Citation: ZHU Jiang, GOU Wenxiu, WANG Xiaomin, CHEN Lidong, LENG Rubing, JIANG Chunjie. Synthesis of Ionic Coordination Compounds with Naphthalenedisulfonic Acid and Their Molecular Recognition Properties[J]. Chinese Journal of Applied Chemistry, ;2017, 34(1): 105-110. doi: 10.11944/j.issn.1000-0518.2017.01.160104 shu

Synthesis of Ionic Coordination Compounds with Naphthalenedisulfonic Acid and Their Molecular Recognition Properties

ZHU Jiang ^a,*,, ,
GOU Wenxiu ^a ,
WANG Xiaomin ^b ,
CHEN Lidong ^a ,
LENG Rubing ^a ,
JIANG Chunjie ^a,*,,

a.
School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 110629, China
b.
Experiment Center, Liaoning Normal University, Dalian, Liaoning 110629, China

Corresponding author: ZHU Jiang, zjryan@lnnu.edu.cn JIANG Chunjie, jiangcj@lnnu.edu.cn
Received Date: 11 March 2016
Revised Date: 31 May 2016
Accepted Date: 31 May 2016

Fund Project: the Doctoral Scientific Research Foundation of Liaoning Province 20131060

Figures(6)

Four compounds[M (en)(H₂O)₄]·1, 5-nds·(H₂O)₂(M=Ni (1), Co (2), Cd (3), Cu (4), based on ethylene diamine (en) and 1, 5-naphthalenedisulfonic acid (nds), were synthesized by hydrothermal synthesis method under room temperature. The structures of the crystals were confirmed by X-ray diffraction (XRD) method and SHELXTL-97 software. The four compounds have the same three dimensional (3D) framework in monoclinic C2/c space group, only different in metal atoms. The cell parameters of compound 1 are:a=1.69026(19) nm, b=1.01373(11) nm, c=1.3448(3) nm, α=90°, β=120.2650°, γ=90°, V=1.9901(5) nm³, Z=4, D_c=1.713 g/cm³, F(000)=1072, R₁=0.0326, wR₂=0.0867. One metal atom is coordinated to four oxygen atoms from water molecules and two nitrogen atoms of one ethylene diamine. There exit abundant hydrogen bonds interactions between free water molecules and oxygen atoms in 1, 5-naphthalenedisulfonic acid anion. One dimensional chains were formed through abundant hydrogen bonds and one[Ni (en)(H₂O)₄]²⁺ located between each two nds^2-. The two adjacent[Ni (en)(H₂O)₄]²⁺ arranged by the opposite mode (head to head). The properties of the two compounds were characterized by XRD, thermal gravimetric analysis (TGA), fluorescence spectroscopy and multi-function spectrometer. The molecular recognition properties of compound 3 with M=Cd in methanol solution was studied. The compound 3 was solved in different solvents in which the highest strength of fluorescence spectroscopy occurs in methanol solution. The strength of fluorescence spectroscopy decreases, with increasing concentration of methanol which may have potential applications in fluorescence probe to recognize polarity.
- naphthalenedisulfonic acid,
- molecular recognition,
- ethylene diamine,
- fluorescence
1. [1]
  Liu Y, Zhang J, Xu F. Lithium-Based 3D Coordination Polymer with Hydrophilic Structure for Sensing of Solvent Molecules[J]. Cryst Growth Des, 2008,8(9):3127-3129. doi: 10.1021/cg701173x
2. [2]
  Shao S, Zhu Y, Ma K. Two M (Ⅱ)-1, 5-NDS-dafo Supramolecular Architectures (M=Cu, Cd):Syntheses, Structures, and Photoluminescence Properties[J]. J Coord Chem, 2013,66(15):2702-2711. doi: 10.1080/00958972.2013.813938
3. [3]
  Jiang H, Liu Y, Ma J. Infinite Chains Constructed from Flexible Bis (benzimidazole) Based Ligands[J]. Polyhedron, 2008,27(12):2595-2602. doi: 10.1016/j.poly.2008.05.019
4. [4]
  Zhang Z, Xiang S, Rao S. A Rod Packing Microporous Metal Organic Framework with Open Metal Site for Selective Guest Sorption and Sensing of Nitrobenzene[J]. Chem Commun, 2010,46(38):7205-7207. doi: 10.1039/c0cc01236j
5. [5]
  Dong M, Zhao M, Ou S. A Luminescent Dye@MOF Platform:Emission Fingerprint Relationships of Volatile Organic Molecules[J]. Angew Chem Int Ed, 2014,53(6):1575-1579. doi: 10.1002/anie.201307331
6. [6]
  Cao K, Xia Y, Wang G. A Robust Luminescent Ba (Ⅱ) Metal Organic Framework Based on Ppyridine Carboxylate Ligand for Sensing of Small Molecules[J]. Inorg Chem Commun, 2015,53:42-45. doi: 10.1016/j.inoche.2015.01.021
7. [7]
