Citation: GONG Wenpeng, KE xiaofen, LI Zhipeng, TIAN Chaoqiang, YANG Shuijin. Adsorption of Methylene Blue by Phosphomolybdiumtungstic Acid Decorated Metal Organic Framework MOF-5[J]. Chinese Journal of Applied Chemistry, ;2016, 33(9): 1047-1055. doi: 10.11944/j.issn.1000-0518.2016.09.160058 shu

Adsorption of Methylene Blue by Phosphomolybdiumtungstic Acid Decorated Metal Organic Framework MOF-5

1.
a Hubei Collaborative Innovation Center for Rare Metal Chemistry, College of Chemistry and Chemical Engineering, Hubei Normal University, Huangshi, Hubei 435002, China;
2.
b College of Arts and Sciences, Hubei Normal University, Huangshi, Hubei 435002, China

Corresponding author: YANG Shuijin,
Received Date: 2 February 2016
Available Online: 20 April 2016
Fund Project:

The novel absorbent H₆P₂Mo₁₅W₃O₆₂/MOF-5 was prepared by the hydrothermal synthesis method. The active component H₆P₂Mo₁₅W₃O₆₂ was introduced during the synthesis of metal organic framework MOF-5. The adsorption property of the composites on methylene blue from water solution was investigated, and the effects of the experimental parameters including the temperature, the initial pH value and initial concentration of methylene blue solution were discussed. The results demonstrate that the lower temperature and lower initial pH value are more favorable for the adsorption methylene blue onto H₆P₂Mo₁₅W₃O₆₂/MOF-5. The experiment data can be well described in the Langmuir equation and a pseudo-second-order kinetic model, and the maximum adsorption capacity of methylene blue is 401.6 mg/g. Thermodynamic parameters ΔG<0, ΔH<0 and ΔS>0 reveal that the adsorption process is spontaneous and exothermic. Furthermore, we also explored the adsorption properties of H₆P₂Mo₁₅W₃O₆₂/MOF-5 to methyl violet, malachite green, rhodamine B, methyl orange and other dyes. The results indicate that this new absorbent shows better adsorption performance towards cationic dyes.
- phosphomolybdiumtungstic acid,
- metal organic frameworks,
- methylene blue,
- adsorption
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沈阳化工大学材料科学与工程学院沈阳 110142