Citation: REN Zhenbo, YING Zongrong, LIU Xindong, WAN Hui. Preparation and Electrochemical Properties of Monthmorillonite-supported Nitrogen-doped Porous Carbon@Polyaniline Composites[J]. Chinese Journal of Applied Chemistry, ;2016, 33(12): 1448-1454. doi: 10.11944/j.issn.1000-0518.2016.12.160056 shu

Preparation and Electrochemical Properties of Monthmorillonite-supported Nitrogen-doped Porous Carbon@Polyaniline Composites

1.
School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Corresponding author: YING Zongrong,
Received Date: 2 February 2016
Available Online: 26 February 2016

The composites of polyaniline(PANI) coating monthmorillonite-supported nitrogen-doped carbon(NMC) were prepared by in situ polymerization of aniline upon NMC in the hydrochloric acid(HCl) solution and the mixed acid solution composed of HCl acid and D-camphorsulfonic acid(DCSA). Fourier transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy were employed to investigate the effect of the doping acid on the crystallization property. NMC@PANI doped with HCl has a short stick morphology, while one doped with HCl/DCSA exhibits a granular and flaked morphology and its crystallization degree is higher than that of the former. NMC@PANI doped with HCl/DCSA has a specific capacitance of 412.5 F/g at 0.5 A/g, which is increased by 24.1% compared to that of NMC@PANI doped with HCl, and shows a lower equivalent series resistance and charge transfer resistance. However, the capacitance of NMC@PANI doped with HCl retains 81.4% at large charge/discharge current, higher than 58.4% of one doped with HCl/DCSA.
- monthmorillonite,
- nitrogen-doped porous carbon,
- polyaniline,
- hydrochloric acid,
- D-camphorsulfonic acid,
- supercapacitor
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沈阳化工大学材料科学与工程学院沈阳 110142