Citation: ZHANG Baotong, WANG Yan, LI Jianfu, YOU Zhenyu, XIA Houping, ZHU Zhaojie, XU Jinlong, TU Chaoyang, WANG Hongyan. Effect of Co-Dopant Rare-Earth Ions on the Spectroscopic Properties of Er³⁺ Activated Mid-Infrared Laser Crystals[J]. Chinese Journal of Applied Chemistry, ;2016, 33(9): 994-1001. doi: 10.11944/j.issn.1000-0518.2016.09.160231 shu

Effect of Co-Dopant Rare-Earth Ions on the Spectroscopic Properties of Er³⁺ Activated Mid-Infrared Laser Crystals

1.
a Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
2.
b College of Material Science and Engineering, Fujian Normal University, Fuzhou 350007, China;
3.
c CRYSTECH Inc., Qingdao, Shandong 266107, China

Corresponding author: WANG Yan,
Received Date: 1 June 2016
Available Online: 29 June 2016
Fund Project:

The Er³⁺-doped crystals can produce 2.7~3.0 μm mid-infrared(MIR) lasers, which have attracted much attention for their numerous applications in laser medical surgery, optical communication, enviromental detector and electro-optical countermeasure, etc. Based on the past few years' work on the study of Er³⁺ activated crystals by our team, we review the effect of co-dopant rare-earth ions on the spectroscopic properties of Er³⁺ activated MIR laser crystals, including the sensitizing ions Cr³⁺, Yb³⁺, etc. which can enhance the intensity of characteristic absorption peaks of Er³⁺; the deactivating ions Ho³⁺, Pr³⁺, etc. which can inhibit the self-termination bottleneck effects, furthermore, the co-dopant Nd³⁺ ion can play a dual role at the same time. In the end, the expectations on the study of MIR lasers are presented.
- Er ion,
- mid-infrared laser crystal,
- spectroscopic properties,
- sensitizing ion,
- deactivating ion
1. [1]
  [1] FENG Lu.The Invention and Development of Laser[J].Physics,2005,(8):6-7(in Chinese).冯璐.激光的发明和发展[J].物理,2005,(8):6-7.
2. [2]
  [2] Sorokina I T,Vodopyanov K L.Solid-state Mid-infrared Laser Sources[M].Springer Science&Business Media,2003.
3. [3]
  [3] Vodopyanov K L.Mid-infrared Optical Parametric Generator with Extra-wide (3~19μm) Tunability:Applications for Spectroscopy of Two-dimensional Electrons in Quantum Wells[J].JOSA B,1999,16(9):1579-1586.
4. [4]
  [4] Godard A.Infrared (2~12μm) Solid-state Laser Sources:A Review[J].Comptes Rendus Physique,2007,8(10):1100-1128.
5. [5]
  [5] Wang Y,You Z,Li J,et al.Spectroscopic Analyses of Yb,Er:Gd₃Ga₅O₁₂,Crystal as a Novel Candidate of LD Pumped~3.0μm Laser[J].Mater Res Bull,2013,48(8):2969-2972.
6. [6]
  [6] Wang Y,You Z,Li J,et al.Spectroscopic Analysis of Cr,Er:Gd₃Ga₅O₁₂,Crystals as Candidates of Potential Xenon Lamp Pumped~2.7μm Laser[J].Opt Commun,2012,285(5):650-654.
7. [7]
  [7] Wang Y,You Z,Li J,et al.Crystal Growth and Optical Properties of Cr³⁺,Er³⁺,RE³⁺:Gd₃Ga₅O₁₂(RE=Tm,Ho,Eu) for Mid-IR Laser Applications[J].J Lumin,2012,132(3):693-696.
