Citation: CHEN Hongrong, WU Ya'nan, CHEN Shiyan, MA Peihua, NI Xinlong. “Naked-eye” and Fluorescence “Turn-on” Recognition of Al³⁺ Based on 2-Hydroxy-Naphthalene-Formaldehyde Benzoyl-Hydrazone Derivatives[J]. Chinese Journal of Applied Chemistry, ;2016, 33(5): 599-605. doi: 10.11944/j.issn.1000-0518.2016.05.150333 shu

“Naked-eye” and Fluorescence “Turn-on” Recognition of Al³⁺ Based on 2-Hydroxy-Naphthalene-Formaldehyde Benzoyl-Hydrazone Derivatives

1.
Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China

Corresponding author: MA Peihua, NI Xinlong,
Received Date: 10 September 2015
Available Online: 24 December 2015
Fund Project:

The probe 4-hydroxy-benzoyl-(2-hydroxy-naphthalene-formaldehyde) hydrazone(L) was synthesized and evaluated. The UV-Vis and fluorescence spectra suggested that probe L has highly Al³⁺-selective affinity over others commonly coexistent metal ions by fluorescence enhancing. Meanwhile, the color change of probe L solution after addition of Al³⁺ is obvious. ¹H NMR titration, job-plot, and (MALDI-TOF) results indicate that the complex molar ratio of Al³⁺/L is 1:2. The binding constant of Al³⁺/L is calculated to be 1.3×10⁴ L/mol by nonlinear curve-fitting based on the UV-Vis titration data, and the detection limit reaches 3.71×10^-6 L/mol. The UV-Vis and fluorescence emission titration experiment show that a wide range and low detection limit can be achieved in the present sensing system. This result suggests that the probe L has potential application in determination of trace Al³⁺ ions.
- hydroxy-naphthaldehyde,
- fluorescent chemosensor,
- “naked-eye” recognition,
- aluminum ion
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

“Naked-eye” and Fluorescence “Turn-on” Recognition of Al3+ Based on 2-Hydroxy-Naphthalene-Formaldehyde Benzoyl-Hydrazone Derivatives

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通讯作者: 陈斌, bchen63@163.com

“Naked-eye” and Fluorescence “Turn-on” Recognition of Al³⁺ Based on 2-Hydroxy-Naphthalene-Formaldehyde Benzoyl-Hydrazone Derivatives