  SONG Pengyue, ZHU Jiang, YU Bohao. Study on the Performance of Phosphotungstic Acid-urea/Fe₃O₄ Magnetic Oxidative Desulfurization Catalyst[J]. Chinese J Appl Chem, 2015,32(3):317-321.
8. [8]
  JIANG Chunjie, SUN Shengnan, WANG Xuyang. Synthesis of Dimethyl Ether from Methanol over Heteropoly Acid/Nanocrystalline HZSM-5 Complex Solid Acidic Catalyst[J]. Acta Chim Sin, 2013,71(5):810-814. doi: 10.6023/A13010107
9. [9]
  WANG Xuyang, SONG Pengyue, WANG Xiangsheng. In-situ Characterization and Reactivity of Heteropoly Acid-based Catalysts for Deep Hydrodesulfurization of Fluid Catalytic Cracking Gasoline[J]. Chinese J Appl Chem, 2014,31(8):990-992.
10. [10]
  CHEN Lidong, LIU DI, NIU Siqi. Oxidative Desulfurization of Organic Sulfides over Phosphotungstic Acid/Nano-ZSM-5 Composite Catalyst[J]. Chinese J Appl Chem, 2016,33(3):364-366.
11. [11]
  Thuery P, Harrowfield J. Uranyl Ion Complexes with Long-Chain Aliphatic α, ω-Dicarboxylates and 3d-Block Metal Counterions[J]. Inorg Chem, 2016,55(5):2133-2145. doi: 10.1021/acs.inorgchem.5b02540
12. [12]
  Eberle B, Damjanovic M, Enders M. Radical Monocationic Guanidino Functionalized Aromatic Compounds (GFAs) as Bridging Ligands in Dinuclear Metal Acetate Complexes:Synthesis, Electronic Structure, and Magnetic Coupling[J]. Inorg Chem, 2016,55(4):1683-1696. doi: 10.1021/acs.inorgchem.5b02614
1. [1]
  Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382
2. [2]
  Zehua Zhang , Haitao Yu , Yanyu Qi . Design Strategy for Thermally Activated Delayed Fluorescence Materials with Multiple Resonance Effect. Acta Physico-Chimica Sinica, 2025, 41(1): 100006-0. doi: 10.3866/PKU.WHXB202309042
3. [3]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
4. [4]
  Feng Lu , Tao Wang , Qi Wang . Preparation and Characterization of Water-Soluble Silver Nanoclusters: A New Design and Teaching Practice in Materials Chemistry Experiment. University Chemistry, 2025, 40(4): 375-381. doi: 10.12461/PKU.DXHX202406005
5. [5]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
6. [6]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
7. [7]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
8. [8]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067
9. [9]
  Renjie Xue , Chao Ma , Jing He , Xuechao Li , Yanning Tang , Lifeng Chi , Haiming Zhang . Catassembly in the Host-Guest Recognition of 2D Metastable Self-Assembled Networks. Acta Physico-Chimica Sinica, 2024, 40(9): 2309011-0. doi: 10.3866/PKU.WHXB202309011
10. [10]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
11. [11]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
12. [12]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
13. [13]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
14. [14]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266
15. [15]
  Jiming XI , Yukang TENG , Rui ZHANG , Zhenzhong LU . Fluorescent coordination polymers based on anthracene-and pyrene-derivative ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 847-854. doi: 10.11862/CJIC.20240367
16. [16]
  Yuanyu YANG , Jianhua XUE , Yujia BAI , Lulu CUI , Dongdong YANG , Qi MA . Design, synthesis, and detection of Al³⁺ of two zinc complexes based on Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1207-1216. doi: 10.11862/CJIC.20250005
17. [17]
  Yanfen PENG , Xinyue WANG , Tianbao LIU , Xiaoshuo WU , Yujing WEI . Syntheses and luminescence of four Cd(Ⅱ)/Zn(Ⅱ) complexes constructed by 1,3‐bis(4H‐1,2,4‐triazole)benzene. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1416-1426. doi: 10.11862/CJIC.20250018
18. [18]
  Youbo HU , Donggang LI , Changhua SUN , Zhenzhong LU , Songjun GU . Coordination polymers based on anthracene- and pyrene-derived ligands: Crystal structure, fluorescent property, and framework isomerization. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1681-1688. doi: 10.11862/CJIC.20250004
19. [19]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
20. [20]
  Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(832)
HTML views(232)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142