2):350-355.
10. [10]
  Jeon Y I, Bharat L K, Yu J S. Eu³⁺Ions Co-doped CLPO:Dy³⁺Single Phase White-light Emitting Phosphors for Near UV-based White LEDs[J]. J Alloys Compd, 2015,649:531-536. doi: 10.1016/j.jallcom.2015.07.175
11. [11]
  Liu X, Lin C, Lin J. White Light Emission from Eu³⁺ in CaIn₂O₄Host Lattices[J]. Appl Phys Lett, 2007,90(8)081904. doi: 10.1063/1.2539632
12. [12]
  Yang Z, Xu D, Du J. Tunable Luminescence and Energy Transfer of a Eu²⁺/Mn²⁺Co-doped Sr₃NaY(PO₄)₃F Phosphor for White LEDs[J]. RSC Adv, 2016,6(90):87493-87501. doi: 10.1039/C6RA20699A
13. [13]
  Shang M, Li C, Lin J. How to Produce White Light in a Single-phase Host?[J]. Chem Soc Rev, 2014,43(5):1372-1386. doi: 10.1039/C3CS60314H
14. [14]
  YANG Zhiping, LYU Liang, LIU Pengfei. Synthesis and Luminescent Properties of the Single White Emitting Phosphor Ca₉Al(PO₄)₇:Ce³⁺, Dy³⁺[J]. Chinese J Lumin, 2013,34(4):395-399.
15. [15]
  HUANG Jun, YI Shuangping, XIAN Jieqiang. Synthesis and Luminescence Properties of Eu³⁺/Dy³⁺ Co-doped Single-phased Ba₂CaWO₆Phosphors for White-light Applications[J]. J Guangdong Univ Technol, 2016,33(2):76-80.
16. [16]
  Niu X, Xu J, Zhang Y. The Spectroscopic Properties of Dy³⁺ and Eu³⁺Co-doped Y₃Al₅O₁₂(YAG) Phosphors for White LED[J]. Prog Nat Sci:Mater Int, 2015,25(3):209-214. doi: 10.1016/j.pnsc.2015.05.006
17. [17]
  Pavitra E, Raju G S R, Yu J S. White Light Emission from Eu³⁺Co-activated Ca₂Gd₈Si₆O₂₆:Dy³⁺ Nanophosphors by Solvothermal Synthesis[J]. Ceram Int, 2013,39(6):6319-6324. doi: 10.1016/j.ceramint.2013.01.057
18. [18]
  Guan H, Liu G, Wang J. Tunable Luminescence and Energy Transfer Properties of NaGdF₄:Dy³⁺, Eu³⁺ Nanophosphors[J]. New J Chem, 2014,38(10):4901-4907. doi: 10.1039/C4NJ00688G
19. [19]
  Yang F, Liu Y, Tian X. Luminescence Properties of Phosphate Phosphor Ba₃Y(PO₄)₃:Sm³⁺[J]. J Solid State Chem, 2015,225:19-23. doi: 10.1016/j.jssc.2014.11.025
20. [20]
  Xin S, Wang Y, Wang Z. An Intense Red-Emitting Phosphor YBa₃(PO₄)₃:Eu³⁺ for Near-ultraviolet Light Emitting Diodes Application[J]. Electrochem Solid-State Lett, 2011,14(11):H438-H441. doi: 10.1149/2.003111esl
21. [21]
  ZHOU Liya, HUANG Lijun, YI Linghong. Luminescent Properties of Ba₃Gd(BO₃)₃:Eu³⁺ Phosphor for White LED Applications[J]. J Chinese Rare Earth Soc, 2009(1):31-35.
22. [22]
  Wang Z, Hu Y, Zhang S. Photoluminescence Properties of a Novel Red Phosphor Sr₃Ga₂O₅Cl₂:Eu³⁺[J]. Appl Phys A, 2016,122(2):1-6.
