Citation: ZHANG Hao, YU Qizhou, ZHANG Xinhui, LIU Jingsheng. Properties of Branched Structure Nd-base Polybutadiene Rubber with Narrow Relative Molecular Mass Distribution[J]. Chinese Journal of Applied Chemistry, ;2016, 33(12): 1408-1414. doi: 10.11944/j.issn.1000-0518.2016.12.160399 shu

Properties of Branched Structure Nd-base Polybutadiene Rubber with Narrow Relative Molecular Mass Distribution

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a National Engineering Laboratory for Wheat and Corn Deep Processing, College of Food Science and Engineering, Jilin Agricultural University, Changchun 130118, China;
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b Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: LIU Jingsheng,
Received Date: 30 September 2016
Available Online: 24 October 2016
Fund Project:

The structure and properties of polybutadiene rubber(BR) with narrow molecular mass distribution synthesized by rare earth Nd catalysts(NMWD-NdBR) were studied and compared with those of the sample with a wider molecular weight distribution(WMWD-NdBR). The results show that NMWD-NdBR gets a steady rheological behavior under the same rotation rate. The scorch time and the optimum curing point of NMWD-NdBR are similar to those of WMWD-NdBR, but the minimum torque(M_L), maximum torque(M_H) and mechanical properties of NMWD-NdBR are slightly better than those of WMWD-NdBR. The data of rubber processing analyzer(RPA) show that the Payne effect of NMWD-NdBR are similar to those of WMWD-NdBR, and the hysteresis loss(tanδ) of NMWD-NdBR are superior to those of WMWD-NdBR. The results of tanδ data are in good agreement with those of carbon black dispersion, heat build-up, permanent set, as well as rolling resistance.
- narrow molecular mass distribution,
- long chain branching,
- Nd-based butadiene rubber,
- payne effect,
- hysteresis loss
1. [1]
  [1] WEI Jinzhu,LIAO Yuzhen,HU Zhenya. The Chain Structure of Rare Earth Butadiene Rubber, the Relationship Between the Quantity, Distribution and Properties of Molecules[J]. China Synth Rubber Ind,1983,6(3):214-218(in Chinese).魏金柱,廖玉珍,胡振亚. 稀土顺丁橡胶的链结构,分子量及其分布与性能的关系[J]. 合成橡胶工业,1983,6(3):214-218.
2. [2]
  [2] JIANG Zhilan,ZHANG Shouxin,LIN Yunqing. Synthesis and Properties of Rare Earth Polybutadiene with Narrow Molecular Weight Distribution[J]. China Synth Rubber Ind,1990,14(1):11-14(in Chinese).蒋芝兰,张守信,林云清. 窄分子量分布稀土顺丁橡胶的合成及其性能[J]. 合成橡胶工业,1990,14(1):11-14.
3. [3]
  [3] LIN Yunqing,ZHANG Xinhui,JIANG Liansheng,et al. Structure and Properties of Rare-Earth Polybutadiene Rubber[J]. China Synth Rubber Ind,1993,16(2):77-80(in Chinese).林云青,张新惠,姜连生,等. 稀土顺丁橡胶的结构与性能[J]. 合成橡胶工业,1993,16(2):77-80.
4. [4]
  [4] ZHANG Xu,XIAO Liguang,CAI Hongguang. The Influence Factors of the Molar Mass of Nd-based Polybutadiene Rubber[J]. J Jilin Jianzhu Univ,2009,26(6):4-8(in Chinese).张旭,肖力光,蔡洪光. 影响稀土顺丁橡胶分子量的因素[J]. 吉林建筑工程学院学报,2009,26(6):4-8.
