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Citation: LI Jin, FENG Xun, GUO Hui. Nanorod-Assembled WO3·0.33H2O Microstructures with Improved Photocatalytic Property[J]. Chinese Journal of Applied Chemistry, ;2017, 34(1): 60-70. doi: 10.11944/j.issn.1000-0518.2017.01.160396 shu

Nanorod-Assembled WO3·0.33H2O Microstructures with Improved Photocatalytic Property

  • He'nan Key Laboratory of Function-Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, He'nan 471934, China

  • Corresponding author: FENG Xun, fengx@lynu.edu.cn
  • Received Date: 29 September 2016
    Revised Date: 19 October 2016
    Accepted Date: 18 November 2016

    Fund Project: the Key Scientific Research Project of Higher Education of He'nan 16A150036the Program for Science & Technology Innovation Talents in Universities of He'nan Province 2014HASTIT014Supported by the National Natural Science Foundation of China 21273101the Excellent Youth Foundation of He'nan Scientific Committee 164100510012

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  • Three-dimensional WO3·0.33H2O hierarchical microstructures consisting of nanorods have been successfully constructed through a facile hydrothermal route, employing sodium tungstate and dodecylbenzenesulfonic acid(DBSA) as precursors without the assistance of any additives. Remarkably, DBSA not only acts as a reagent to provide H+ but also serves as a surfactant to tailor the morphology of the as-synthesized products. The hierarchically-structured WO3·0.33H2O displays a strong structure-enhanced photocatalytic activity for the degradation of rhodamine B(RhB) under visible light irradiation, and the degradation ratio of RhB is 100% and is still kept at a high degradation ratio after using 5 times.
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