Citation: ZHANG Xiaonan, SUN Yudong, LI Naixuan. Synthesis and Photocatalytic Activity of Graphitic Carbon Nitride/Cyanuric Chloride Composite Photocatalyst[J]. Chinese Journal of Applied Chemistry, ;2016, 33(7): 820-826. doi: 10.11944/j.issn.1000-0518.2016.07.150356 shu

Synthesis and Photocatalytic Activity of Graphitic Carbon Nitride/Cyanuric Chloride Composite Photocatalyst

1.
Chemistry and Chemical Engineering College, Tianjin University of Technology, Tianjin 300384, China

Corresponding author: LI Naixuan,
Received Date: 9 October 2015
Available Online: 6 January 2016
Fund Project:

A graphitic carbon nitride/cyanuric chloride(g-C₃N₄/C₃Cl₃N₃) composite photocatalyst was developed. The obtained catalyst effectively expands π-conjugated system of g-C₃N₄. Moreover, the band gap is significantly shifted, and the reduction ability of the photo generated charge is improved because of the introduction of a chlorine atom. The catalyst can effectively degrade organic pollutants under visible light. The result shows that the degradation ratio of reactive red-dye is 94.7% and is still kept at 94% after using 5 times. The mechanism on the degradation of organic pollutants under visible light was studied.
- graphitic carbon nitride,
- cyanuric chloride,
- reactive red,
- visible light catalysis
1. [1]
  [1] Wang X C,Maeda K,Thomas A,et al. Ametal-Free Polymeric Photocatalyst for Hydrogen Production from Water under Visible Light[J]. Nat Mater,2009,8(1):76-80.
2. [2]
  [2] Wang Y F,Gao B Y,Yue Q Y,et al. Flocculation Performance of Epichlorohydrin-Dimethylamine Polyamine in Treating Dyeing Wastewater[J]. Environ Manage,2009,1(2):423-431.
3. [3]
  [3] Zhang F J,Xie F Z,Zhu S F,et al. A Novel Photofunctional g-C₃N₄/Ag₃PO₄ Bulk Heterojunction for Decolorization of RhB[J]. Chem Eng,2013,28(15):435-441.
4. [4]
  [4] Mitoraj D,Kisch H. On the Mechanism of Urea Induced Titania Modification[J]. Chem Eur,2010,16(1):261-269.
5. [5]
  [5] He P Z,Song L M,Zhang S J,et al. Synthesis of g-C₃N₄/Ag₃PO₄ Heterojunction with Enhanced Photocatalytic Performance[J]. Mater Res Bull,2014,51(6):432-437.
6. [6]
  [6] Xu H,Yan J,Xu Y G,et al. Novel Visible-Light-Driven AgX/Graphite-Like C₃N₄(X=Br,I) Hybrid Materials with Synergistic Photocatalytic Activity[J]. Appl Catal B:Environ,2013,129:182-193.
7. [7]
  [7] Meng Y L,Shen J,Chen D,et al. Photodegradation Peoformance of Methylene Blue Aqueous Solution on Ag/g-C₃N₄ Catalyst[J]. Rare Met,2011,30(1):276-279.
8. [8]
  [8] Wang X C,Blechert S,Antonietti M. Polymeric Graphitic Carbon Nitride for Heterogeneous Photocatalysis[J]. ACS Catal,2012,2(8):1596-1606.
9. [9]
  [9] Maeda K,Wang X C,Nishihara D,et al. Photocatalytic Activities of Graphitic Carbon Nitride Powder for Water Reduction and Oxidation under Visible Light[J]. Phys Chem,2009,113(12):4940-4947.
10. [10]
  [10] Wang X C,Thomas A,Fu X Z,et al. Metal-Containing Carbon Nitride Compounds:A New Functional Organic-Metal Hybrid Material[J]. Adv Mater,2009,21(16):1609-1612.
11. [11]
  [11] Fu X Z,Wang X C,Antonietti M,et al. Fe-g-C₃N₄-Catalyzed Oxidation of Benzene to Phenol Using Hydrogen Peroxide and Visible Light[J]. J Am Chem Soc,2009,131(33):11658-11659.
12. [12]
  [12] Ding Z X,Wang X C,Antonietti M,et al. Synthesis of Transition Metal-Modified Carbon Nitride Polymers for Selective Hydrocarbon Oxidation[J]. ChemSusChem,2011,4(2):274-281.
13. [13]
  [13] Yan S C,Li Z S. Photodegradation of Rhodamine B and Methyl Orange over Boron-Doped g-C₃N₄ under Visible Light Irradiation[J]. Langmuir,2010,26(6):3894-3901.
14. [14]
  [14] Liu G,Niu P,Smith S,et al. Unique Electronic Structure Induced High Photoreactivity of Sulfur-Doped Graphitic C₃N₄[J]. J Am Chem Soc,2010,132(33):11642-11648.
15. [15]
  [15] Zhang Y J,Mori T,Antonietti M,et al. Phosphorus-Doped Carbon Nitride Solid: Enhanced Electrical Conductivity and Photocurrent Generation[J]. J Am Chem Soc,2010,132(18):6294-6295.
16. [16]
  [16] Dong G H,Zhao Kun,Zhang L Z,et al. Carbon Self-Doping Induced High Electronic Conductivity and Photoreactivity of g-C₃N₄[J]. Chem Commun,2012,48(49):6178-6180.
17. [17]
  [17] Li J H,Shen B,Chen Y L,et al. A Facile Approach to Synthesize Novel Oxygen-Doped g-C₃N₄ with Superior Visible-Light Photoreactivity[J]. Chem Commun,2012,48(98):12017-12019.
18. [18]
  [18] Wang Y,Antonietti M,Wang X C,et al. Excellent Visible Light Photocatalysis of Fluorinated Polymeric Carbon Nitride Solids[J]. Chem Mater,2010,22(18):5119-5121.
