Citation: HUANG Xiaomei, DENG Xiang. Fluorescent Quenching Method for the Detection of 2,4,6-Trinitrophenol Using Riboflavin[J]. Chinese Journal of Applied Chemistry, ;2016, 33(5): 606-610. doi: 10.11944/j.issn.1000-0518.2016.05.150367 shu

Fluorescent Quenching Method for the Detection of 2,4,6-Trinitrophenol Using Riboflavin

HUANG Xiaomei ^, ,
DENG Xiang

1.
Sichuan Key Laboratory of Characteristic Plant Development Research, Department of Chemistry and Chemical Engineering, Sichuan University of Arts and Science, Dazhou, Sichuan 635000, China

Corresponding author: HUANG Xiaomei,
Received Date: 19 October 2015
Available Online: 12 January 2016
Fund Project:

A novel method for the determination of 2,4,6-trinitrophenol has been developed based on fluorescent quenching of riboflavin by 2,4,6-trinitrophenol(TNP) in aqueous solutions. The proposed fluorescent quenching method for TNP detection at pH=6.2 using 0.2 mol/L phosphate(NaH₂PO₄-Na₂HPO₄) as buffer solution responses within 1 min and with a broad linear relationship from 2.5 to 1000 μmol/L(r=0.9938). The limit of detection for TNP is 0.55 μmol/L. When 5.00 and 20.00 μmol/L TNP is added to different water samples, the recovery ranges from 98.2% to 103.5%. Furthermore, this method is simple, selective, and with wide linear range. Therefore, it can be applied in the determination of 2,4,6-trinitrophenol in real samples.
- riboflavin,
- trinitrophenol(TNP),
- fluorescent quenching method
1. [1]
  [1] Ma Y,Li H,Peng S,et al. Highly Selective and Sensitive Fluorescent Paper Sensor for Nitroaromatic Explosive Detection[J]. Anal Chem,2012,84(19):8415-8421.
2. [2]
  [2] Babaee S,Beiraghi A. Extraction and High Performance Liquid Chromatography-Ultra Violet Determination of Some Explosives in Water Samples[J]. Anal Chim Acta,2010,662(1):9-13.
3. [3]
  [3] Dey N,Samanta S K,Bhattacharya S. Selective and Efficient Detection of Nitro-aromatic Explosives in Multiple Media Including Water, Micelles, Organogel, and Solid Support[J]. ACS Appl Mater Interfaces,2013,5(17):8394-8400.
4. [4]
  [4] Conway R A,Ross R D. Waste Water. In:Hand Book of Industrial Waste Disposal[M]. New York:Educational Publishing Inc,1980:582.
5. [5]
  [5] Bhalla V,Gupta A,Kumar M,et al. Self-assembled Pentacenequinone Derivative for Trace Detection of Picric Acid[J]. ACS Appl Mater Interfaces,2013,5(3):672-679.
6. [6]
  [6] Pramanik S,Bhalla V,Kumar M. Mercury Assisted Fluorescent Supramolecular Assembly of Hexaphenylbenzene Derivative for Femtogram Detection of Picric Acid[J]. Anal Chim Acta,2013,793(2):99-106.
7. [7]
  [7] Ma Y X,Li H,Peng S,et al. Highly Selective and Sensitive Fluorescent Paper Sensor for Nitroaromatic Explosive Detection[J]. Anal Chem,2012,84(19):8415-8421.
8. [8]
  [8] Chen J C,Shih J L,Liu C H,et al. Disposable Electrochemical Sensor for Determination of Nitroaromatic Compounds by a Single-run Approach[J]. Anal Chem,2006,78(11):3752-3757.
9. [9]
  [9] Chen P C,Sukcharoenchoke S,Ryu K,et al. 2,4,6-Trinitrotoluene(TNT) Chemical Sensing based on Aligned Single-walled Carbon Nanotubes and ZnO Nanowires[J]. Adv Mater,2010,22(17):1900-1904.
10. [10]
  [10] Peng Y,Zhang A J,Dong M,et al. A Colorimetric and Fluorescent Chemosensor for the Detection of an Explosive-2,4,6-Trinitrophenol(TNP)[J]. Chem Commun,2011,47(15):4505-4507.
11. [11]
  [11] Li X G,Liao Y Z,Huang M R,et al. Ultra-sensitive Chemosensors for Fe(Ⅲ) and Explosives based on Highly Fluorescent Oligofluoranthene[J]. Chem Sci,2013,4(5):1970-1978.
12. [12]
  [12] Samanta D,Mukherjee P S. Pt^Ⅱ₆ Nanoscopic Cages with an Organometallic Backbone as Sensors for Picric Acid[J]. Dalton Trans,2013,42(48):16784-16795.