8. [8]
  [8] WANG Yan,XIA Houping,LI Jianfu,et al.The Study of MIR Laser Crystal of Er³⁺ Activated SrGdGa₃O₇[C].The Crystal Growth and Material Academic Meeting,2015(in Chinese).王燕,夏侯平,李坚富,等.Er³⁺激活SrGdGa₃O₇中红外激光晶体的研究[C].全国晶体生长与材料学术会议,2015.
9. [9]
  [9] Thiel C W,Sun Y,Cone R L.Progress in Relating Rare-earth Ion 4f and 5d Energy Levels to Host Bands in Optical Materials for Hole Burning,Quantum Information and Phosphors[J].J Mod Opt,2002,49(14):2399-2411.
10. [10]
  [10] Dinerman B J,Moulton P F.3μm CW Laser Operations in Erbium-doped YSGG,GGG,and YAG[J].Opt Lett,1994,19(15):1143-1145.
11. [11]
  [11] Wang Y,You Z,Li J,et al.Spectroscopic Investigations of Highly Doped Er³⁺:GGG and Er³⁺/Pr³⁺:GGG crystals[J].J Phys D-Appl Phys,2009,42(21):215406-215413.
12. [12]
  [12] You Z,Wang Y,Xu J,et al.Diode-End-Pumped Midinfrared Multiwavelength Er:Pr:GGG Laser[J].IEEE Photon Technol Lett,2014,26(7):667-670.
13. [13]
  [13] Wang Y,Li J,Zhu Z,et al.Impact of Codopant Ions on 2.5~3.0μm Emission of Er³⁺:⁴I_11/2→⁴I_13/2,Transition in Yb,Er,Eu:LaYSGG Crystal[J].J Quant Spectrosc Radiat Transfer,2015,167(24):76-81.
14. [14]
  [14] WANG Yan.The Study of Erbium Doped Gd₃Ga₅O₁₂~3.0μm Mid-IR Laser Crystals[D].Fuzhou:Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,2011(in Chinese).王燕.铒离子激活的Gd₃Ga₅O₁₂~3.0μm波段中红外激光晶体的研究[D].福州:中国科学院福建物质结构研究所,2011.
15. [15]
  [15] Xia H,Feng J,Wang Y,et al.The effects of Ho³⁺ and Pr³⁺ Ions on the Spectroscopic Properties of Er³⁺ Doped SrGdGa₃O₇ Crystals Used in Mid-infrared Lasers[J].J Phys D Appl Phys,2015,48(43):435106-435111.
16. [16]
  [16] Wang Y,Li J,You Z,et al.Enhanced 2.7μm Emission and its Origin in Nd³⁺/Er³⁺,Codoped SrGdGa₃O₇ Crystal[J].J Quant Spectrosc Radiat Transfer,2014,149:253-257.
17. [17]
  [17] Xia H,Feng J,Wang Y,et al.Evaluation of Spectroscopic Properties of Er³⁺/Yb³⁺/Pr³⁺:SrGdGa₃O₇ Crystal for Use in Mid-infrared Lasers[J].Sci Rep,2015,5:13988-13996.
18. [18]
  [18] Xia H,Feng J,Ji Y,et al.2.7μm Emission Properties of Er³⁺/Yb³⁺/Eu³⁺:SrGdGa₃O₇ and Er³⁺/Yb³⁺/Ho³⁺:SrGdGa₃O₇ Crystals[J].J Quant Spectrosc Radiat Transfer,2016,173:7-12.
19. [19]
  [19] Wang Y,Li J,Zhu Z,et al.Dual Function of Nd³⁺ in Nd,Er:LuYSGG Crystal for LD Pumped~3.0μm Mid-infrared Laser[J].Opt Express,2015,23(14):18554-18562.
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沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Co-Dopant Rare-Earth Ions on the Spectroscopic Properties of Er3+ Activated Mid-Infrared Laser Crystals

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通讯作者: 陈斌, bchen63@163.com

Effect of Co-Dopant Rare-Earth Ions on the Spectroscopic Properties of Er³⁺ Activated Mid-Infrared Laser Crystals