Citation: ZHAO Wenpeng, LI Aiqin, DING Sanyuan. Application of Porous Organic Polymers in Water Contaminants Removal[J]. Chinese Journal of Applied Chemistry, ;2016, 33(5): 513-523. doi: 10.11944/j.issn.1000-0518.2016.05.150212 shu

Application of Porous Organic Polymers in Water Contaminants Removal

a.
a. Environmental Monitoring Station of Xinxiang, Xinxiang, He'nan 453003, China;
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b. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China

Corresponding author: LI Aiqin,
Received Date: 24 June 2015
Available Online: 26 October 2015
Fund Project:

Porous organic polymers(POPs) are a new type of porous materials that consist of pure organic groups. The application of POPs in water contaminants removal have attracted widespread interest in recent years. This article briefly reviews the most recent developments in this field, and discusses the adsorption mechanism, impact factors and the future developments.
- porous organic polymer,
- water treatment,
- adsorption
1. [1]
  [1] United Nations Educational, Scientific and Cultural Organization. The United Nations World Water Development Report 2014[R]. Paris:UNESCO,2014.
2. [2]
  [2] Qu X L,Brame J,Li Q L. Nanotechnology for a Safe and Sustainable Water Supply:Enabling Integrated Water Treatment and Reuse[J]. Acc Chem Res,2013,46(3):834-843.
3. [3]
  [3] Hu A M,Apblett A. Nanotechnology for Water Treatment and Purification[M]. Cham,Heidelberg,New York,Dordrecht,London: Springer,2014.
4. [4]
  [4] Thomas A. Functional Materials:From Hard to Soft Porous Frameworks[J]. Angew Chem Int Ed,2010,49(45):8328-8344.
5. [5]
  [5] Dawson R,Cooper A I,Adams D J. Nanoporous Organic Polymer Networks[J]. Prog Polym Sci,2012,37(4): 530-563.
6. [6]
  [6] XU Shujun,LIANG,Liyun,LI Buyi,et al. Research Progress on Microporous Organic Polymers[J]. Prog Chem,2011,23(10):2085-2094(in Chinese).徐叔军,梁丽芸,李步怡,等. 有机微孔聚合物研究进展[J]. 化学进展,2011,23(10):2085-2094.
7. [7]
  [7] Zhang Y G,Riduan S N. Functional Porous Organic Polymers for Heterogeneous Catalysis[J]. Chem Soc Rev,2012,41(6):2083-2094.
8. [8]
  [8] Xu Y H,Jin S B,Xu H,et al. Conjugated Microporous Polymers:Design, Synthesis and Application[J]. Chem Soc Rev,2013,42(20):8012-8031.
9. [9]
  [9] Ding S Y,Wang W. Covalent Organic Frameworks(COFs):From Design to Applications[J]. Chem Soc Rev,2013,42(2):548-568.
10. [10]
  [10] TAN Dazhi. Studies on Synthesis, Structures, and Absorption Properties of Novel Porous Materials[D]. Dalian:Dalian University of Technology,2012(in Chinese).谭大志. 新型孔材料的合成、结构及其吸附性质的研究[D]. 大连:大连理工大学,2012.
11. [11]
  [11] Zhang Y L,Wei S,Liu F J,et al. Superhydrophobic Nanoporous Polymers as Efficient Adsorbents for Organic Compounds[J]. Nano Today,2009,4(2): 35-142.
12. [12]
  [12] Zhang Y L,Wei S,He Y Y,et al. Solvothermal Synthesis of Carboxyl and Amido Functionalized Mesoporous Resins for Water Treatments[J]. J Mater Chem,2010,20(22):4609-4614.
13. [13]
  [13] Li A,Sun H X,Tan D Z,et al. Superhydrophobic Conjugated Microporous Polymers for Separation and Adsorption[J]. Energy Environ Sci,2011,4(6):2062-2065.
14. [14]
  [14] Tan D Z,Fan W J,Xiong W N,et al. Study on Adsorption Performance of Conjugated Microporous Polymers for Hydrogen and Organic Solvents:The Role of Pore Volume[J]. Eur Polym J,2012,48(4):705-711.
15. [15]
  [15] Tan D Z,Fan W J,Xiong W N,et al. Study on the Morphologies of Covalent Organic Microporous Polymers:The Role of Reaction Solvents[J]. Macromol Chem Phys,2012,213(14):1435- 1440.
16. [16]
  [16] Wang X S,LIU J,Bonefonet J M,et al. A Porous Covalent Porphyrin Framework with Exceptional Uptake Capacity of Saturated Hydrocarbons for Oil Spill Cleanup[J]. Chem Commun,2013,49(15):5815-5817.