13. [13]
  [13] Ko H,Chang S,Tsukruk V V. Porous Substrates for Label-free Molecular Level Detection of Nonresonant Organic Molecules[J]. ACS Nano,2009,3(1):181-188.
14. [14]
  [14] Mu R,Shi H,Yuan Y,et al. Fast Separation and Quantification Method for Nitroguanidine and 2,4-Dinitroanisole by Ultrafast Liquid Chromatography Tandem Mass Spectrometry[J]. Anal Chem,2012,84(7):3427-3432.
1. [1]
  Yingpeng ZHANG , Xingxing LI , Yunshang YANG , Zhidong TENG . A pyrazole-based turn-off fluorescent probe for visual detection of hydrazine. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1301-1308. doi: 10.11862/CJIC.20250064
2. [2]
  Mi Wen , Baoshuo Jia , Yongqi Chai , Tong Wang , Jianbo Liu , Hailong Wu . Improvement of Fluorescence Quantitative Analysis Experiment: Simultaneous Determination of Rhodamine 6G and Rhodamine 123 in Food Using Chemometrics-Assisted Three-Dimensional Fluorescence Method. University Chemistry, 2025, 40(4): 390-398. doi: 10.12461/PKU.DXHX202405147
3. [3]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
4. [4]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
5. [5]
  Zhongyan Cao , Youzhi Xu , Menghua Li , Xiao Xiao , Xianqiang Kong , Deyun Qian . Electrochemically Driven Denitrative Borylation and Fluorosulfonylation of Nitroarenes. University Chemistry, 2025, 40(4): 277-281. doi: 10.12461/PKU.DXHX202407017
6. [6]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
7. [7]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
8. [8]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
9. [9]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
10. [10]
  Zhou Fang , Zhihao Zhang , Weihan Jiang , Kin Shing Chan . Warfarin: From Poison to Cure, the Remarkable Journey of a Molecule. University Chemistry, 2025, 40(4): 326-330. doi: 10.12461/PKU.DXHX202406038
11. [11]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
12. [12]
  Fengmiao Yu , Yang Sheng , Chanyue Li , Bao Li . The Three Lives of Aspirin. University Chemistry, 2024, 39(9): 115-121. doi: 10.12461/PKU.DXHX202402033
13. [13]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
14. [14]
  Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu³⁺-doped CaLaGaO₄ red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242
15. [15]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
16. [16]
  Xinyu Liu , Weiran Hu , Zhengkai Li , Wei Ji , Xiao Ni . Algin Lab: Surging Luminescent Sea. University Chemistry, 2024, 39(5): 396-404. doi: 10.3866/PKU.DXHX202312021
17. [17]
  Aiyi Xin , Jiawei Li , Xinyang Ran , Chuanjiang Fu , Zhiguo Wang . Collaborative Science and Education Based Experimental Design in Organic Chemistry: A Case Study of the Nucleophilic Substitution Reaction of 2-Hydroxymethyl-4,6-Di-Tert-Butylphenol. University Chemistry, 2025, 40(5): 366-375. doi: 10.12461/PKU.DXHX202407031
18. [18]
  Hui Shi , Shuangyan Huan , Yuzhi Wang . Ideological and Political Design of Potassium Permanganate Oxidation-Reduction Titration Experiment. University Chemistry, 2024, 39(2): 175-180. doi: 10.3866/PKU.DXHX202308042
19. [19]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
20. [20]
  Feng Liang , Desheng Li , Yuting Jiang , Jiaxin Dong , Dongcheng Liu , Xingcan Shen . Method Exploration and Instrument Innovation for the Experiment of Colloid ζ Potential Measurement by Electrophoresis. University Chemistry, 2024, 39(5): 345-353. doi: 10.3866/PKU.DXHX202312009

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(341)
HTML views(47)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142