Citation: LOU Sunqi, XUAN Tongtong, YU Caiyan, LI Huili. Synthesis, Properties and Applications of Inorganic Halide Perovskite Nanocrystals[J]. Chinese Journal of Applied Chemistry, ;2016, 33(9): 977-993. doi: 10.11944/j.issn.1000-0518.2016.09.160212 shu

Synthesis, Properties and Applications of Inorganic Halide Perovskite Nanocrystals

1.
Engineering Research Center for Nanophotonics & Advanced Instrument, Ministry of Education, School of Physics and Material Science, East China Normal University, Shanghai 200062, China

Corresponding author: LI Huili,
Received Date: 20 May 2016
Available Online: 23 June 2016
Fund Project:

Inorganic halide perovskite CsPbX₃(X=Cl,Br,I) nanocrystals(NCs) have been received much concern because it owns many excellent optical properties, such as high quantum yield(~90%), the emission wavelength covering the entire visible light region(400~700 nm), and the narrow full width at half maximum(12~42 nm). These advantages make it becomes one of the luminescence materials which have the most potential applications. Therefore, in recent years, reports involving inorganic halide perovskite materials become more and more. In this review, the development history, the synthetic routes, structures, growth mechanisms, and applications of inorganic halide perovskite NCs that make them excellent optoelectronic materials for various strategies are mainly discussed and highlighted. The existing problems of inorganic halide perovskite luminescence materials under the current research backgrounds are summarized. Finally, perspectives on future exploration of inorganic halide perovskite NCs for photoelectric devices are also given.
- Inorganic halide perovskite,
- CsPbX₃(X=Cl,Br,I),
- photoluminescent materials,
- nanocrystals,
- photoelectric devices
1. [1]
  [1] Kagan C R,Mitzi D B.Dimitrakopoulos C D.Organic-inorganic Hybrid Materials as Semiconducting Channels in Thin-film Field-effect Transistors[J].Science,1999,286(5441):945-947.
2. [2]
  [2] Kojima Akihiro,Kenjiro Teshima,Yasuo Shirai,et al.Organometal Halide Perovskites as Visible-light Sensitizers for Photovoltaic Cells[J].J Am Chem Soc,2009,131(17):6050-6051.
3. [3]
  [3] Werner J,Weng C H,Walter A,et al.Efficient Monolithic Perovskite/Silicon Tandem Solar Cell With Cell Area >1 cm²[J].J Phys Chem Lett,2016,7(1):161-166.
4. [4]
  [4] Møller C K.Crystal Structure and Photoconductivity of Caesium Plumbohalides[J].Nature,1958,182:1436.
5. [5]
  [5] Nikl M,Nitscha K,Poláka K,et al.Quantum Size Effect in the Excitonic Luminescence of CsPbX-like Quantum Dots in CsX (X=Cl,Br) Single Crystal Host[J].J Lumin,1997,72(74):377-379.
6. [6]
  [6] Zhang D D,Eaton S W,Yu Y,et al.Solution-Phase Synthesis of Cesium Lead Halide Perovskite Nanowires[J].J Am Chem Soc,2015,137(29):9230-9233.
7. [7]
  [7] Bekenstein Y,Koscher B A,Eaton S W,et al.Highly Luminescent Colloidal Nanoplates of Perovskite Cesium Lead Halide and Their Oriented Assemblies[J].J Am Chem Soc,2015,137(51):16008-16011.
8. [8]
  [8] Sun S,Yuan D,Xu Y,et al.Ligand-Mediated Synthesis of Shape-Controlled Cesium Lead Halide Perovskite Nanocrystals via Reprecipitation Process at Room Temperature[J].ACS Nano,2016,10(3):3648-3657.
9. [9]
  [9] Swarnkar A,Chulliyil R,Ravi V K,et al.Colloidal CsPbBr₃ Perovskite Nanocrystals:Luminescence Beyond Traditional Quantum Dots[J].Angew Chem Int Ed,2015,54(51):1-6.
10. [10]
  [10] Raino G,Nedelcu G,Protesescu L,et al.Single Cesium Lead Halide Perovskite Nanocrystals at Low Temperature:Fast Single-Photon Emission,Reduced Blinking,and Exciton Fine Structure[J].ACS Nano,2016,10(2):2485-2490.