17. [17]
  [17] Xue Z X,Sun Z X,Cao Y Z,et al. Superoleophilic and Superhydrophobic Biodegradable Material with Porous Structures for Oil Absorption and Oil water Separation[J]. RSC Adv,2013,3(45):23432-23437.
18. [18]
  [18] Yang Y Q,Zhang Q,Zhang S B,et al. Triphenylamine-Containing Microporous Organic Copolymers for Hydrocarbons/Water Separation[J]. RSC Adv,2014,4(11):5568-5574.
19. [19]
  [19] Patel H A,Yavuzb M S,Yavuz, C T. Exceptional Organic Solvent Uptake by Disulfide-linked Polymeric Networks[J]. RSC Adv,2014,4(46):24320-24323.
20. [20]
  [20] Kuhn P,Kruger K,Thomas Arne,et al. "Everything is Surface":Tunable Polymer Organic Frameworks with Ultrahigh Dye Sorption Capacity[J]. Chem Commun,2008,44:5815-5817.
21. [21]
  [21] Wang T,Kailasam K,Xiao P,et al. Adsorption Removal of Organic Dyes on Covalent Triazine Framework(CTF)[J]. Micropor Mesopor Mater,2014,187:63-70.
22. [22]
  [22] Zhang W,Liang F,Li C,et al. Microwave-enhanced Synthesis of Magnetic Porous Covalent Triazine-Based Framework Composites for Fast Separation of Organic Dye from Aqueous Solution[J]. J Colloid Interface Sci,2011,186:984-990.
23. [23]
  [23] Baraka A. Adsorptive Removal of Tartrazine and Methylene Blue from Wastewater Using Melamine -Formaldehyde-Tartaric Acid Resin(and a Discussion About Pseudo Second Order Model)[J]. Desalin Water Treat,2012,44(1/2/3):128-141.
24. [24]
  [24] Van Kuringen H P C,Eikelboom G,Shishmanova I K,et al. Responsive Nanoporous Smectic Liquid Crystal Polymer Networks as Efficient and Selective Adsorbents[J]. Adv Funct Mater,2014,24:5045-5051.
25. [25]
  [25] Li B Y,Su F B,Luo H K,et al. Hypercrosslinked Microporous Polymer Networks for Effective Removal of Toxic Metal Ions from Water[J]. Micropor Mesopor Mater,2011,138:207-214.
26. [26]
  [26] Wang J N,Xu L,Meng Y,et al. Adsorption of Cu²⁺ on New Hyper-crosslinked Polystyrene Adsorbent: Batch and Column Studies[J]. Chem Eng J,2011,178:108-114.
27. [27]
  [27] Cheng C,Wang J N,Xu L,et al. Preparation of New Hypercross-linked Chelating Resin for Adsorption of Cu²⁺ and Ni²⁺ from Water[J]. Chinese Chem Lett,2012,23:245-248.
28. [28]
  [28] Li B Y,Zhang Y M,Ma D X,et al. Mercury Nano-Trap for Effective and Efficient Removal of Mercury(Ⅱ) from Aqueous Solution[J]. Nat Commun,2014,5:5537.
29. [29]
  [29] Yang G W,Han H Y,Du C Y,et al. Facile Synthesis of Melamine-Based Porous Polymer Networks and Their Application for Removal of Aqueous Mercury Ions[J]. Polymer,2010,51:6193-6202.
30. [30]
  [30] Tan M X,Sum Y N,Ying J Y,et al. Mesoporous Poly-melamine-formaldehyde Polymer as A Solid Sorbent for Toxic Metal Removal[J]. Energy Environ Sci,2013,6(11):3254-3259.
31. [31]
  [31] Amoyaw P,Ingram C,Hsu F L,et al. Poly[4-(4-vinylbenzyloxy)-2-hydroxylbenzaldehyde] for Rapid Removal of Low Concentrations of Pb(Ⅱ)[J]. J Appl Polym Sci,2009,113(4):2096-2102.
32. [32]
  [32] Li C,Duan H D,Wang X J,et al. Fabrication of Porous Resins via Solubility Differences for Adsorption of Cadmium(Ⅱ)[J]. Chem Eng J,2015,262:250-259.
33. [33]
  [33] Wang J T,Xu S,Wang Y F,et al. Controllable Synthesis of Hierarchical Mesoporous/Microporous Nitrogen-Rich Polymer Networks for CO₂ and Cr(Ⅵ) Ion Adsorption[J]. RSC Adv,2014,4(31):16224-16232.
34. [34]
  [34] LYU Z F,Liang C S,Cui J Y,et al. A Facile Route for The Synthesis of Mesoporous Melamine-Formaldehyde Resins for Hexavalent Chromium Removal[J]. RSC Adv,2015,5(24):18213-18217
35. [35]
  [35] Taskin O S,Kiskan B,Aksu A,et al. Polybenzoxazine:A Powerful Tool for Removal of Mercury Salts from Water[J]. Chem Eur J,2014,20:10953-10958.
