Citation: YANG Chengxiong, WANG Shiwei, YAN Xiuping. Adsorption Thermodynamics and Kinetics of Phenols on Metal-Organic Framework Aluminum Terephthalate in Water[J]. Chinese Journal of Applied Chemistry, ;2016, 33(9): 1040-1046. doi: 10.11944/j.issn.1000-0518.2016.09.160211 shu

Adsorption Thermodynamics and Kinetics of Phenols on Metal-Organic Framework Aluminum Terephthalate in Water

1.
Research Center for Analytical Sciences, College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: YAN Xiuping,
Received Date: 20 May 2016
Available Online: 27 June 2016
Fund Project:

Adsorption of phenols such as o-nitrophenol, phenol, and catechol on metal-organic framework aluminum terephthalate[MIL-53(Al), MIL:Materials of Institut Lavoisier] was investigated in detail in terms of adsorption isotherms, thermodynamics, and kinetics. The adsorption of the phenols on MIL-53(Al) follows a pseudo-second order kinetic model. Intraparticle diffusion model analysis reveals that the adsorption of the phenols on MIL-53(Al) proceeds by two phases, surface sorption and intraparticle/pore diffusion. The adsorption of phenols fits well with the Freundlich model. In addition, the results indicate that the adsorption of the phenols on MIL-53(Al) is a thermodynamically spontaneous process with positive enthalpy change and positive entropy change. The adsorption capacities for o-nitrophenol, phenol, and catechol at 40℃ are 78.6, 30.5, and 16.5 mg/g, respectively.
- metal-organic framework,
- adsorption,
- phenols,
- aluminum terephthalate
1. [1]
  [1] Snyder S A,Westerhoff P,Yoon Y.Pharmaceuticals,Personal Care Products and Endocrine Disrupters in Water:Implications for the Water Industry[J].Environ Eng Sci,2003,20(5):449-469.
2. [2]
  [2] WU Yongmin,LI Fu,HUANG Xianyu,et al.New Techniques for Treatment of Phenol-Containing Wastewater and Prospect of Them[J].Environ Sci Manage,2007,32(3):150-153(in Chinese).吴勇民,李甫,黄咸雨,等.含酚废水处理新技术及其发展前景[J].环境科学与管理,2007,32(3):150-153.
3. [3]
  [3] Annagiev M K,Rustamova D T,Bairamova S S.Study of Phenol Adsorption on Modified Forms of Zeolite[J].Russ J Appl Chem,2012,85(4):684-685.
4. [4]
  [4] Liu C,Chen Z,Ni C,et al.Adsorption of Phenol from Aqueous Solution by a Hierarchical Micro-nano Porous Carbon Material[J].Rare Met,2012,31(5):582-589.
5. [5]
  [5] Kumar K,Porkodi K.Comments on "Adsorption of 4-Chlorophenol from Aqueous Solutions by xad-4 Resin:Isotherm,Kinetic,and Thermodynamic Analysis"[J].J Hazard Mater,2007,143(1/2):598-599.
6. [6]
  [6] Eddaoudi M,Moler D B,Li H L,et al.Modular Chemistry:Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal-organic Carboxylate Frameworks[J].Acc Chem Res,2001,34(4):319-330.
7. [7]
  [7] Férey G,Mellot-Draznieks C,Serre C,et al.Crystallized Frameworks with giant Pores:Are There Limits to the Possible[J].Acc Chem Res,2005,38(4):217-225.
8. [8]
  [8] Kitagawa S,Kitaura R,Noro S.Functional Porous Coordination Polymers[J].Angew Chem Int Ed,2004,43(18):2334-2375.
9. [9]
  [9] HAN Yitong,LIU Min,LI Keyan,et al.Preparation and Application of High Stability Metal-organic Framework UiO-66[J].Chinese J Appl Chem,2016,33(4):367-378(in Chinese).韩易潼,刘民,李克艳,等.高稳定性金属有机骨架UiO-66的合成与应用[J].应用化学,2016,33(4):367-378.
10. [10]
  [10] ZHAO Wenpeng,Li Aiqin,DING Sanyuan.Application of Porous Organic Polymers in Water Contaminants Removal[J].Chinese J Appl Chem,2016,33(5):513-523(in Chinese).赵文鹏,李爱琴,丁三元.多孔有机聚合物在水处理中的应用[J].应用化学,2016,33(5):513-523.
