Citation: FENG Xiaodong, LIN Xiaomen, WANG Yang, BAI Fengying, XING Yongheng. Synthesis and Phenol Red Catalytic Bromination Activity of Polypyrazole Borate Oxovanadium Complex[J]. Chinese Journal of Applied Chemistry, ;2016, 33(11): 1303-1309. doi: 10.11944/j.issn.1000-0518.2016.11.160033 shu

Synthesis and Phenol Red Catalytic Bromination Activity of Polypyrazole Borate Oxovanadium Complex

1.
College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China

Corresponding author: BAI Fengying,
Received Date: 20 January 2016
Available Online: 30 March 2016
Fund Project:

Oxovanadium complex[VO(C₆H₉O₂)(Tp^4I)]·2H₂O(Tp^4I=tri-(4-lodopyrazole)borate) was designed and synthesized. The spectral and structural characters of the complex were analyzed by elemental analysis, IR spectroscopy, UV spectroscopy, thermogravimetric analysis, X-ray powder diffraction and single crystal X-ray diffraction analysis. The structural analysis shows that the complex has an octahedron geometry with hexa-coordinated metal. Ligand tri-(4-lodopyrazole)borate adopts a tridentate chelating coordination mode. The complex exhibits good catalytic activity in the mimic bromination of phenol red, and the reaction rate constant is 2.424×10² (mol/L)^-2·s^-1. Meanwhile, the reaction system was applied in the hydrogen peroxide determination.
- oxovanadium complex,
- tri-(4-lodopyrazole)borate,
- crystal structure,
- mmimic catalytic bromination
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沈阳化工大学材料科学与工程学院沈阳 110142