36. [36]
  [36] Cegowski M,Schroeder G. Preparation of Porous Resin with Schiff Base Chelating Groups for Removal of Heavy Metal Ions from Aqueous Solutions[J]. Chem Eng J,2015,263:402-411.
37. [37]
  [37] Li J,Yang X D,Bai C Y,et al. A Novel Benzimidazole-Functionalized 2-D COF Material: Synthesis and Application as A Selective Solid-Phase Extractant for Separation of Uranium[J]. J Colloid Interface Sci,2015,437:211-218.
38. [38]
  [38] Xu Q H,Ding S Y,Pan D Q,et al. A Multisite-functionalised Polymer for the Extraction of Thorium(Ⅳ) from Water[J]. RSC Adv,2015,5(50):39903-39907.
39. [39]
  [39] Liu J L,Zong E M,Fu H Y,et al. Adsorption of Aromatic Compounds on Porous Covalent Triazine-Based Framework[J]. J Colloid Interface Sci,2012,372:99-107.
40. [40]
  [40] Liu J L,Chen H,Zheng S R,et al. Adsorption of 4,4'-(Propane-2,2-diyl)diphenol from Aqueous Solution by a Covalent Triazine-based Framework[J]. J Chem Eng Data,2013,58(12):3557-3562.
41. [41]
  [41] Bhunia A,Dey S,Bous M,et al. High Adsorptive Properties of Covalent Triazine-based Frameworks(CTFs) for Surfctants from Aqueous Solution[J]. Chem Commun,2015,51(3):484-486.
42. [42]
  [42] Xiao G Q,Fu L C,Li A M. Enhanced Adsorption of Bisphenol A from Water by Acetylaniline Modified Hypercross-linked Polymeric Adsorbent: Effect of the Cross-linked Bridge[J]. Chem Eng J,2012,191:171-176.
43. [43]
  [43] Xiao G Q,Li H,Xu M C. Adsorption of Salicylic Acid in Aqueous Solution by a Water-compatible Hyper-cross-linked Resin Functionalized with Amino-group[J]. J Appl Polym Sci,2013,127(5):3858-3863.
44. [44]
  [44] Huang J H. Hydroquinone Modified Hyper-cross-linked Resin to be Used as a Polymeric Adsorbent for Adsorption of Salicylic Acid from Aqueous Solution[J]. J Appl Polym Sci,2011,121:3717-3723.
45. [45]
  [45] Huang J H,Jin X Y,Deng S G. Phenol Adsorption on an N-Methylacetamide-modified Hypercrosslinked Resin from Aqueous Solutions[J]. Chem Eng J,2012,192:192-200.
46. [46]
  [46] Huang J H,Wang X M,Patil P D,et al. Synthesis, Characterization and Adsorption Properties of an Amide-modified Hyper-crosslinked Resin[J]. RSC Adv,2014,4(77):41172-41178.
47. [47]
  [47] Huang J H,Wang X L,Wang X M,et al. Hyper-cross-linked Polystyrene-co-divinylbenzene Resin Modified with Acetanilide:Synthesis, Structure, and Adsorptive Removal of Salicylic Acid from Aqueous Solution[J]. Ind Eng Chem Res,2011,50(5):2891-2897.
48. [48]
  [48] Huang J H,Jin X Y,Deng S G. Phenol Adsorption on an N-Methylacetamide-modified Hypercrosslinked Resin from Aqueous Solutions[J]. Chem Eng J,2012,192:192-200.
49. [49]
  [49] Huang J H,Jin X Y,Mao J L,et al. Synthesis, Characterization and Adsorption Properties of Diethylenetriamine-Modified Hypercrosslinked Resins for Efficient Removal of Salicylic Acid from Aqueous Solution[J]. J Hazard Mater,2012,217/218:406-415.
50. [50]
  [50] Zhang H Y,Li A M,Sun J,et al. Adsorption of Amphoteric Aromatic Compounds by Hyper-cross-linked Resins with Amino Groups and Sulfonic Groups[J]. Chem Eng J,2013,217:354-362.
51. [51]
  [51] Yang W L,Li X C,Pan B C,et al. Effective Removal of Effluent Organic Matter(EfOM) from Bio-Treated Coking Wastewater by a Recyclable Aminated Hyper-cross-linked Polymer[J]. Water Res,2013,47:4730-4738.
52. [52]
  [52] Kica M,Ronka S. The Removal of Atrazine from Water Using Specific Polymeric Adsorbent[J]. Sep Sci Technol,2014,49:1634-1642.
53. [53]
  [53] Yang X J,Li B Y,Majeed I,et al. Magnetic Microporous Polymer Nanoparticles[J]. Polym Chem,2013,4(5):1425-1429.
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