23. [23]
  Wu Y, Zhao F, Piao X. Zn-doped CaTiO₃:Eu³⁺ Red Phosphors for Enhanced Photoluminescence in White LEDs by Solid-state Reaction[J]. Luminescence, 2016,31(1):152-157. doi: 10.1002/bio.2937
24. [24]
  Yu R, Noh H M, Moon B K. Synthesis and Luminescence Properties of a Novel Red-emitting Phosphor Ba₃La(PO₄)₃:Eu³⁺ for Solid-state Lighting[J]. J Alloys Compd, 2013,576:236-241. doi: 10.1016/j.jallcom.2013.04.150
25. [25]
  Liu Q, Liu Y, Ding Y. A White Light Emitting Luminescent Material Ba₃Y(PO₄)₃:Dy³⁺[J]. Ceram Int, 2014,40(7):10125-10129. doi: 10.1016/j.ceramint.2014.01.137
26. [26]
  Xiong F B, Lin H F, Wang L J. White Light Emission in Host-sensitized Dy³⁺-Single-Doped NaIn(WO₄)₂ Phosphors[J]. Physica B, 2015,459:41-45. doi: 10.1016/j.physb.2014.11.100
27. [27]
  Guo C, Jing H, Li T. Green-emitting Phosphor Na₂Gd₂B₂O₇:Ce³⁺, Tb³⁺ for Near-UV LEDs[J]. RSC Adv, 2012,2(5):2119-2122. doi: 10.1039/c2ra00808d
28. [28]
  Zeng X, Im S J, Jang S H. Luminescent Properties of (Y, Gd)BO₃:Bi³⁺, RE³⁺(RE=Eu, Tb) Phosphor under VUV/UV Excitation[J]. J Lumin, 2006,121(1):1-6. doi: 10.1016/j.jlumin.2005.09.006
29. [29]
  Yang Z, Xu D, Sun J. Luminescence Properties and Energy Transfer Investigations of Sr₃Lu(PO₄)₃:Ce³⁺, Tb³⁺ Phosphors[J]. Mater Sci Eng B, 2016,211:13-19. doi: 10.1016/j.mseb.2016.05.015
30. [30]
  Ye S, Xiao F, Pan Y X. Phosphors in Phosphor-converted White Light-emitting Diodes:Recent Advances in Materials, Techniques and Properties[J]. Mater Sci Eng:R, 2010,71(1):1-34. doi: 10.1016/j.mser.2010.07.001
31. [31]
  Zhang X, Gong M. Single-phased White-light-emitting NaCaBO₃:Ce³⁺, Tb³⁺, Mn²⁺ Phosphors for LED Applications[J]. Dalton Trans, 2014,43(6):2465-2472. doi: 10.1039/C3DT52328D
32. [32]
  Maggay I V B, Lin P C, Liu W R. Investigation of Luminescence Properties and the Energy Transfer Mechanism of Li₆Lu(BO₃)₃:Ce³⁺, Tb³⁺ Green-emitting Phosphors[J]. RSC Adv, 2015,5(8):5591-5597. doi: 10.1039/C4RA12538J
33. [33]
  Zhu J, Xia Z, Liu Q. Synthesis and Energy Transfer Studies of LaMgAl₁₁O₁₉:Cr³⁺, Nd³⁺ Phosphors[J]. Mater Res Bull, 2016,74:9-14. doi: 10.1016/j.materresbull.2015.09.031
34. [34]
  Wang Z, Lou S, Li P. Enhanced Orange Red Emission of Sr₃La(PO₄)₃:Ce³⁺, Mn²⁺ via Energy Transfer[J]. J Lumin, 2014,156:87-90. doi: 10.1016/j.jlumin.2014.07.016
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Synthesis and Luminescence Properties of Ba3Y(PO4)3:Dy3+, Eu3+ Single Phase White-emitting Phosphor

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Luminescence Properties of Ba₃Y(PO₄)₃:Dy³⁺, Eu³⁺ Single Phase White-emitting Phosphor