Citation: WANG Ning, ZHOU Dongxue, YANG Jinchuang, AN Yue, LYU Chengwei. Determination of Hydrogen Sulfide in Water by Biphenyl Ratio Fluorescence Probe[J]. Chinese Journal of Applied Chemistry, ;2017, 34(4): 449-455. doi: 10.11944/j.issn.1000-0518.2017.04.160301 shu

Determination of Hydrogen Sulfide in Water by Biphenyl Ratio Fluorescence Probe

College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China

Corresponding author: AN Yue, anyue_11@163.com LYU Chengwei, chengweilv@126.com
Received Date: 28 July 2016
Revised Date: 9 October 2016
Accepted Date: 9 November 2016

Fund Project: the Higher Education Research Program of Education Department of Liaoning Province of China L2014421the National Natural Science Foundation of China 21403100

Figures(8)

A biphenyl-derived ratiometric fluorescent probe (WN) for the detection of H₂S was synthesized using 4, 4'-biphenyl dicarboxylic acid as the raw material and characterized by ¹H NMR, ¹³C NMR, and MS. For the purpose of detection of H₂S in aqueous solution, its fluorescent properties had been systematically researched. The results show that probe WN exhibits good sensitivity and selectivity for detection of H₂S, response time is 12 min. WN has strong anti-interference ability to biological mercaptan (Cys, Gsh), active oxides (H₂O₂, ClO^-), various anions and cations (H₂PO₄^-, SO₄^2-, Cl^-, HCO₃^-, CO₃^2-, Mg²⁺, Zn²⁺, K⁺, Ca²⁺, Na⁺), and a good fluorescence response in a wide pH range, the fluorescence in tensity has good linear relation ships with H₂S in the range of 1.1~350 μmol/L (R²=0.9943), the detection limit of H₂S is estimated to be 1.07×10^-6 mol/L. The test for three different water samples shows that the probe WN has a certain application significance in the detection of H₂S in water.
- hydrogen sulfide,
- azide group,
- ratiometric fluorescent probe
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