11. [11]
  [11] Chang Y H,Park C H.First-principles Study of the Structural and the Electronic Properties of the Lead-halide-based Inorganic-organic Perovskites (CH₃NH₃) PbX₃ and CsPbX₃(X=Cl,Br,I)[J].J Korean Phys Soc,2004,44(4):889-893.
12. [12]
  [12] Lin C C,Meijerink A,Liu R S.Critical Red Components for Next-Generation White LEDs[J].J Phys Chem Lett,2016,7(3):495-503.
13. [13]
  [13] Palazon F,Di Stasio F,Akkerman Q A,et al.Polymer-free Films of Inorganic Halide Perovskite Nanocrystals as UV-to-white Color-conversion Layers in LEDs[J].Chem Mater,2016,28(9):2902-2906.
14. [14]
  [14] Song J Z,Li J H,Li X M,et al.Quantum Dot Light-Emitting Diodes Based on Inorganic Perovskite Cesium Lead Halides (CsPbX₃)[J].Adv Mater,2015,27(44):7162-7167.
15. [15]
  [15] Wang Y,Li X,Song J,et al.All-Inorganic Colloidal Perovskite Quantum Dots:A New Class of Lasing Materials with Favorable Characteristics[J].Adv Mater,2015,27(44):7101-7108.
16. [16]
  [16] Eaton S W,Lai M,Gibson N A,et al.Lasing in Robust Cesium Lead Halide Perovskite Nanowires[J].Proc Natl Acad Sci,2016,113(8):1993-1998.
17. [17]
  [17] Xu Y,Chen Q,Zhang C,et al.Two-Photon-Pumped Perovskite Semiconductor Nanocrystal Lasers[J].J Am Chem Soc,2016,138(11):3761-3768.
18. [18]
  [18] Ramasamy P,Lim D H,Kim B,et al.All-inorganic Cesium Lead Halide Perovskite Nanocrystals for Photodetector Applications[J].Chem Commun,2016,52(10):2067-2070.
19. [19]
  [19] Beal R E,Slotcavage D J,Leijtens T,et al.Cesium Lead Halide Perovskites with Improved Stability for Tandem Solar Cells[J].J Phys Chem Lett,2016,7(5):746-751.
20. [20]
  [20] Lignos I,Stavrakis S,Nedelcu G,et al.Synthesis of Cesium Lead Halide Perovskite Nanocrystals in a Droplet-Based Microfluidic Platform:Fast Parametric Space Mapping[J].Nano Lett,2016,16(3):1869-1877.
21. [21]
  [21] Akkerman Q A,D'Innocenzo V,Accornero S,et al.Tuning the Optical Properties of Cesium Lead Halide Perovskite Nanocrystals by Anion Exchange Reactions[J].J Am Chem Soc,2015,137(32):10276-10281.
22. [22]
  [22] Protesescu L,Yakunin S,Bodnarchuk M I,et al.Nanocrystals of Cesium Lead Halide Perovskites (CsPbX₃,X=Cl,Br,and I):Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut[J].Nano Lett,2015,15(6):3692-3696.
23. [23]
  [23] Bai Z L,Zhong H Z.Halide Perovskite Quantum Dots:Potential Candidates for Display Technology[J].Sci Bull,2015,60(18):1622-1624.
24. [24]
  [24] Tanford C.Theory of Micelle Formation in Aqueous Solutions[J].J Phys Chem,1974,78(24):2469-2479.
25. [25]
  [25] Eastoe J,Hollamby M J,Hudson L.Recent Advances in Nanoparticle Synthesis with Reversed Micelles[J].Adv Colloid Interface Sci,2006,128:5-15.
26. [26]
  [26] Koolyk M,Amgar D,Aharon S,et al.Kinetics of Cesium Lead Halide Perovskite Nanoparticle Growth;Focusing and De-Focusing of Size Distribution[J].Nanoscale,2016,8(12):6403-6409.
27. [27]
  [27] Kim Y,Yassitepe E,Voznyy O,et al.Efficient Luminescence from Perovskite Quantum Dot Solids[J].ACS Appl Mater Interfaces,2015,7(45):25007-25013.
