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金属-有机骨架对苯二甲酸酯-铝吸附水中酚类化合物动力学和热力学

杨成雄 ,  王士伟 ,  严秀平

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引用本文: 杨成雄, 王士伟, 严秀平. 金属-有机骨架对苯二甲酸酯-铝吸附水中酚类化合物动力学和热力学[J]. 应用化学, 2016, 33(9): 1040-1046. doi: 10.11944/j.issn.1000-0518.2016.09.160211 shu
Citation:  YANG Chengxiong, WANG Shiwei, YAN Xiuping. Adsorption Thermodynamics and Kinetics of Phenols on Metal-Organic Framework Aluminum Terephthalate in Water[J]. Chinese Journal of Applied Chemistry, 2016, 33(9): 1040-1046. doi: 10.11944/j.issn.1000-0518.2016.09.160211 shu

金属-有机骨架对苯二甲酸酯-铝吸附水中酚类化合物动力学和热力学

  • 1.

    南开大学化学学院, 分析科学研究中心 天津 300071

    • 通讯作者: 严秀平,教授;Tel/Fax:022-23506075;E-mail:xpyan@nankai.edu.cn;研究方向:环境分析
  • 基金项目:

    973项目（2015CB932001) 

    国家自然科学基金项目（21305071）资助 

摘要: 以吸附等温线、动力学和热力学等方法研究了金属-有机骨架对苯二甲酸酯-铝[MIL-53（Al），MIL：Materials of Institut Lavoisier]对水中邻硝基苯酚、苯酚和邻苯二酚的吸附行为。MIL-53（Al）对上述酚类化合物的吸附符合准二级吸附动力学模型，且包含表面吸附和孔内扩散两个过程。吸附热力学结果表明，MIL-53（Al）对酚类化合物的吸附是自发的，且为吸热和熵增加过程。在40℃条件下，MIL-53（Al）对邻硝基苯酚、苯酚和邻苯二酚的吸附量分别为78.6、30.5和16.5 mg/g。

English

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  • 收稿日期:  2016-05-20
  • 网络出版日期:  2016-06-27
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