Citation: HUANG Xiaomei, DENG Xiang. Fluorescent Quenching Method for the Detection of 2,4,6-Trinitrophenol Using Riboflavin[J]. Chinese Journal of Applied Chemistry, ;2016, 33(5): 606-610. doi: 10.11944/j.issn.1000-0518.2016.05.150367 shu

Fluorescent Quenching Method for the Detection of 2,4,6-Trinitrophenol Using Riboflavin

HUANG Xiaomei ^, ,
DENG Xiang

1.
Sichuan Key Laboratory of Characteristic Plant Development Research, Department of Chemistry and Chemical Engineering, Sichuan University of Arts and Science, Dazhou, Sichuan 635000, China

Corresponding author: HUANG Xiaomei,
Received Date: 19 October 2015
Available Online: 12 January 2016
Fund Project:

A novel method for the determination of 2,4,6-trinitrophenol has been developed based on fluorescent quenching of riboflavin by 2,4,6-trinitrophenol(TNP) in aqueous solutions. The proposed fluorescent quenching method for TNP detection at pH=6.2 using 0.2 mol/L phosphate(NaH₂PO₄-Na₂HPO₄) as buffer solution responses within 1 min and with a broad linear relationship from 2.5 to 1000 μmol/L(r=0.9938). The limit of detection for TNP is 0.55 μmol/L. When 5.00 and 20.00 μmol/L TNP is added to different water samples, the recovery ranges from 98.2% to 103.5%. Furthermore, this method is simple, selective, and with wide linear range. Therefore, it can be applied in the determination of 2,4,6-trinitrophenol in real samples.
- riboflavin,
- trinitrophenol(TNP),
- fluorescent quenching method
1. [1]
  [1] Ma Y,Li H,Peng S,et al. Highly Selective and Sensitive Fluorescent Paper Sensor for Nitroaromatic Explosive Detection[J]. Anal Chem,2012,84(19):8415-8421.
2. [2]
  [2] Babaee S,Beiraghi A. Extraction and High Performance Liquid Chromatography-Ultra Violet Determination of Some Explosives in Water Samples[J]. Anal Chim Acta,2010,662(1):9-13.
3. [3]
  [3] Dey N,Samanta S K,Bhattacharya S. Selective and Efficient Detection of Nitro-aromatic Explosives in Multiple Media Including Water, Micelles, Organogel, and Solid Support[J]. ACS Appl Mater Interfaces,2013,5(17):8394-8400.
4. [4]
  [4] Conway R A,Ross R D. Waste Water. In:Hand Book of Industrial Waste Disposal[M]. New York:Educational Publishing Inc,1980:582.
5. [5]
  [5] Bhalla V,Gupta A,Kumar M,et al. Self-assembled Pentacenequinone Derivative for Trace Detection of Picric Acid[J]. ACS Appl Mater Interfaces,2013,5(3):672-679.
6. [6]
  [6] Pramanik S,Bhalla V,Kumar M. Mercury Assisted Fluorescent Supramolecular Assembly of Hexaphenylbenzene Derivative for Femtogram Detection of Picric Acid[J]. Anal Chim Acta,2013,793(2):99-106.
7. [7]
  [7] Ma Y X,Li H,Peng S,et al. Highly Selective and Sensitive Fluorescent Paper Sensor for Nitroaromatic Explosive Detection[J]. Anal Chem,2012,84(19):8415-8421.
8. [8]
  [8] Chen J C,Shih J L,Liu C H,et al. Disposable Electrochemical Sensor for Determination of Nitroaromatic Compounds by a Single-run Approach[J]. Anal Chem,2006,78(11):3752-3757.
9. [9]
  [9] Chen P C,Sukcharoenchoke S,Ryu K,et al. 2,4,6-Trinitrotoluene(TNT) Chemical Sensing based on Aligned Single-walled Carbon Nanotubes and ZnO Nanowires[J]. Adv Mater,2010,22(17):1900-1904.
10. [10]
  [10] Peng Y,Zhang A J,Dong M,et al. A Colorimetric and Fluorescent Chemosensor for the Detection of an Explosive-2,4,6-Trinitrophenol(TNP)[J]. Chem Commun,2011,47(15):4505-4507.
11. [11]
  [11] Li X G,Liao Y Z,Huang M R,et al. Ultra-sensitive Chemosensors for Fe(Ⅲ) and Explosives based on Highly Fluorescent Oligofluoranthene[J]. Chem Sci,2013,4(5):1970-1978.
12. [12]
  [12] Samanta D,Mukherjee P S. Pt^Ⅱ₆ Nanoscopic Cages with an Organometallic Backbone as Sensors for Picric Acid[J]. Dalton Trans,2013,42(48):16784-16795.
13. [13]
  [13] Ko H,Chang S,Tsukruk V V. Porous Substrates for Label-free Molecular Level Detection of Nonresonant Organic Molecules[J]. ACS Nano,2009,3(1):181-188.
14. [14]
  [14] Mu R,Shi H,Yuan Y,et al. Fast Separation and Quantification Method for Nitroguanidine and 2,4-Dinitroanisole by Ultrafast Liquid Chromatography Tandem Mass Spectrometry[J]. Anal Chem,2012,84(7):3427-3432.
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沈阳化工大学材料科学与工程学院沈阳 110142