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Citation: ZHU Xiaoming, FENG Yonglan, ZHANG Fuxing, YU Jiangxi, JIANG Wujiu, OU Yaping, KUANG Daizhi. Synthesis, Crystal Structure and Properties of Dinuclear Copper(Ⅱ) Complex {[Cu(Phen)(Nap)2]2·(EtOH)2·(H2O)2} (Phen=1,10-Phenanthroline; Nap=1-Naphthoic Acid; EtOH=Ethyl Alcohol)[J]. Chinese Journal of Applied Chemistry, ;2016, 33(8): 932-938. doi: 10.11944/j.issn.1000-0518.2016.08.150402 shu

Synthesis, Crystal Structure and Properties of Dinuclear Copper(Ⅱ) Complex {[Cu(Phen)(Nap)2]2·(EtOH)2·(H2O)2} (Phen=1,10-Phenanthroline; Nap=1-Naphthoic Acid; EtOH=Ethyl Alcohol)

  • 1.

    Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hu'nan Province, College of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hu'nan 421008, China

  • Corresponding author: KUANG Daizhi, 
  • Received Date: 16 November 2015
    Available Online: 25 January 2016

    Fund Project:

  • A new complex [Cu(Phen)(Nap)2]2·(EtOH)2·(H2O)2(Phen=1,10-phenanthroline; Nap=1-naphthoic acid; EtOH=ethyl alcohol) was synthesized. The compound was characterized by elemental analysis, FTIR, TG-DTG, single crystal X-ray diffraction. The complex is dinuclear copper(Ⅱ) structure. The electrochemical and luminescent properties of the complex was studied by cyclic voltammetry and emission spectrum. The interactions of the complex with calf thymus DNA(ct-DNA) has been studied by UV and fluorescence spectroscopy. The results show that the copper(Ⅱ) complex shows irreversible redox process, and possesses a fluorescent emission band at 416 nm, and this copper(Ⅱ) complex binds to ct-DNA in groove binding and its intrinsic binding constant Kb is 4.68×103 L/mol.
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