Citation: ZHU Jiang, GOU Wenxiu, WANG Xiaomin, CHEN Lidong, LENG Rubing, JIANG Chunjie. Synthesis of Ionic Coordination Compounds with Naphthalenedisulfonic Acid and Their Molecular Recognition Properties[J]. Chinese Journal of Applied Chemistry, ;2017, 34(1): 105-110. doi: 10.11944/j.issn.1000-0518.2017.01.160104 shu

Synthesis of Ionic Coordination Compounds with Naphthalenedisulfonic Acid and Their Molecular Recognition Properties

ZHU Jiang ^a,*,, ,
GOU Wenxiu ^a ,
WANG Xiaomin ^b ,
CHEN Lidong ^a ,
LENG Rubing ^a ,
JIANG Chunjie ^a,*,,

a.
School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 110629, China
b.
Experiment Center, Liaoning Normal University, Dalian, Liaoning 110629, China

Corresponding author: ZHU Jiang, zjryan@lnnu.edu.cn JIANG Chunjie, jiangcj@lnnu.edu.cn
Received Date: 11 March 2016
Revised Date: 31 May 2016
Accepted Date: 31 May 2016

Fund Project: the Doctoral Scientific Research Foundation of Liaoning Province 20131060

Figures(6)

Four compounds[M (en)(H₂O)₄]·1, 5-nds·(H₂O)₂(M=Ni (1), Co (2), Cd (3), Cu (4), based on ethylene diamine (en) and 1, 5-naphthalenedisulfonic acid (nds), were synthesized by hydrothermal synthesis method under room temperature. The structures of the crystals were confirmed by X-ray diffraction (XRD) method and SHELXTL-97 software. The four compounds have the same three dimensional (3D) framework in monoclinic C2/c space group, only different in metal atoms. The cell parameters of compound 1 are:a=1.69026(19) nm, b=1.01373(11) nm, c=1.3448(3) nm, α=90°, β=120.2650°, γ=90°, V=1.9901(5) nm³, Z=4, D_c=1.713 g/cm³, F(000)=1072, R₁=0.0326, wR₂=0.0867. One metal atom is coordinated to four oxygen atoms from water molecules and two nitrogen atoms of one ethylene diamine. There exit abundant hydrogen bonds interactions between free water molecules and oxygen atoms in 1, 5-naphthalenedisulfonic acid anion. One dimensional chains were formed through abundant hydrogen bonds and one[Ni (en)(H₂O)₄]²⁺ located between each two nds^2-. The two adjacent[Ni (en)(H₂O)₄]²⁺ arranged by the opposite mode (head to head). The properties of the two compounds were characterized by XRD, thermal gravimetric analysis (TGA), fluorescence spectroscopy and multi-function spectrometer. The molecular recognition properties of compound 3 with M=Cd in methanol solution was studied. The compound 3 was solved in different solvents in which the highest strength of fluorescence spectroscopy occurs in methanol solution. The strength of fluorescence spectroscopy decreases, with increasing concentration of methanol which may have potential applications in fluorescence probe to recognize polarity.
- naphthalenedisulfonic acid,
- molecular recognition,
- ethylene diamine,
- fluorescence
1. [1]
  Liu Y, Zhang J, Xu F. Lithium-Based 3D Coordination Polymer with Hydrophilic Structure for Sensing of Solvent Molecules[J]. Cryst Growth Des, 2008,8(9):3127-3129. doi: 10.1021/cg701173x
2. [2]
  Shao S, Zhu Y, Ma K. Two M (Ⅱ)-1, 5-NDS-dafo Supramolecular Architectures (M=Cu, Cd):Syntheses, Structures, and Photoluminescence Properties[J]. J Coord Chem, 2013,66(15):2702-2711. doi: 10.1080/00958972.2013.813938
3. [3]
  Jiang H, Liu Y, Ma J. Infinite Chains Constructed from Flexible Bis (benzimidazole) Based Ligands[J]. Polyhedron, 2008,27(12):2595-2602. doi: 10.1016/j.poly.2008.05.019
4. [4]
  Zhang Z, Xiang S, Rao S. A Rod Packing Microporous Metal Organic Framework with Open Metal Site for Selective Guest Sorption and Sensing of Nitrobenzene[J]. Chem Commun, 2010,46(38):7205-7207. doi: 10.1039/c0cc01236j
5. [5]
  Dong M, Zhao M, Ou S. A Luminescent Dye@MOF Platform:Emission Fingerprint Relationships of Volatile Organic Molecules[J]. Angew Chem Int Ed, 2014,53(6):1575-1579. doi: 10.1002/anie.201307331
6. [6]
  Cao K, Xia Y, Wang G. A Robust Luminescent Ba (Ⅱ) Metal Organic Framework Based on Ppyridine Carboxylate Ligand for Sensing of Small Molecules[J]. Inorg Chem Commun, 2015,53:42-45. doi: 10.1016/j.inoche.2015.01.021
7. [7]
  SONG Pengyue, ZHU Jiang, YU Bohao. Study on the Performance of Phosphotungstic Acid-urea/Fe₃O₄ Magnetic Oxidative Desulfurization Catalyst[J]. Chinese J Appl Chem, 2015,32(3):317-321.
8. [8]
  JIANG Chunjie, SUN Shengnan, WANG Xuyang. Synthesis of Dimethyl Ether from Methanol over Heteropoly Acid/Nanocrystalline HZSM-5 Complex Solid Acidic Catalyst[J]. Acta Chim Sin, 2013,71(5):810-814. doi: 10.6023/A13010107
9. [9]
  WANG Xuyang, SONG Pengyue, WANG Xiangsheng. In-situ Characterization and Reactivity of Heteropoly Acid-based Catalysts for Deep Hydrodesulfurization of Fluid Catalytic Cracking Gasoline[J]. Chinese J Appl Chem, 2014,31(8):990-992.
10. [10]
  CHEN Lidong, LIU DI, NIU Siqi. Oxidative Desulfurization of Organic Sulfides over Phosphotungstic Acid/Nano-ZSM-5 Composite Catalyst[J]. Chinese J Appl Chem, 2016,33(3):364-366.
11. [11]
  Thuery P, Harrowfield J. Uranyl Ion Complexes with Long-Chain Aliphatic α, ω-Dicarboxylates and 3d-Block Metal Counterions[J]. Inorg Chem, 2016,55(5):2133-2145. doi: 10.1021/acs.inorgchem.5b02540
12. [12]
  Eberle B, Damjanovic M, Enders M. Radical Monocationic Guanidino Functionalized Aromatic Compounds (GFAs) as Bridging Ligands in Dinuclear Metal Acetate Complexes:Synthesis, Electronic Structure, and Magnetic Coupling[J]. Inorg Chem, 2016,55(4):1683-1696. doi: 10.1021/acs.inorgchem.5b02614
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