5. [5]
  [5] FU Yanjie,ZHAO Zhenhua,CAO Zhengang.Comprehensive Properties of Domestic Cis-1,4-polybutadiene Rubber with Neodymium Catalyst System[J]. China Synth Rubber Ind,1999,22(3):140-145(in Chinese).傅彦杰,赵振华,曹振刚. 国产钕系BR的综合性能[J]. 合成橡胶工业,1999,22(3):140-145.
6. [6]
  [6] ZHANG Xinhui,LI Bailin,CAI Hongguang. Properties of Cis-1,4-polybutadien Rubber by Neodymium Caprate Catalyst System[J]. China Synth Rubber Ind,2001,24(1):18-21(in Chinese).张新惠,李柏林,蔡洪光. 新癸酸钕系顺丁橡胶的性能[J]. 合成橡胶工业,2001,24(1):18-21.
7. [7]
  [7] ZHANG Xinhui,LI Bailin,ZHANG Xuequan,et al. Properties of Domestic Cis-1,4-polybutadiene Rubber Polymerized with Rare-Earth Catalyst[J]. China Synth Rubber Ind,2006,29(1):11-13(in Chinese).张新惠,李柏林,张学全,等. 国产稀土顺丁橡胶的性能[J]. 合成橡胶工业,2006,29(1):11-13.
8. [8]
  [8] ZHANG Xinhui,LI Bailin,ZHANG Xuequan. Cis-polybutadiene Synthesized with Rare-earth Catalysts[J]. Spec Purpose Rubber Prod,2005,26(2):1-2(in Chinese).张新惠,李柏林,张学全. 稀土催化剂顺式聚丁二烯橡胶[J]. 特种橡胶制品,2005,26(2):1-2.
9. [9]
  [9] JIN Chunshan,SUN Shulian,GAO Yuanzhe,et al. Long Chain Branching in Polybutadiene and Polyisoprene Rubbers[J]. China Synth Rubber Ind,1991,14(5):335-338(in Chinese).金春山,孙淑莲,高元哲,等. 聚丁二烯和聚异戊二烯橡胶的长链支化[J]. 合成橡胶工业,1991,14(5):335-338.
10. [10]
  [10] LIU Dong,WANG Qingfu,SONG Zhibin,et al. Study on RPA Dynamic Properties of Different Polybutadiene Rubber[J]. World Rubber Ind,2009,36(6):19-24(in Chinese).刘冬,王庆富,宋智彬,等. 不同聚丁二烯橡胶RPA动态性能分析[J]. 世界橡胶工业,2009,36(6):19-24.
11. [11]
  [11] ZHANG Xinhui,LI Bailin,DONG Weimin,et al. Effects of Relative Molecular Mass and Its Distribution on Properties of Rare-Earth Catalyst-based Cis-1,4-polybutadiene Rubber[J]. China Synth Rubber Ind,2007,30(5):391-394(in Chinese).张新惠,李柏林,董为民,等. 相对分子质量及其分布对稀土顺丁橡胶性能的影响[J]. 合成橡胶工业,2007,30(5):391-394.
12. [12]
  [12] JIANG Liansheng,ZHANG Xuequan,DONG Weimin,et al. Methods for Preparing a Rare-earth cis-1,4-Polybutadiene Rubber with a Controlled Molecular Weight Distribution:US7,288,611B2[P]. 2004-09-27(in Chinese).姜连升,张学全,董为民,等. 分子量分布可控的稀土顺丁橡胶的制备方法:US7,288,611B2[P]. 2004-09-27.
13. [13]
  [13] Neusa M T,Pires A,Ferreira A,et al. Performance Evaluation of High-cis-1,4-polybutadienes[J]. J Appl Polym Sci,2006,99(1):88-99.
14. [14]
  [14] John S D,Henry A P. Application of RPA 2000 Rubber Processing Performance Analyzer[J]. Rubber Ind,1998,45(5):301-314(in Chinese).John S D,Henry A P. RPA 2000橡胶加工性能分析仪的应用[J]. 橡胶工业,1998,45(5):301-314.
15. [15]
  [15] WANG Guiyi. Application of Rubber Processability Tester RPA2000 to Rubber Study[J]. Spec Purpose Rubber Prod,2001,22(1):57-58(in Chinese).王贵一. RPA2000橡胶加工分析仪在橡胶研究中的应用[J]. 特种橡胶制品,2001,22(1):57-58.
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沈阳化工大学材料科学与工程学院沈阳 110142