Citation: WANG Yutong, FAN Weidong, XIAO Zhenyu, HUANG Zhaodi, XU Lin, ZHANH Liangliang, XING Lixue, DAI Fangna, SUN Daofeng. Solvent-Dependent Synthesis and Fluorescent Properties of Cu(Ⅱ) Metal-Organic Frameworks[J]. Chinese Journal of Applied Chemistry, ;2017, 34(9): 1035-1045. doi: 10.11944/j.issn.1000-0518.2017.09.170180 shu

Solvent-Dependent Synthesis and Fluorescent Properties of Cu(Ⅱ) Metal-Organic Frameworks

a.
China University of Petroleum(East China), Qingdao, Shandong 266580, China
b.
Huangdao Entry-Exit Inspection and Quarantine Bureau, Qingdao, Shandong 266555, China

Corresponding author: DAI Fangna, fndai@upc.edu.cn SUN Daofeng, dfsun@upc.edu.cn
Received Date: 26 May 2017
Revised Date: 23 June 2017
Accepted Date: 23 June 2017

Fund Project: the National Natural Science Foundation of China 21571187Supported by the National Natural Science Foundation of China(No.21571187)

Figures(8)

Metal-organic frameworks have promising potentials of for applications in the areas of fluorescence recognition. To explore more accurate identification of synthetic substancess, we synthesized two copper metal-organic frameworks(MOFs), {[Cu(PAIA)(H₂O)]·2H₂O}(1) and {[Cu₃(PAIA)₂(DMSO)(Pyridine)_1.5]}(2)(H₂PAIA=5-(propionyl-λ2-azanyl)isophthalic acid; DMSO=dimethyl sulphoxide), by the solvothermal reaction in the presence of H₂PAIA under different solvents(H₂O and DMSO/H₂O). Synthetic investigations and structural analyses reveal that both MOFs show distinct frameworks with remarkable solvent-directed feature, although they are assembled from the same starting materials, i.e., Cu(NO₃)₂·3H₂O with H₂PAIA for complexes 1 and 2. The topological structures and fluorescent properties of the two coordination compounds show a significant difference. Complex 1 is a three-dimensional NbO-type topology, while the complex 2 is a two-dimensional sql-type topology. Complex 1 exhibits fluorescent recognition to both Pb²⁺ and Ag⁺ ions, while complex 2 exhibits fluorescent recognition of Pb²⁺ ion. The water contact angle for complex 1 is 85.06°, while the water contact angle for complex 2 is 52.71°.
- solvent control,
- metal-organic frameworks,
- topology analysis,
- fluorescence properties,
- hydrophobic properties
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