19. [19]
  [19] Niu P,Zhang L L,Liu G,et al. Graphene-Like Carbon Nitride Nanosheets for Improved Photocatalytic Activities[J]. Funct Mater,2012,21(22):4763 4770.
20. [20]
  [20] Bettina V,Sehnert J,Seyfarth L,et al. Unmasking Melon by a Complementary Approach Employing Electron Diffraction, Solid-State NMR Spectroscopy, and Theoretical Calculations-Structural Characterization of a Carbon Nitride Polymer[J]. Chem Eur,2007,13(17):4969-4980.
21. [21]
  [21] Jing D L,Chen L L,Xie J M,et al. Ag₂S/g-C₃N₄ Composite Photocatalysts for Efficient Pt-Free Hydrogen Production[J]. Dalton Trans,2014,43(12):4878-4885.
22. [22]
  [22] DONG Fan,LI Yuhan,HO Wingkei,et al. Synthesis of Mesoporous Polymeric Carbon Nitride Exhibiting Enhanced and Durable Visible Light Photocatalytic Performance[J]. Chinese Sci Bull,2014,59(7):688-698(in Chinese).董帆,李昱翰,何咏基博,等. 增强和持久可见光催化性能的介孔聚合物碳氮化物的合成[J]. 中国科学通报,2014,59(7):688-698 .
23. [23]
  [23] Wang S M,Li D L,Sun C,et al. Synthesis and Characterization of g-C₃N₄/Ag₃VO₄ Composites with Significantly Enhanced Visible-Light Photocatalytic Activity for Triphenylmethane Dye Degradation[J]. Appl Catal B:Environ,2014,144(2):885-892.
24. [24]
  [24] Chu S,Wang Y,Guo Y,et al. Band Structure Engineering of Carbon Nitride:In Search of a Polymer Photocatalyst with High Photooxidation Property[J]. ACS Catal,2013,3(5):912-919.
25. [25]
  [25] Li X F,Zheng J,Shen L H,et al. Preparation and Characterization of Graphitic Carbon Nitride through Pyrolysis of Melamine[J]. Appl Phys,2009,94(2):387-392.
26. [26]
  [26] LU Changyuan,HAN Zhenhui,PAN Jingxi,et al. Riboflavin(vitamin B₂) Photochemical Activity:The Potential Biological Effects of Light Particles[J]. J Radiat Res Radiat Process,2000,2(1):12-18(in Chinese).陆长元,韩镇辉,潘景喜,等. 核黄素(维生素B₂)的光化学活性粒子:潜在的光生物学效应[J]. 辐射研究与辐射工艺学报,2000,2(1):12-18.
27. [27]
  [27] Cao J,Zhao Y J,Lin H L,et al. Ag/AgBr/g-C₃N₄:A Highly Efficient and Stable Composite Photocatalyst for Degradation of Organic Contaminants under Visible Light[J]. Mater Res Bull,2013,48(10):3873-3880.
1. [1]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
2. [2]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . Modulating reactive oxygen species in O, S co-doped C₃N₄ to enhance photocatalytic degradation of microplastics. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-. doi: 10.1016/j.actphy.2025.100052
3. [3]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
4. [4]
  Dan Liu . 可见光-有机小分子协同催化的不对称自由基反应研究进展. University Chemistry, 2025, 40(6): 118-128. doi: 10.12461/PKU.DXHX202408101
5. [5]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
6. [6]
  Weikang Wang , Yadong Wu , Jianjun Zhang , Kai Meng , Jinhe Li , Lele Wang , Qinqin Liu . 三聚氰胺泡沫支撑的S型硫铟锌镉/硫掺杂氮化碳异质结的绿色H₂O₂合成：协同界面电荷转移调控与局域光热效应. Acta Physico-Chimica Sinica, 2025, 41(8): 100093-. doi: 10.1016/j.actphy.2025.100093
7. [7]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
8. [8]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
9. [9]
  Xinzhe HUANG , Lihui XU , Yue YANG , Liming WANG , Zhangyong LIU , Zhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212
10. [10]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
11. [11]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
12. [12]
  Jie Li , Huida Qian , Deyang Pan , Wenjing Wang , Daliang Zhu , Zhongxue Fang . Efficient Synthesis of Anethaldehyde Induced by Visible Light. University Chemistry, 2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076
13. [13]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
14. [14]
  Fanpeng Meng , Fei Zhao , Jingkai Lin , Jinsheng Zhao , Huayang Zhang , Shaobin Wang . 优化氮化碳纳米片/球形共轭聚合物S型异质结界面电场以促进析氢反应. Acta Physico-Chimica Sinica, 2025, 41(8): 100095-. doi: 10.1016/j.actphy.2025.100095
15. [15]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
16. [16]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
17. [17]
  Yuanyuan Ping , Wangqing Kong . 光催化碳氢键官能团化合成1-苯基-1,2-乙二醇. University Chemistry, 2025, 40(6): 238-247. doi: 10.12461/PKU.DXHX202408092
18. [18]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
19. [19]
  Xueqi Yang , Juntao Zhao , Jiawei Ye , Desen Zhou , Tingmin Di , Jun Zhang . 调节NNU-55(Fe)的d带中心以增强CO₂吸附和光催化活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100074-. doi: 10.1016/j.actphy.2025.100074
20. [20]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(642)
HTML views(65)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142