28. [28]
  [28] Palazon F,Akkerman Q A,Prato M,et al.X-ray Lithography on Perovskite Nanocrystals Films:From Patterning with Anion-Exchange Reactions to Enhanced Stability in Air and Water[J].ACS Nano,2016,10(1):1224-1230.
29. [29]
  [29] Akkerman Q A,Motti S G,Kandada S A R,et al.Solution Synthesis Approach to Colloidal Cesium Lead Halide Perovskite Nanoplatelets with Monolayer-Level Thickness Control[J].J Am Chem Soc,2016,138(3):1010-1016.
30. [30]
  [30] Nedelcu G,Protesescu L,Yakunin S,et al.Fast Anion-Exchange in Highly Luminescent Nanocrystals of Cesium Lead Halide Perovskites (CsPbX₃,X=Cl,Br,I)[J].Nano Lett,2015,15(8):5635-5640.
31. [31]
  [31] Palazon F,Akkerman Q A,Prato M,et al.X-Ray Lithography on Perovskite Nanocrystals Films:From Patterning with Anion-Exchange Reactions to Enhanced Stability in Air and Water[J].ACS Nano,2016,10(1):1224-1230.
32. [32]
  [32] Wu K F,Liang G J,Shang Q Y,et al.Ultrafast Interfacial Electron and Hole Transfer from CsPbBr₃ Perovskite Quantum Dots[J].J Am Chem Soc,2015,137(40):12792-12795.
33. [33]
  [33] Wang Y,Li X,Zhao X,et al.Nonlinear Absorption and Low-threshold Multi-photon Pumped Stimulated Emission from All-inorganic Perovskite Nanocrystals[J].Nano lett,2016,16(1):448-453.
34. [34]
  [34] Makarov N S,Guo S,Isaienko O,et al.Spectral and Dynamical Properties of Single Excitons,Biexcitons,and Trions in Cesium-Lead-Halide Perovskite Quantum Dots[J].Nano Lett,2016,16(4):2349-2362.
35. [35]
  [35] Raino G,Nedelcu G,Protesescu L,et al.Single Cesium Lead Halide Perovskite Nanocrystals at Low Temperature:Fast Single-Photon Emission,Reduced Blinking and Exciton Fine Structure[J].ACS Nano,2016,10(2):2485-2490.
36. [36]
  [36] Seth S,Mondal N,Patra S,et al.Fluorescence Blinking and Photo-activation of All-inorganic Perovskite Nanocrystals,CsPbBr₃ and CsPbBr₂I[J].J Phys Chem Lett,2016,7(2):266-271.
37. [37]
  [37] De Roo J,Ibáñez M,Geiregat P,et al.Highly Dynamic Ligand Binding and Light Absorption Coefficient of Cesium Lead Bromide Perovskite Nanocrystals[J].ACS Nano,2016,10(2):2071-2081.
38. [38]
  [38] Zhang X Y,Lin H,Huang H,et al.Enhancing the Brightness of Cesium Lead Halide Perovskite Nanocrystal Based Green Light-emitting Devices Through the Interface Engineering with Per fluorinated Ionomer[J].Nano Lett,2016,16(2):1415-1420.
39. [39]
  [39] Zhang X L,Xu B,Zhang J B,et al.All-Inorganic Perovskite Nanocrystals for High-Efficiency Light Emitting Diodes:Dual-Phase CsPbBr₃-CsPb₂Br₅ Composites[J].Adv Funct Mater,2016,26(25):4595-4600.
40. [40]
  [40] Li G,Rivarola F W R,Davis N J L K,et al.Highly Efficient Perovskite Nanocrystal Light-Emitting Diodes Enabled by a Universal Crosslinking Method[J].Adv Mater,2016,28(18):3528-3534.
41. [41]
  [41] Wei S,Yang Y,Kang X,et al.Room-temperature and Gram-scale Synthesis of CsPbX₃(X=Cl,Br,I) Perovskite Nanocrystals with 50~85% Photoluminescence Quantum Yields[J].Chem Commun,2016,52(45):7265-7268.
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