Citation: WANG Zheng, YIN Shaoyun, PAN Mei, LIU Yu, SUN Sisi, WANG Haiping, FAN Ya'nan, SU Chengyong. Assembly and Luminescence of Mononuclear Ln to Heteronuclear Ln-M Supramolecular Complexes[J]. Chinese Journal of Applied Chemistry, ;2017, 34(9): 1017-1023. doi: 10.11944/j.issn.1000-0518.2017.09.170144 shu

Assembly and Luminescence of Mononuclear Ln to Heteronuclear Ln-M Supramolecular Complexes

Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China

Corresponding author: PAN Mei, panm@mail.sysu.edu.cn
Received Date: 8 May 2017
Revised Date: 1 June 2017
Accepted Date: 2 June 2017

Fund Project: the Science and Technology Planning Project of Guangzhou 201504010031the National Natural Science Foundation of China 21373276the Science and Technology Planning Project of Guangzhou 201510010246Supported by the National Natural Science Foundation of China(No.21373276), the Science and Technology Planning Project of Guangzhou (No.201510010246, No.201504010031)

Figures(4)

Via stepwise assembly method, discrete mononuclear Ln(Ln=Tb/Sm/Yb) complexes were synthesized from 3-or 4-pyridyl modified tripodal ligands, which were then assembled into three dimensional Ln-M(M=Ag or Cd) metal-organic frameworks(MOFs) with different topologies through the linkage of pyridyl ends. The heteronuclear MOFs sustain a characteristic emission of Ln³⁺ coordination centers, but the energy levels of the ligands are lowered in the three-dimensional packing structures, which affects the energy transfer efficiency to lanthanide centers. As a result, a stronger near-infrared luminescence is obtained in 2-Yb-Ag compared with its mononuclear counterpart, and the decay lifetime increases from 4.3 μs to 6.7 μs. While 4-Tb-Cd simultaneously emits metal-centered and ligand-based emissions, in which the decay lifetime for Tb-centered emission shortens from 2.91 ms to 0.62 ms compared with the corresponding mononuclear complex.
- lanthanide emission,
- metal-organic framework,
- heteronuclear complex
1. [1]
  Bünzli J C G. On the Design of Highly Luminescent Lanthanide Complexes[J]. Coord Chem Rev, 2015,293/294:19-47. doi: 10.1016/j.ccr.2014.10.013
2. [2]
  Barry D E, Caffrey D F, Gunnlaugsson T. Lanthanide-Directed Synthesis of Luminescent Self-Assembly Supramolecular Structures and Mechanically Bonded Systems from Acyclic Coordinating Organic Ligands[J]. Chem Soc Rev, 2016,45(11):3244-74. doi: 10.1039/C6CS00116E
3. [3]
  Xu L J, Xu G T, Chen Z N. Recent Advances in Lanthanide Luminescence with Metal-Organic Chromophores as Sensitizers[J]. Coord Chem Rev, 2014,273/274:47-62. doi: 10.1016/j.ccr.2013.11.021
4. [4]
  Liu Y, Pan M, Yang Q Y. Dual-Emission from a Single-Phase Eu-Ag Metal-Organic Framework:An Alternative Way to Get White-Light Phosphor[J]. Chem Mater, 2012,24(10):1954-1960. doi: 10.1021/cm3008254
5. [5]
  Pan M, Du B B, Zhu Y X. Highly Efficient Visible-to-NIR Luminescence of LnⅢ) Complexes with Zwitterionic Ligands Bearing Charge Transfer Character:Beyond Triplet Sensitization[J]. Chem Eur J, 2016,22(7):2440-2451. doi: 10.1002/chem.201504344
6. [6]
  Du B B, Zhu Y X, Pan M. Direct White-Light and Dual-channel Barcode Module from Pr(Ⅲ)-MOF Crystals[J]. Chem Commun, 2015,51(63):12533-12536. doi: 10.1039/C5CC04468E
7. [7]
  Pan M, Yan C, Chen L. Photoluminescence and White-Light Emitting in Two Series of Heteronuclear Pb(Ⅱ)-Ln(Ⅲ) Complexes[J]. New J Chem, 2015,39(5):3770-3776. doi: 10.1039/C5NJ00168D
8. [8]
  Yang Q Y, Wu K, Jiang J J. Pure White-Light and Yellow-to-Blue Emission Tuning in Single Crystals of Dy(Ⅲ) Metal-Organic Frameworks[J]. Chem Commun, 2014,50(57):7702-7704. doi: 10.1039/C4CC01763C
9. [9]
  He J, Huang J, He Y H. A Boiling-Water-Stable, Tunable White-Emitting Metal-Organic Framework from Soft-Imprint Synthesis[J]. Chem Eur J, 2016,22(5):1597-1601. doi: 10.1002/chem.201504941
10. [10]
  Zhou J M, Li H H, Zhang H. A Bimetallic Lanthanide Metal-Organic Material as a Self-Calibrating Color-Gradient Luminescent Sensor[J]. Adv Mater, 2015,27(44):7072-7077. doi: 10.1002/adma.201502760
11. [11]
  Wang L, Xie Z G, Dang S. Self-Assembly of Tunable Heterometallic Ln-Ru Coordination Polymers with Near-Infrared Luminescence and Magnetocaloric Effect[J]. Chem Eur J, 2017,23(12):2852-2857. doi: 10.1002/chem.v23.12
12. [12]
  Chen L, Zhang H, Pan M. An Efficient Visible and NIR Emitting Sm(Ⅲ) Metal-Organic Framework(Sm-MOF) Sensitized by Excited-State Intramolecular Proton Transfer(ESIPT) Ligand[J]. Chem Asian J, 2016,11(12):1765-1769. doi: 10.1002/asia.v11.12
13. [13]
  Zhang L Y, Li K, Pan M. Observation of Cascade f→d→f Energy Transfer in Sensitizing Near-Infrared(NIR) Lanthanide Complexes Containing Ru(Ⅱ) Polypyridine Metalloligand[J]. New J Chem, 2016,40(6):5379-5386. doi: 10.1039/C6NJ00089D
14. [14]
  Zhang L Y, Hou Y J, Pan M. Near-Infrared(NIR) Emitting Nd/Yb(Ⅲ) Complexes Sensitized by MLCT States of Ru(Ⅱ)/Ir(Ⅲ) Metalloligands in Visible Light Region[J]. Dalton Trans, 2015,44(34):15212-15219. doi: 10.1039/C5DT00545K
15. [15]
  Ning Y Y, Ke X S, Hu J Y. Bioinspired Orientation of β-Substituents on Porphyrin Antenna Ligands Switches Ytterbium(Ⅲ) NIR Emission with Thermosensitivity[J]. Inorg Chem, 2017,56(4):1897-1905. doi: 10.1021/acs.inorgchem.6b02481
16. [16]
  Pan M, Zheng X L, Liu Y. Structural and Photoluminescent Studies of Lanthanide Complexes with Tripodal TriRNTB(N-Substituted Tris(Benzimidazol-2-ylmethyl)Amine):Ligand Substituent, Anionic and Secondary Ligand Effects[J]. Dalton Trans, 2009,12(12):2157-2169.
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