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Citation: XU Shengnan, NA Zhaolin, YIN Dongming, WU Yaoming, WANG Limin. Performance of A Copper-Cerium Redox Flow Battery[J]. Chinese Journal of Applied Chemistry, ;2016, 33(12): 1462-1464. doi: 10.11944/j.issn.1000-0518.2016.12.160300 shu

Performance of A Copper-Cerium Redox Flow Battery

XU Shengnan ^a,c ,
NA Zhaolin ^a,c ,
YIN Dongming ^a ,
WU Yaoming ^a,b ,
WANG Limin ^a,b,,

1.
a State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, CAS, Changchun 130022, China;
2.
b Changzhou Institute of Energy Storage Materials & Devices, Changzhou, Jiangsu 213000, China;
3.
c University of Chinese Academy of Science, Beijing 130049, China

Corresponding author: WANG Limin,
Received Date: 22 July 2016
Available Online: 22 August 2016
Fund Project:

We reported a novel cerium-copper redox flow battery and, the cyclic voltammetry characteristics of the Ce³⁺/Ce⁴⁺, Cu²⁺/Cu⁰ redox couples were studied. Moreover, a laboratory level redox flow battery was assembled to study the charge-discharge performance of this battery. The test result suggests that the battery delivers a desirable discharge voltage of approximately 1.0 V, with a high average coulombic efficiency(CE) of 100% and energy efficiency(EE) of over 75% during 100 cycles at 45 mA charge-discharge current.
- Ce-Cu,
- flow battery,
- electrochemical performance,
- cycling performance
1. [1]
  [1] Thaller L H. Electrically Rechargeable Redox Flow Cell:US,3996064[P],1976.
2. [2]
  [2] Remick R J,Ang P G P. Electrically Rechargeable Anionically Active Reduction-oxidation Electrical Storage-supply System:US,4485154 A[P],1984.
3. [3]
  [3] Skyllas-Kazacos M,Grossmith F. Efficient Vanadium Redox Flow Cell[J]. J Electrochem Soc,1987,134(12):2950-2953.
4. [4]
  [4] ZHANG Shengtao,ZHANG Rui,LI Dan. Study on the Electrical Property of All-chromium Flow Battery[J]. Chinese Battery Ind,2007,12(4):225-227(in Chinese).张胜涛,张瑞,李丹. 全铬液流电池的电性能研究[J]. 电池工业,2007,12(4):225-227.
5. [5]
  [5] Leung P K,Ponce-De-León C,Low C T J,et al. Characterization of a Zinc-cerium Flow Battery[J]. J Power Sources,2011,196(11):5174-5185.
6. [6]
  [6] Grubač Z,Metikoš-Hukovič M. Nucleation of Copper on an Assembly of Carbon Microelectrodes[J]. Mater Lett,2007,61(3):794-798.
7. [7]
  [7] Majidi M R,Asadpour-Zeynali K,Hafezi B. Reaction and Nucleation Mechanisms of Copper Electrodeposition on Disposable Pencil Graphite Electrode[J]. Electrochim Acta,2009,54(3):1119-1126.
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