Citation: GONG Wenpeng, KE xiaofen, LI Zhipeng, TIAN Chaoqiang, YANG Shuijin. Adsorption of Methylene Blue by Phosphomolybdiumtungstic Acid Decorated Metal Organic Framework MOF-5[J]. Chinese Journal of Applied Chemistry, ;2016, 33(9): 1047-1055. doi: 10.11944/j.issn.1000-0518.2016.09.160058 shu

Adsorption of Methylene Blue by Phosphomolybdiumtungstic Acid Decorated Metal Organic Framework MOF-5

1.
a Hubei Collaborative Innovation Center for Rare Metal Chemistry, College of Chemistry and Chemical Engineering, Hubei Normal University, Huangshi, Hubei 435002, China;
2.
b College of Arts and Sciences, Hubei Normal University, Huangshi, Hubei 435002, China

Corresponding author: YANG Shuijin,
Received Date: 2 February 2016
Available Online: 20 April 2016
Fund Project:

The novel absorbent H₆P₂Mo₁₅W₃O₆₂/MOF-5 was prepared by the hydrothermal synthesis method. The active component H₆P₂Mo₁₅W₃O₆₂ was introduced during the synthesis of metal organic framework MOF-5. The adsorption property of the composites on methylene blue from water solution was investigated, and the effects of the experimental parameters including the temperature, the initial pH value and initial concentration of methylene blue solution were discussed. The results demonstrate that the lower temperature and lower initial pH value are more favorable for the adsorption methylene blue onto H₆P₂Mo₁₅W₃O₆₂/MOF-5. The experiment data can be well described in the Langmuir equation and a pseudo-second-order kinetic model, and the maximum adsorption capacity of methylene blue is 401.6 mg/g. Thermodynamic parameters ΔG<0, ΔH<0 and ΔS>0 reveal that the adsorption process is spontaneous and exothermic. Furthermore, we also explored the adsorption properties of H₆P₂Mo₁₅W₃O₆₂/MOF-5 to methyl violet, malachite green, rhodamine B, methyl orange and other dyes. The results indicate that this new absorbent shows better adsorption performance towards cationic dyes.
- phosphomolybdiumtungstic acid,
- metal organic frameworks,
- methylene blue,
- adsorption
1. [1]
  [1] Gan Y Q,Tian N,Tian X K,et al.Adsorption Behavior of Methylene Blue on Amine-functionalized Ordered Mesoporous Alumina[J].J Porous Mater,2015,22(1):147-155.
2. [2]
  [2] Ai L,Zhang C,Liao F,et al.Removal of Methylene Blue from Aqueous Solution with Magnetite Loaded Multi-wall Carbon Nanotube:Kinetic,Isotherm and Mechanism Analysis[J].Hazard Mater,2011,198(2):282-290.
3. [3]
  [3] Srinivasan M,White T.Degradation of Methylene Blue by Three-dimensionally Ordered Macroporous Titania[J].Environ Sci Technol,2007,41(12):4405-4409.
4. [4]
  [4] ZHANG Deyi,MA Ying,WANG Yi,et al.Preparation and Characterization of a Carbon/Fly Ash Composite Adsorbent[J].Chinese J Appl Chem,2011,28(8):942-948(in Chinese).张德懿,马颖,王毅,等.C/粉煤灰复合吸附材料的制备及表征[J].应用化学,2011,28(8):942-948.
5. [5]
  [5] Xue A,Zhou S,Zhao Y,et al.Effective NH₂-grafting on Attapulgite Surfaces for Adsorption of Reactive Dyes[J].Hazard Mater,2011,194(5):7-14.
6. [6]
  [6] Singh K P,Mohan D,Sinha S,et al.Color Removal from Wastewater Using Low-cost Activated Carbon Derived from Agricultural Waste Material[J].Ind Eng Chem Res,2003,42(9):1965-1976.
7. [7]
  [7] Liu X X,Luo J,Zhu Y T,et al.Removal of Methylene Blue from Aqueous Solutions by an Adsorbent Based on Metal-organic Framework and Polyoxometalates[J].Alloys Compd,2015,648:986-993.
8. [8]
  [8] Wang F,Li F L,Xu M M,et al.Facile Synthesis of a Ag (Ⅰ)-doped Coordination Polymer with Enhanced Catalytic Performance in the Photodegradation of Azo Dyes in Water[J].Mater Chem A,2015,3(11):5908-5916.
9. [9]
  [9] Tan Y X,He Y P,Wang M.A Water-stable Zeolite-like Metal-organic Framework for Selective Separation of Organic Dyes[J].RSC Adv,2014,4(3):1480-1483.
10. [10]