11. [11]
  [11] Gu Z Y,Yang C X,Chang N,et al.Metal-organic Frameworks for Analytical Chemistry:from Sample Collection to Chromatographic Separation[J].Acc Chem Res,2012,45(5):734-745.
12. [12]
  [12] Suh M P,Park H J,Prasad T K,et al.Hydrogen Storage in Metal-organic Frameworks[J].Chem Rev,2012,112(2):782-835.
13. [13]
  [13] Yoon M,Srirambalaji R,Kim K.Homochiral Metal-organic Frameworks for Asymmetric Heterogeneous Catalysis[J].Chem Rev,2012,112(2):1196-1231.
14. [14]
  [14] Cui Y,Yue Y,Qian G,et al.Luminescent Functional Metal-organic Frameworks[J].Chem Rev,2012,112(2):1126-1162.
15. [15]
  [15] Li J R,Sculley J,Zhou H C.Metal-organic Frameworks for Separations[J].Chem Rev,2012,112(2):869-932.
16. [16]
  [16] Horcajada P,Gref R,Baati T,et al.Metal-organic Frameworks in Biomedicine[J].Chem Rev,2012,112(2):1232-1268.
17. [17]
  [17] Cychosz K A,Ahmad R,Matzger A J.Liquid Phase Separations by Crystalline Microporous Coordination Polymers[J].Chem Sci,2010,1(3):293-302.
18. [18]
  [18] Haque E,Lee J E,Jang I T,et al.Adsorptive Removal of Methyl Orange from Aqueous Solution with Metal-organic Frameworks,Porous Chromium-benzenedicarboxylates[J].J Hazard Mater,2010,181(1/2/3):535-542.
19. [19]
  [19] Haque E,Jun J W,Jhung S H.Adsorptive Removal of Methyl Orange and Methylene Blue from Aqueous Solution with a Metal-organic Framework Material,Iron Terephthalate (MOF-235)[J].J Hazard Mater,2011,185(1):507-511.
20. [20]
  [20] Cychosz K A,Matzger A J.Water Stability of Microporous Coordination Polymers and the Adsorption of Pharmaceuticals from Water[J].Langmuir,2010,26(22):17198-17202.
21. [21]
  [21] Hasan Z,Jeon J,Jhung S H.Adsorptive Removal of Naproxen and Clofibric Acid from Water Using Metal-organic Frameworks[J].J Hazard Mater,2012,209/210:151-157.
22. [22]
  [22] Yang C X,Yan X P.Selective Adsorption and Extraction of C70 and Higher Fullerenes on a Reusable Metal-organic Framework MIL-101(Cr)[J].J Mater Chem,2012,22(34):17833-17841.
23. [23]
  [23] Huo S H,Yan X P.Metal-organic Framework MIL-100(Fe) for the Adsorption of Malachite Green from Aqueous Solution[J].J Mater Chem,2012,22(15):7449-7455.
24. [24]
  [24] Huo S H,Yan X P.Facile Magnetization of Metal-organic Framework MIL-101 for Magnetic Solid-phase Extraction of Polycyclic Aromatic Hydrocarbons in Environmental Water Samples[J].Analyst,2012,137(15):3445-3451.
25. [25]
  [25] Loiseau T,Serre C,Huguenard C,et al.A Pationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL-53) upon Hydration[J].Chem-Eur J,2004,10(6):1373-1382.
26. [26]
  [26] Yang C X,Liu S S,Wang H F,et al.High-performance Liquid Chromatographic Separation of Position Isomers Using Metal-organic Framework MIL-53(Al) as the Stationary Phase[J].Analyst,2012,137(1):133-139.
27. [27]
  [27] Liu S S,Yang C X,Wang S W,et al.Metal-organic Frameworks for Reverse-phase High-performance Liquid Chromatography[J].Analyst,2012,137(4):816-818.
28. [28]
  [28] Hameed B.Rahman A.Removal of Phenol from Aqueous Solutions by Adsorption onto Activated Carbon Prepared from Biomass[J].J Hazard Mater,2008,160(2/3):576-581.
29. [29]
  [29] Wang S,Li H,Xu L.Application of Zeolite MCM-22 for Basic Dye Removal from Wastewater[J].J Colloid Interface Sci,2006,295(1):71-78.
30. [30]
  [30] Ho Y,McKay G.Pseudo-second Order Model for Sorption Processes[J].Process Biochem,1999,34(5):451-465.
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