Citation: ZHU Yiming, ZHANG Hao, ZHANG Jun, MI Gang, SONG Bangcai, DU Xigang. Preparation and Catalytic Performance Evaluation of Multi-metal Catalysts for Conversion of Tetrachloromethaneto Trichloromethane by Liquid Phase Hydrogenation[J]. Chinese Journal of Applied Chemistry, ;2017, 34(2): 242-244. doi: 10.11944/j.issn.1000-0518.2017.02.160251 shu

Preparation and Catalytic Performance Evaluation of Multi-metal Catalysts for Conversion of Tetrachloromethaneto Trichloromethane by Liquid Phase Hydrogenation

Chemical Engineering & Pharmaceutics School, He'nan University of Science & Technology, Luoyang, He'nan 471023, China

Corresponding author: ZHANG Jun, j-zhang@126.com
Received Date: 15 June 2016
Revised Date: 20 July 2016
Accepted Date: 9 August 2016

Fund Project: the National Natural Science Foundation of China 21076063the National Natural Science Foundation of China 21576073

Figures(2)

By using Pd/Pt as main active ingredients and Fe/Ni as auxiliary, coconut shell activated carbon (ACcs) loaded mono metal (M/ACcs), binary metal (M-Ni/ACcs, M-Fe/ACcs) and ternary metal (M-Ni-Fe/ACcs) catalysts have been prepared via metal impregnation and H₂ reduction. The catalytic activity and selectivity of the catalysts for conversion of CCl₄ to CHCl₃ by liquid-phase hydrogenation was evaluated. Compared with Pt-based catalysts, the Pd-based counterparts have higher activity, but lower CHCl₃ selectivity. During initial reaction time of 5 h, the catalytic activity order follows:Pd-Ni-Fe/ACcs > Pd-Fe/ACcs > Pd/ACcs > Pd-Ni/ACcs and Pt/ACcs≈Pt-Fe/ACcs > Pt-Ni/ACcs > Pt-Ni-Fe/ACcs. Addition of Fe component improves the activity while single addition of Ni lowers the catalytic performance. The Pd-Ni-Fe/ACcs catalyst can realize more than 97% conversion of CCl₄ and nearly 100% selectivity for CHCl₃ at 393 K for 5 h.
- tetrachloromethane,
- trichloromethane,
- liquid-phase hydrogenation,
- Pd/Pt catalysts,
- catalytic performance,
- conversion rate
1. [1]
  ZHANG Dongbao, ZHU Jianjun, SHAN Yuhua. Advances in Hydrodechlorination of Carbon Tetrachloride[J]. Chem Ind Eng Prog, 2007,26(4):477-480.
2. [2]
  Bae J W, Kim I G, Lee K H. Hydrodechlorination of CCl₄ over Pt/γ-Al₂O₃ Effects of Reaction Pressure and Diluent Gases on Distribution of Products and Catalyst Stability[J]. Appl Catal A, 2001,217(1):79-89.
3. [3]
  Barnes R J, Riba O, Gardner M N. Optimization of Nano-Scale Nickel/Iron Particles for Reduction of High Concentration Chlorinated Aliphatic Hydrocarbon Solutions[J]. Chemosphere, 2010,79(4):448-454. doi: 10.1016/j.chemosphere.2010.01.044
4. [4]
  Gómez-Sainero L M, Grau J M, Arcoyna A. Liquid-Phase Hydrodechlorination of CCl₄ to CHCl₃ on Pd/Carbon Catalysts:Nature and Role of Pd Active Species[J]. J Catal, 2002,209(2):279-288. doi: 10.1006/jcat.2002.3655
5. [5]
  Choi H C, Choi S H, Yang O B. Hydrodechlorination of Carbon Tetrachloride over Pt/MgO[J]. J Catal, 1996,161(2):790-797. doi: 10.1006/jcat.1996.0242
6. [6]
  Choi H C, Choi S H, Lee J S. Effects of Pt Precursors on Hydrodechlorination of Carbon Tetrachloride over Pt/Al₂O₃[J]. J Catal, 1997,166(2):284-293. doi: 10.1006/jcat.1997.1508
7. [7]
  Gómez-Sainero L M, Seoane X L, Arcoya A. Hydrodechlorination of Carbon Tetrachloride in the Liquid Phase on a Pd/Carbon Catalyst:Kinetic and Mechanistic Studies[J]. Appl Catal B, 2004,53(2):101-110. doi: 10.1016/j.apcatb.2004.05.007
8. [8]
  Zinovyev S, Perosa A, Yufit S. Hydrodechlorination and Hydrogenation over Raney-Ni under Multiphase Conditons:Role of Multiphase Environment in Reaction Kinetics and Selectivity[J]. J Catal, 2002,211(2):347-354. doi: 10.1016/S0021-9517(02)93755-3
9. [9]
  HUANG Yuanying, LIU Fei, TANG Mingnie. Dechlorination of Tetrachloroethene with Nanoscale Ni/Fe and Cu/Fe Bimetallic Particles[J]. J Environ Sci-China, 2007,27(1):80-85.
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