  [10] Park D R,Song J H,Lee S H,et al.Redox Properties of H₃PMo_XW_12-XO₄₀ and H₆P₂Mo_XW_18-XO₆₂ Heteropolyacid Catalysts and Their Catalytic Activity for Benzyl Alcohol Oxidation[J].Appl Catal A,2008,349(1/2):222-228.
11. [11]
  [11] Li R,Ren X Q,Zhao J S,et al.Polyoxometallates Trapped in a Zeolitic Imidazolate Framework Leading to High Uptake and Selectivity of Bioactive Molecules[J].J Mater Chem A,2014,2(7):2168-2173.
12. [12]
  [12] WANG Enbo,GAO Lihua,LIU Jingfu,et al.Preparation and Properties of the Molybdovanadophosphoric Acids with Dawson Srructure[J].Acta Chim Sin,1988,46(8):757-762(in Chinese).王恩波,高丽华,刘景福,等.具有Dawson结构的钼钒磷杂多酸的制备和性质研究[J].化学学报,1988,46(8):757-762.
13. [13]
  [13] Liu Y W,Liu S M,Liu S X,et al.Crystal Facets Make a Profound Difference in Polyoxometalate-Containing Metal-Organic Frameworks as Catalysts for Biodiesel Production[J].J Am Chem Soc,2015,137(39):12697-12703.
14. [14]
  [14] Panellab H.Hydrogen Physisorption in Metal Organic Porous Crystals[J].Adv Mater,2005,7(5):538-541.
15. [15]
  [15] Sun R Q,Sun L B,Chun Y,et al.Catalytic Performance of Porous Carbons Obtained by Chemical Activation[J].Carbon,2008,46(3):1757-1764.
16. [16]
  [16] Luo H M,Zhao X,Chen N L,et al.Research on the Adsorptive Mechanism and Capability of Modified Coke Powder to Methylene Blue[J].Ion Exch Adsorpt,2011,27(2):152-159.
17. [17]
  [17] Eftekhari S,Habibi-Y A,Sohrabnezhand.Application of AlMCM-41 for Competitive Adsorption of Methylene Blue and Rhodamine B:Thermodynamic and Kinetic Studies[J].Hazard Mater,2010,78(1/2/3):349-355.
18. [18]
  [18] Langmuir I.The Adsorption of Gases on Plane Surfaces of Glass,Mica and Platinum[J].J Am Chem Soc,1918,40(9):1361-1403.
19. [19]
  [19] Hameed B H.Equilibrium and Kinetic Studies of Methyl Violet Sorption by Agricultural Waste[J].Hazard Mater,2008,154(1/2/3):204-212.
20. [20]
  [20] Chen S H,Zhang J,Zhang C L,et al.Equilibrium and Kinetic Studies of Methyl Orange and Methyl Violet Adsorption on Activated Carbon Derived from Phragmites Australis[J].Desalination,2010,252(1/2/3):149-156.
1. [1]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
2. [2]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
3. [3]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
4. [4]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
5. [5]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
6. [6]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
7. [7]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
8. [8]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
9. [9]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
10. [10]
  Mengzhen JIANG , Qian WANG , Junfeng BAI . Research progress on low-cost ligand-based metal-organic frameworks for carbon dioxide capture from industrial flue gas. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 1-13. doi: 10.11862/CJIC.20240355
11. [11]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
12. [12]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
13. [13]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
14. [14]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
15. [15]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
16. [16]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
17. [17]
  Aiai WANG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress of bimetallic organic framework in tumor diagnosis and treatment. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1825-1839. doi: 10.11862/CJIC.20240225
18. [18]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
19. [19]
  Bin HE , Hao ZHANG , Lin XU , Yanghe LIU , Feifan LANG , Jiandong PANG . Recent progress in multicomponent zirconium?based metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2041-2062. doi: 10.11862/CJIC.20240161
20. [20]
  Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(396)
HTML views(37)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142